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6-Aryl- and 6,7-diaryl-1,3-dimethyl-1H-perimidin-2(3H)-ones: synthesis, conformational stability, crystal structure and optical properties

6-Aryl- and 6,7-diaryl-1,3-dimethyl-1H-perimidin-2(3H)-ones: synthesis, conformational stability, crystal structure and optical properties

6-Bromo- and 6,7-dibromo-1,3-dimethyl-1H-perimidin-2(3H)-ones were arylated with arylboronic acids under Suzuki–Miyaura reaction conditions to afford 6-aryl-, 6-bromo-7-aryl- and 6,7-diaryl-1,3-dimethyl-1H-perimidin-2(3H)-ones. A comparison of the X-ray structural parameters of peri-diaryl derivativ...

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Bibliographic Details
Main Authors: Demidov, O. P., Демидов, О. П.
Format: Статья
Language:English
Published: Royal Society of Chemistry 2025
Subjects:
Alkylation
Crystals structures
Isomerization
Isomers
Naphthalene
Synthesis (chemical)
Arylboronic acids
Conformational stabilities;
H NMR spectroscopy
Property
Proton sponge
Reaction conditions
Structural parameter
Suzuki-Miyaura reaction
Nuclear magnetic resonance spectroscopy
Online Access:https://dspace.ncfu.ru/handle/123456789/29599
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