Development and optimization of the synthesis procedure of selenium nanoparticles stabilized by methylcellulose

As a result of the work performed, a method for synthesizing selenium nanoparticles stabilized with methylcellulose was developed and optimized. Selenious acid was used as a selenium-containing precursor, ascorbic acid as a reducing agent, and methylcellulose as a stabilizer. A multifactorial experi...

Полное описание

Сохранить в:

Библиографические подробности
Главные авторы:	Blinova, A. A., Блинова, А. А., Gvozdenko, A. A., Гвозденко, А. А., Rekhman, Z. A., Рехман, З. А., Blinov, A. V., Блинов, А. В., Taravanov, M. A., Тараванов, М. А., Nazaretova, E. D., Назаретова, Е. Д.
Формат:	Статья
Язык:	Russian
Опубликовано:	2025
Темы:	Selenium Optimization Average hydrodynamic radius Methylcellulose Nanoparticles
Online-ссылка:	https://dspace.ncfu.ru/handle/123456789/29615
Метки:	Добавить метку Нет меток, Требуется 1-ая метка записи!

id	ir-123456789-29615
record_format	dspace
spelling	ir-123456789-296152025-02-04T13:04:08Z Development and optimization of the synthesis procedure of selenium nanoparticles stabilized by methylcellulose Blinova, A. A. Блинова, А. А. Gvozdenko, A. A. Гвозденко, А. А. Rekhman, Z. A. Рехман, З. А. Blinov, A. V. Блинов, А. В. Taravanov, M. A. Тараванов, М. А. Nazaretova, E. D. Назаретова, Е. Д. Selenium Optimization Average hydrodynamic radius Methylcellulose Nanoparticles As a result of the work performed, a method for synthesizing selenium nanoparticles stabilized with methylcellulose was developed and optimized. Selenious acid was used as a selenium-containing precursor, ascorbic acid as a reducing agent, and methylcellulose as a stabilizer. A multifactorial experiment was conducted to optimize the method for synthesizing selenium nanoparticles stabilized with methylcellulose. It was found that for the synthesis of selenium nanoparticles with the smallest average hydrodynamic radius, the molar concentration of selenious acid in the solution should be in the range from 0,0036 to 0,1033 mol/l, the mass of methylcellulose – from 3,0 to 3,985 g, the molar concentration of ascorbic acid – from 1,52 to 2,12 mol/l. It is shown that pH of the medium, charge and concentration of sodium and barium ions do not affect the average hydrodynamic radius of selenium nanoparticles stabilized with methylcellulose. However, when exposed to iron ions, the radius increases from 150 to 270 nm. It is established that an increase in the concentration and charge of anions has a significant effect on the average hydrodynamic radius of selenium nanoparticles stabilized with methylcellulose. With an increase in the concentration of chlorine ions from 0,1 to 1 mol/l, an increase in the average hydrodynamic radius of particles occurred from 143 to 156 nm, with an increase in the concentration of sulfate ions from 0,1 to 1 mol/l, an increase in the average hydrodynamic radius of particles – from 165 to 6129 nm, with an increase in the concentration of phosphate ions from 0,1 to 1 mol/l, an increase in the average hydrodynamic radius of particles – from 149 to 17000 nm. 2025-02-04T12:59:28Z 2025-02-04T12:59:28Z 2024 Статья Blinova, A. A., Gvozdenko А. А., Rekhman, Z. A., Blinov, A. V., Taravanov, М. А., Nazaretova, Е. D. Development and optimization of the synthesis procedure of selenium nanoparticles stabilized by methylcellulose // PHYSICAL AND CHEMICAL ASPECTS OF THE STUDY OF CLUSTERS NANOSTRUCTURES AND NANOMATERIALS. - 2024. - 16. - pp. 758-766. - DOI: 10.26456/pcascnn/2024.16.758 https://dspace.ncfu.ru/handle/123456789/29615 ru PHYSICAL AND CHEMICAL ASPECTS OF THE STUDY OF CLUSTERS NANOSTRUCTURES AND NANOMATERIALS application/pdf
institution	СКФУ
collection	Репозиторий
language	Russian
topic	Selenium Optimization Average hydrodynamic radius Methylcellulose Nanoparticles
spellingShingle	Selenium Optimization Average hydrodynamic radius Methylcellulose Nanoparticles Blinova, A. A. Блинова, А. А. Gvozdenko, A. A. Гвозденко, А. А. Rekhman, Z. A. Рехман, З. А. Blinov, A. V. Блинов, А. В. Taravanov, M. A. Тараванов, М. А. Nazaretova, E. D. Назаретова, Е. Д. Development and optimization of the synthesis procedure of selenium nanoparticles stabilized by methylcellulose
