A simple method for the synthesis of diarylamines containing a nitroso group in the ortho position based on the SNH arylamination of 5-nitroisoquinoline

A simple and efficient arylamination reaction of 5-nitroisoquinoline based on the oxidative nucleophilic substitution of hydrogen was demonstrated under metal-catalyst-free conditions. This reaction can be used as a method for the synthesis of isoquinoline-based diarylamines containing a nitroso gro...

Полное описание

Сохранить в:

Библиографические подробности
Главные авторы:	Pobedinskaya, D. Y., Побединская, Д. Ю., Demidov, O. P., Демидов, О. П., Avakyan, E. K., Авакян, Е. К., Borovleva, A. A., Боровлева, А. А., Larin, A. N., Ларин, А. Н., Ermolenko, A. P., Ермоленко, А. П., Borovlev, I. V., Боровлев, И. В.
Формат:	Статья
Язык:	English
Опубликовано:	Springer 2024
Темы:	Heterocycles SNH methodology Metal-free C–N bond formation Oxidative SNH arylamination Nitroso compound Redox process
Online-ссылка:	https://dspace.ncfu.ru/handle/123456789/28671
Метки:	Добавить метку Нет меток, Требуется 1-ая метка записи!

id	ir-123456789-28671
record_format	dspace
spelling	ir-123456789-286712025-04-02T14:06:16Z A simple method for the synthesis of diarylamines containing a nitroso group in the ortho position based on the SNH arylamination of 5-nitroisoquinoline Pobedinskaya, D. Y. Побединская, Д. Ю. Demidov, O. P. Демидов, О. П. Avakyan, E. K. Авакян, Е. К. Borovleva, A. A. Боровлева, А. А. Larin, A. N. Ларин, А. Н. Ermolenko, A. P. Ермоленко, А. П. Borovlev, I. V. Боровлев, И. В. Heterocycles SNH methodology Metal-free C–N bond formation Oxidative SNH arylamination Nitroso compound Redox process A simple and efficient arylamination reaction of 5-nitroisoquinoline based on the oxidative nucleophilic substitution of hydrogen was demonstrated under metal-catalyst-free conditions. This reaction can be used as a method for the synthesis of isoquinoline-based diarylamines containing a nitroso group in the ortho position, which are compounds with high synthetic potential. The oxidation of the latter leads to the formation of 6-arylamino-5-nitroisoquinoline N-oxides. The absence of the need to introduce leaving groups and a good overall yield are features of this reaction. 2024-07-31T13:11:12Z 2024-07-31T13:11:12Z 2024 Статья Pobedinskaya, D.Y., Demidov, O.P., Avakyan, E.K., Borovleva, A.A., Larin, A.N., Ermolenko, A.P., Borovlev, I.V. A simple method for the synthesis of diarylamines containing a nitroso group in the ortho position based on the SNH arylamination of 5-nitroisoquinoline // Chemistry of Heterocyclic Compounds. - 2024. - 60 (3-4). - pp. 161-168. - DOI: 10.1007/s10593-024-03313-3 https://dspace.ncfu.ru/handle/123456789/28671 en Chemistry of Heterocyclic Compounds application/pdf application/pdf Springer
institution	СКФУ
collection	Репозиторий
language	English
topic	Heterocycles SNH methodology Metal-free C–N bond formation Oxidative SNH arylamination Nitroso compound Redox process
spellingShingle	Heterocycles SNH methodology Metal-free C–N bond formation Oxidative SNH arylamination Nitroso compound Redox process Pobedinskaya, D. Y. Побединская, Д. Ю. Demidov, O. P. Демидов, О. П. Avakyan, E. K. Авакян, Е. К. Borovleva, A. A. Боровлева, А. А. Larin, A. N. Ларин, А. Н. Ermolenko, A. P. Ермоленко, А. П. Borovlev, I. V. Боровлев, И. В. A simple method for the synthesis of diarylamines containing a nitroso group in the ortho position based on the SNH arylamination of 5-nitroisoquinoline
description	A simple and efficient arylamination reaction of 5-nitroisoquinoline based on the oxidative nucleophilic substitution of hydrogen was demonstrated under metal-catalyst-free conditions. This reaction can be used as a method for the synthesis of isoquinoline-based diarylamines containing a nitroso group in the ortho position, which are compounds with high synthetic potential. The oxidation of the latter leads to the formation of 6-arylamino-5-nitroisoquinoline N-oxides. The absence of the need to introduce leaving groups and a good overall yield are features of this reaction.
format	Статья
author	Pobedinskaya, D. Y. Побединская, Д. Ю. Demidov, O. P. Демидов, О. П. Avakyan, E. K. Авакян, Е. К. Borovleva, A. A. Боровлева, А. А. Larin, A. N. Ларин, А. Н. Ermolenko, A. P. Ермоленко, А. П. Borovlev, I. V. Боровлев, И. В.
author_facet	Pobedinskaya, D. Y. Побединская, Д. Ю. Demidov, O. P. Демидов, О. П. Avakyan, E. K. Авакян, Е. К. Borovleva, A. A. Боровлева, А. А. Larin, A. N. Ларин, А. Н. Ermolenko, A. P. Ермоленко, А. П. Borovlev, I. V. Боровлев, И. В.
author_sort	Pobedinskaya, D. Y.
title	A simple method for the synthesis of diarylamines containing a nitroso group in the ortho position based on the SNH arylamination of 5-nitroisoquinoline
title_short	A simple method for the synthesis of diarylamines containing a nitroso group in the ortho position based on the SNH arylamination of 5-nitroisoquinoline
title_full	A simple method for the synthesis of diarylamines containing a nitroso group in the ortho position based on the SNH arylamination of 5-nitroisoquinoline
title_fullStr	A simple method for the synthesis of diarylamines containing a nitroso group in the ortho position based on the SNH arylamination of 5-nitroisoquinoline
title_full_unstemmed	A simple method for the synthesis of diarylamines containing a nitroso group in the ortho position based on the SNH arylamination of 5-nitroisoquinoline
title_sort	simple method for the synthesis of diarylamines containing a nitroso group in the ortho position based on the snh arylamination of 5-nitroisoquinoline
publisher	Springer
publishDate	2024
url	https://dspace.ncfu.ru/handle/123456789/28671
work_keys_str_mv	AT pobedinskayady asimplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT pobedinskaâdû asimplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT demidovop asimplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT demidovop asimplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT avakyanek asimplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT avakânek asimplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT borovlevaaa asimplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT borovlevaaa asimplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT larinan asimplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT larinan asimplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT ermolenkoap asimplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT ermolenkoap asimplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT borovleviv asimplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT borovleviv asimplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT pobedinskayady simplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT pobedinskaâdû simplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT demidovop simplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT demidovop simplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT avakyanek simplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT avakânek simplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT borovlevaaa simplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT borovlevaaa simplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT larinan simplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT larinan simplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT ermolenkoap simplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT ermolenkoap simplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT borovleviv simplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline AT borovleviv simplemethodforthesynthesisofdiarylaminescontaininganitrosogroupintheorthopositionbasedonthesnharylaminationof5nitroisoquinoline
_version_	1842245616369926144

A simple method for the synthesis of diarylamines containing a nitroso group in the ortho position based on the SNH arylamination of 5-nitroisoquinoline

Схожие документы