Effects of the structure of primary nitroalkanes and reaction conditions on the selectivity of acylamination of arenes in polyphosphoric acid

The mechanism of acylamination of arenes with nitroalkanes in polyphosphoric acid has been clarified. The influence of the concentration of polyphosphoric acid, the structure of the starting compounds, and temperature on the result of the Beckmann rearrangement, which makes it possible to shift the...

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Hauptverfasser:	Aksenov, A. V., Аксенов, А. В., Grishin, I. Y., Гришин, И. Ю., Aksenov, D. A., Аксенов, Д. А., Grishin, Y. I., Гришин, Ю. И., Aksenova, I. V., Аксенова, И. В., Aksenov, N. A., Аксенов, Н. А.
Format:	Статья
Sprache:	English
Veröffentlicht:	Springer 2024
Schlagworte:	Acylamination Polyphosphoric acid Aliphatic nitro compounds Anilides Beckmann rearrangement Benzamides
Online Zugang:	https://dspace.ncfu.ru/handle/123456789/28759
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spelling	ir-123456789-287592024-08-14T14:36:41Z Effects of the structure of primary nitroalkanes and reaction conditions on the selectivity of acylamination of arenes in polyphosphoric acid Aksenov, A. V. Аксенов, А. В. Grishin, I. Y. Гришин, И. Ю. Aksenov, D. A. Аксенов, Д. А. Grishin, Y. I. Гришин, Ю. И. Aksenova, I. V. Аксенова, И. В. Aksenov, N. A. Аксенов, Н. А. Acylamination Polyphosphoric acid Aliphatic nitro compounds Anilides Beckmann rearrangement Benzamides The mechanism of acylamination of arenes with nitroalkanes in polyphosphoric acid has been clarified. The influence of the concentration of polyphosphoric acid, the structure of the starting compounds, and temperature on the result of the Beckmann rearrangement, which makes it possible to shift the reaction towards either benzamides or anilides, has been assessed. 2024-08-14T14:35:23Z 2024-08-14T14:35:23Z 2024 Статья Aksenov, A.V., Grishin, I.Y., Aksenov, D.A., Grishin, Y.I., Aksenova, I.V., Aksenov, N.A. Effects of the structure of primary nitroalkanes and reaction conditions on the selectivity of acylamination of arenes in polyphosphoric acid // Russian Chemical Bulletin. - 2024. - 73 (6). - pp. 1612-1622. - DOI: 10.1007/s11172-024-4277-8 https://dspace.ncfu.ru/handle/123456789/28759 en Russian Chemical Bulletin application/pdf application/pdf Springer
institution	СКФУ
collection	Репозиторий
language	English
topic	Acylamination Polyphosphoric acid Aliphatic nitro compounds Anilides Beckmann rearrangement Benzamides
spellingShingle	Acylamination Polyphosphoric acid Aliphatic nitro compounds Anilides Beckmann rearrangement Benzamides Aksenov, A. V. Аксенов, А. В. Grishin, I. Y. Гришин, И. Ю. Aksenov, D. A. Аксенов, Д. А. Grishin, Y. I. Гришин, Ю. И. Aksenova, I. V. Аксенова, И. В. Aksenov, N. A. Аксенов, Н. А. Effects of the structure of primary nitroalkanes and reaction conditions on the selectivity of acylamination of arenes in polyphosphoric acid
description	The mechanism of acylamination of arenes with nitroalkanes in polyphosphoric acid has been clarified. The influence of the concentration of polyphosphoric acid, the structure of the starting compounds, and temperature on the result of the Beckmann rearrangement, which makes it possible to shift the reaction towards either benzamides or anilides, has been assessed.
format	Статья
author	Aksenov, A. V. Аксенов, А. В. Grishin, I. Y. Гришин, И. Ю. Aksenov, D. A. Аксенов, Д. А. Grishin, Y. I. Гришин, Ю. И. Aksenova, I. V. Аксенова, И. В. Aksenov, N. A. Аксенов, Н. А.
author_facet	Aksenov, A. V. Аксенов, А. В. Grishin, I. Y. Гришин, И. Ю. Aksenov, D. A. Аксенов, Д. А. Grishin, Y. I. Гришин, Ю. И. Aksenova, I. V. Аксенова, И. В. Aksenov, N. A. Аксенов, Н. А.
author_sort	Aksenov, A. V.
title	Effects of the structure of primary nitroalkanes and reaction conditions on the selectivity of acylamination of arenes in polyphosphoric acid
title_short	Effects of the structure of primary nitroalkanes and reaction conditions on the selectivity of acylamination of arenes in polyphosphoric acid
title_full	Effects of the structure of primary nitroalkanes and reaction conditions on the selectivity of acylamination of arenes in polyphosphoric acid
title_fullStr	Effects of the structure of primary nitroalkanes and reaction conditions on the selectivity of acylamination of arenes in polyphosphoric acid
title_full_unstemmed	Effects of the structure of primary nitroalkanes and reaction conditions on the selectivity of acylamination of arenes in polyphosphoric acid
title_sort	effects of the structure of primary nitroalkanes and reaction conditions on the selectivity of acylamination of arenes in polyphosphoric acid
publisher	Springer
publishDate	2024
url	https://dspace.ncfu.ru/handle/123456789/28759
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Effects of the structure of primary nitroalkanes and reaction conditions on the selectivity of acylamination of arenes in polyphosphoric acid

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