Synthesis and characterization of selenium nanoparticles stabilized with oxyethylated alkylphenol (neonol) for potential modification of fabric materials

This work demonstrates the first time synthesis of selenium nanoparticles (Se NPs) stabilized with neonol. The synthesis method was optimized using a multifactorial experiment with three input parameters. The most stable sample had a radius of 15 nm and a ζ-potential of -36.76 mV. It was found that...

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Главные авторы:	Rekhman, Z. A., Рехман, З. А., Blinov, A. V., Блинов, А. В., Gvozdenko, A. A., Гвозденко, А. А., Golik, A. B., Голик, А. Б., Nagdalian, A. A., Нагдалян, А. А., Blinova, A. A., Блинова, А. А., Serov, A. V., Серов, А. В., Pirogov, M. A., Пирогов, М. А., Askerova, A. S., Аскерова, А. С., Nazaretova, E. D., Назаретова, Е. Д.
Формат:	Статья
Язык:	English
Опубликовано:	Public Library of Science 2024
Темы:	Anti-bacterial agents Particle size Metal nanoparticles Nanoparticles Phenols Selenium Textiles Antiinfective Metal nanoparticle Phenol derivative
Online-ссылка:	https://dspace.ncfu.ru/handle/123456789/29407
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spelling	ir-123456789-294072024-12-13T12:52:02Z Synthesis and characterization of selenium nanoparticles stabilized with oxyethylated alkylphenol (neonol) for potential modification of fabric materials Rekhman, Z. A. Рехман, З. А. Blinov, A. V. Блинов, А. В. Gvozdenko, A. A. Гвозденко, А. А. Golik, A. B. Голик, А. Б. Nagdalian, A. A. Нагдалян, А. А. Blinova, A. A. Блинова, А. А. Serov, A. V. Серов, А. В. Pirogov, M. A. Пирогов, М. А. Askerova, A. S. Аскерова, А. С. Nazaretova, E. D. Назаретова, Е. Д. Anti-bacterial agents Particle size Metal nanoparticles Nanoparticles Particle size Phenols Selenium Textiles Antiinfective Metal nanoparticle Phenol derivative This work demonstrates the first time synthesis of selenium nanoparticles (Se NPs) stabilized with neonol. The synthesis method was optimized using a multifactorial experiment with three input parameters. The most stable sample had a radius of 15 nm and a ζ-potential of -36.76 mV. It was found that the optimal parameters for the synthesis of Se NPs stabilized with neonol are the following concentration values: 0.12 mol/L selenic acid, 0.095 mol/L neonol and 0.95 mol/L ascorbic acid. Quantum chemical modeling of Se-neonol molecular complex formation showed that interaction of Se with neonol occurs through a hydroxyl group. Difference in the total energy of the neonol molecule and Se-neonol molecular complex is more than 2399 kcal/mol, which indicates that formation of chemical bond between Se and neonol is energetically advantageous. It was found that all samples exhibit stability over the entire pH range from 1.81 to 11.98, and the particle size is in the range of 25–30 nm. The analysis of the study of the influence of the ionic force showed that cations do not significantly affect the Se NPs radius, but anions have a significant effect, increasing the average hydrodynamic radius up to 2750 nm. For modification with Se NPs, silk, gauze, wool, cotton and cardboard samples were used. Elemental mapping of the samples showed an ambiguous distribution of Se NPs over the surface of fabric material. Assessment of potential antibacterial activity of modified fabric materials revealed inhibition zones of Micrococcus luteus growth from 12 to 16 mm for silk, gauze, wool and cotton. Notably, the most intense inhibition of Micrococcus luteus was observed in wool treated be Se NPs stabilized with neonol. Cardboard did not express Micrococcus luteus growth inhibition action because of weak interaction of cellulose filaments with Se NPs and neonol and possible microbial digestion of cellulose and xylan. This is an open access article, free of all copyright, and may be freely reproduced, distributed, transmitted, modified, built upon, or otherwise used by anyone for any lawful purpose. The work is made available under the Creative Commons CC0 public domain dedication. 2024-12-13T12:46:54Z 2024-12-13T12:46:54Z 2024 Статья Rekhman Z., Blinov A., Gvozdenko A., Golik A., Nagdalian A., Blinova A., Serov A., Pirogov M., Askerova A., Nazaretova E., Shariati M.A., Al Zahrani A.A., AL-Farga A., Al-Maaqar S.M. Synthesis and characterization of selenium nanoparticles stabilized with oxyethylated alkylphenol (neonol) for potential modification of fabric materials // PLoS ONE. - 2024. - 19 (11). - art. no. e0314208. - DOI: 10.1371/journal.pone.0314208 https://dspace.ncfu.ru/handle/123456789/29407 en PLoS ONE application/pdf application/pdf Public Library of Science
institution	СКФУ
collection	Репозиторий
language	English
topic	Anti-bacterial agents Particle size Metal nanoparticles Nanoparticles Particle size Phenols Selenium Textiles Antiinfective Metal nanoparticle Phenol derivative