description	As a result of the work performed, a method for synthesizing selenium nanoparticles stabilized with methylcellulose was developed and optimized. Selenious acid was used as a selenium-containing precursor, ascorbic acid as a reducing agent, and methylcellulose as a stabilizer. A multifactorial experiment was conducted to optimize the method for synthesizing selenium nanoparticles stabilized with methylcellulose. It was found that for the synthesis of selenium nanoparticles with the smallest average hydrodynamic radius, the molar concentration of selenious acid in the solution should be in the range from 0,0036 to 0,1033 mol/l, the mass of methylcellulose – from 3,0 to 3,985 g, the molar concentration of ascorbic acid – from 1,52 to 2,12 mol/l. It is shown that pH of the medium, charge and concentration of sodium and barium ions do not affect the average hydrodynamic radius of selenium nanoparticles stabilized with methylcellulose. However, when exposed to iron ions, the radius increases from 150 to 270 nm. It is established that an increase in the concentration and charge of anions has a significant effect on the average hydrodynamic radius of selenium nanoparticles stabilized with methylcellulose. With an increase in the concentration of chlorine ions from 0,1 to 1 mol/l, an increase in the average hydrodynamic radius of particles occurred from 143 to 156 nm, with an increase in the concentration of sulfate ions from 0,1 to 1 mol/l, an increase in the average hydrodynamic radius of particles – from 165 to 6129 nm, with an increase in the concentration of phosphate ions from 0,1 to 1 mol/l, an increase in the average hydrodynamic radius of particles – from 149 to 17000 nm.
format	Статья
author	Blinova, A. A. Блинова, А. А. Gvozdenko, A. A. Гвозденко, А. А. Rekhman, Z. A. Рехман, З. А. Blinov, A. V. Блинов, А. В. Taravanov, M. A. Тараванов, М. А. Nazaretova, E. D. Назаретова, Е. Д.
author_facet	Blinova, A. A. Блинова, А. А. Gvozdenko, A. A. Гвозденко, А. А. Rekhman, Z. A. Рехман, З. А. Blinov, A. V. Блинов, А. В. Taravanov, M. A. Тараванов, М. А. Nazaretova, E. D. Назаретова, Е. Д.
author_sort	Blinova, A. A.
title	Development and optimization of the synthesis procedure of selenium nanoparticles stabilized by methylcellulose
title_short	Development and optimization of the synthesis procedure of selenium nanoparticles stabilized by methylcellulose
title_full	Development and optimization of the synthesis procedure of selenium nanoparticles stabilized by methylcellulose
title_fullStr	Development and optimization of the synthesis procedure of selenium nanoparticles stabilized by methylcellulose
title_full_unstemmed	Development and optimization of the synthesis procedure of selenium nanoparticles stabilized by methylcellulose
title_sort	development and optimization of the synthesis procedure of selenium nanoparticles stabilized by methylcellulose
publishDate	2025
url	https://dspace.ncfu.ru/handle/123456789/29615
work_keys_str_mv	AT blinovaaa developmentandoptimizationofthesynthesisprocedureofseleniumnanoparticlesstabilizedbymethylcellulose AT blinovaaa developmentandoptimizationofthesynthesisprocedureofseleniumnanoparticlesstabilizedbymethylcellulose AT gvozdenkoaa developmentandoptimizationofthesynthesisprocedureofseleniumnanoparticlesstabilizedbymethylcellulose AT gvozdenkoaa developmentandoptimizationofthesynthesisprocedureofseleniumnanoparticlesstabilizedbymethylcellulose AT rekhmanza developmentandoptimizationofthesynthesisprocedureofseleniumnanoparticlesstabilizedbymethylcellulose AT rehmanza developmentandoptimizationofthesynthesisprocedureofseleniumnanoparticlesstabilizedbymethylcellulose AT blinovav developmentandoptimizationofthesynthesisprocedureofseleniumnanoparticlesstabilizedbymethylcellulose AT blinovav developmentandoptimizationofthesynthesisprocedureofseleniumnanoparticlesstabilizedbymethylcellulose AT taravanovma developmentandoptimizationofthesynthesisprocedureofseleniumnanoparticlesstabilizedbymethylcellulose AT taravanovma developmentandoptimizationofthesynthesisprocedureofseleniumnanoparticlesstabilizedbymethylcellulose AT nazaretovaed developmentandoptimizationofthesynthesisprocedureofseleniumnanoparticlesstabilizedbymethylcellulose AT nazaretovaed developmentandoptimizationofthesynthesisprocedureofseleniumnanoparticlesstabilizedbymethylcellulose
_version_	1842245814169108480

Development and optimization of the synthesis procedure of selenium nanoparticles stabilized by methylcellulose

Схожие документы