Substitution of Praseodymium for Cadmium and Lead in the Structure of Pr5Mo3O16+δ

Solid solutions based on fluorite-like phase in systems Pr<inf>5–x</inf>Me<inf>x</inf>Mo<inf>3</inf>O<inf>16+δ</inf>, where Me = Cd, Pb, have been obtained by solid-phase synthesis from metal oxides. The phase content after calcination at 1000°C has be...

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Huvudupphovsmän:	Berezhnaya, T. S., Бережная, Т. С., Ukleina, I. Y., Уклеина, И. Ю., Guseva, A. V., Гусева, А. В., Chebyshev, K. A., Чебышев, К. А.
Materialtyp:	Статья
Språk:	English
Publicerad:	Pleiades Publishing 2025
Ämnen:	Electrical conductivity Crystal structure Heterovalent substitutions Isomorphic substitutions Nd5mo3o16+δ structure Praseodymium molybdate Additives Cadmium Cadmium compounds
Länkar:	https://dspace.ncfu.ru/handle/123456789/31831
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spelling	ir-123456789-318312025-08-11T08:53:41Z Substitution of Praseodymium for Cadmium and Lead in the Structure of Pr5Mo3O16+δ Berezhnaya, T. S. Бережная, Т. С. Ukleina, I. Y. Уклеина, И. Ю. Guseva, A. V. Гусева, А. В. Chebyshev, K. A. Чебышев, К. А. Electrical conductivity Crystal structure Heterovalent substitutions Isomorphic substitutions Nd5mo3o16+δ structure Praseodymium molybdate Additives Cadmium Cadmium compounds Solid solutions based on fluorite-like phase in systems Pr<inf>5–x</inf>Me<inf>x</inf>Mo<inf>3</inf>O<inf>16+δ</inf>, where Me = Cd, Pb, have been obtained by solid-phase synthesis from metal oxides. The phase content after calcination at 1000°C has been studied by X-ray powder diffraction; the substitution limits and the dependences of the unit cell parameter on the composition of the systems have been determined. The parameters of the crystal structure of solid solutions have been specified by the Rietveld method. The influence of magnesium oxide additives on the sinterability of cadmium-containing solid solutions has been established. Isomorphous substitution of praseodymium by lead and cadmium has been found to result in a decrease in the conductivity value of the samples in the studied systems. 2025-08-11T08:49:27Z 2025-08-11T08:49:27Z 2025 Статья Sidorenko, A. O., Berezhnaya, T. S.,Pasechnik, L. V., Ukleina, I. Y., Guseva, A. V., Chebyshev, K. A. Substitution of Praseodymium for Cadmium and Lead in the Structure of Pr5Mo3O16+δ // Russian Journal of Inorganic Chemistry. - 2-25. - 70 (5). - pp. 666 - 673. - DOI: 10.1134/S0036023624603179 https://dspace.ncfu.ru/handle/123456789/31831 en Russian Journal of Inorganic Chemistry application/pdf application/pdf Pleiades Publishing
institution	СКФУ
collection	Репозиторий
language	English
topic	Electrical conductivity Crystal structure Heterovalent substitutions Isomorphic substitutions Nd5mo3o16+δ structure Praseodymium molybdate Additives Cadmium Cadmium compounds
spellingShingle	Electrical conductivity Crystal structure Heterovalent substitutions Isomorphic substitutions Nd5mo3o16+δ structure Praseodymium molybdate Additives Cadmium Cadmium compounds Berezhnaya, T. S. Бережная, Т. С. Ukleina, I. Y. Уклеина, И. Ю. Guseva, A. V. Гусева, А. В. Chebyshev, K. A. Чебышев, К. А. Substitution of Praseodymium for Cadmium and Lead in the Structure of Pr5Mo3O16+δ
description	Solid solutions based on fluorite-like phase in systems Pr<inf>5–x</inf>Me<inf>x</inf>Mo<inf>3</inf>O<inf>16+δ</inf>, where Me = Cd, Pb, have been obtained by solid-phase synthesis from metal oxides. The phase content after calcination at 1000°C has been studied by X-ray powder diffraction; the substitution limits and the dependences of the unit cell parameter on the composition of the systems have been determined. The parameters of the crystal structure of solid solutions have been specified by the Rietveld method. The influence of magnesium oxide additives on the sinterability of cadmium-containing solid solutions has been established. Isomorphous substitution of praseodymium by lead and cadmium has been found to result in a decrease in the conductivity value of the samples in the studied systems.
format	Статья
author	Berezhnaya, T. S. Бережная, Т. С. Ukleina, I. Y. Уклеина, И. Ю. Guseva, A. V. Гусева, А. В. Chebyshev, K. A. Чебышев, К. А.
author_facet	Berezhnaya, T. S. Бережная, Т. С. Ukleina, I. Y. Уклеина, И. Ю. Guseva, A. V. Гусева, А. В. Chebyshev, K. A. Чебышев, К. А.
author_sort	Berezhnaya, T. S.
title	Substitution of Praseodymium for Cadmium and Lead in the Structure of Pr5Mo3O16+δ
title_short	Substitution of Praseodymium for Cadmium and Lead in the Structure of Pr5Mo3O16+δ
title_full	Substitution of Praseodymium for Cadmium and Lead in the Structure of Pr5Mo3O16+δ
title_fullStr	Substitution of Praseodymium for Cadmium and Lead in the Structure of Pr5Mo3O16+δ
title_full_unstemmed	Substitution of Praseodymium for Cadmium and Lead in the Structure of Pr5Mo3O16+δ
title_sort	substitution of praseodymium for cadmium and lead in the structure of pr5mo3o16+δ
publisher	Pleiades Publishing
publishDate	2025
url	https://dspace.ncfu.ru/handle/123456789/31831
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Substitution of Praseodymium for Cadmium and Lead in the Structure of Pr5Mo3O16+δ

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