spellingShingle	Anti-bacterial agents Particle size Metal nanoparticles Nanoparticles Particle size Phenols Selenium Textiles Antiinfective Metal nanoparticle Phenol derivative Rekhman, Z. A. Рехман, З. А. Blinov, A. V. Блинов, А. В. Gvozdenko, A. A. Гвозденко, А. А. Golik, A. B. Голик, А. Б. Nagdalian, A. A. Нагдалян, А. А. Blinova, A. A. Блинова, А. А. Serov, A. V. Серов, А. В. Pirogov, M. A. Пирогов, М. А. Askerova, A. S. Аскерова, А. С. Nazaretova, E. D. Назаретова, Е. Д. Synthesis and characterization of selenium nanoparticles stabilized with oxyethylated alkylphenol (neonol) for potential modification of fabric materials
description	This work demonstrates the first time synthesis of selenium nanoparticles (Se NPs) stabilized with neonol. The synthesis method was optimized using a multifactorial experiment with three input parameters. The most stable sample had a radius of 15 nm and a ζ-potential of -36.76 mV. It was found that the optimal parameters for the synthesis of Se NPs stabilized with neonol are the following concentration values: 0.12 mol/L selenic acid, 0.095 mol/L neonol and 0.95 mol/L ascorbic acid. Quantum chemical modeling of Se-neonol molecular complex formation showed that interaction of Se with neonol occurs through a hydroxyl group. Difference in the total energy of the neonol molecule and Se-neonol molecular complex is more than 2399 kcal/mol, which indicates that formation of chemical bond between Se and neonol is energetically advantageous. It was found that all samples exhibit stability over the entire pH range from 1.81 to 11.98, and the particle size is in the range of 25–30 nm. The analysis of the study of the influence of the ionic force showed that cations do not significantly affect the Se NPs radius, but anions have a significant effect, increasing the average hydrodynamic radius up to 2750 nm. For modification with Se NPs, silk, gauze, wool, cotton and cardboard samples were used. Elemental mapping of the samples showed an ambiguous distribution of Se NPs over the surface of fabric material. Assessment of potential antibacterial activity of modified fabric materials revealed inhibition zones of Micrococcus luteus growth from 12 to 16 mm for silk, gauze, wool and cotton. Notably, the most intense inhibition of Micrococcus luteus was observed in wool treated be Se NPs stabilized with neonol. Cardboard did not express Micrococcus luteus growth inhibition action because of weak interaction of cellulose filaments with Se NPs and neonol and possible microbial digestion of cellulose and xylan. This is an open access article, free of all copyright, and may be freely reproduced, distributed, transmitted, modified, built upon, or otherwise used by anyone for any lawful purpose. The work is made available under the Creative Commons CC0 public domain dedication.
format	Статья
author	Rekhman, Z. A. Рехман, З. А. Blinov, A. V. Блинов, А. В. Gvozdenko, A. A. Гвозденко, А. А. Golik, A. B. Голик, А. Б. Nagdalian, A. A. Нагдалян, А. А. Blinova, A. A. Блинова, А. А. Serov, A. V. Серов, А. В. Pirogov, M. A. Пирогов, М. А. Askerova, A. S. Аскерова, А. С. Nazaretova, E. D. Назаретова, Е. Д.
author_facet	Rekhman, Z. A. Рехман, З. А. Blinov, A. V. Блинов, А. В. Gvozdenko, A. A. Гвозденко, А. А. Golik, A. B. Голик, А. Б. Nagdalian, A. A. Нагдалян, А. А. Blinova, A. A. Блинова, А. А. Serov, A. V. Серов, А. В. Pirogov, M. A. Пирогов, М. А. Askerova, A. S. Аскерова, А. С. Nazaretova, E. D. Назаретова, Е. Д.
author_sort	Rekhman, Z. A.
title	Synthesis and characterization of selenium nanoparticles stabilized with oxyethylated alkylphenol (neonol) for potential modification of fabric materials
title_short	Synthesis and characterization of selenium nanoparticles stabilized with oxyethylated alkylphenol (neonol) for potential modification of fabric materials
title_full	Synthesis and characterization of selenium nanoparticles stabilized with oxyethylated alkylphenol (neonol) for potential modification of fabric materials
title_fullStr	Synthesis and characterization of selenium nanoparticles stabilized with oxyethylated alkylphenol (neonol) for potential modification of fabric materials
title_full_unstemmed	Synthesis and characterization of selenium nanoparticles stabilized with oxyethylated alkylphenol (neonol) for potential modification of fabric materials
title_sort	synthesis and characterization of selenium nanoparticles stabilized with oxyethylated alkylphenol (neonol) for potential modification of fabric materials
publisher	Public Library of Science
publishDate	2024
url	https://dspace.ncfu.ru/handle/123456789/29407
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Synthesis and characterization of selenium nanoparticles stabilized with oxyethylated alkylphenol (neonol) for potential modification of fabric materials

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