Electrophilically activated nitroalkanes in reaction with aliphatic diamines en route to imidazolines

A novel synthetic methodology for the assembly of imidazolines via an unusual reaction between nitroalkanes and aliphatic 1,2-diamines in the presence of phosphorous acid is described. In contrast to the related highly efficient preparation of benzimidazoles from aromatic amines, this process repres...

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Auteurs principaux:	Aksenov, A. V., Аксенов, А. В., Aksenov, N. A., Аксенов, Н. А., Arutiunov, N. A., Арутюнов, Н. А., Malyuga, V. V., Малюга, В. В., Ovcharov, S. N., Овчаров, С. Н., Rubin, M. A., Рубин, М. А.
Format:	Статья
Langue:	English
Publié:	Royal Society of Chemistry 2019
Sujets:	Amines Aliphatic diamines Aromatic amines Benzimidazoles En-route Imidazolines Nitroalkanes Phosphorous acid Synthetic methodology Paraffins
Accès en ligne:	https://dspace.ncfu.ru/handle/20.500.12258/10138
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id	ir-20.500.12258-10138
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spelling	ir-20.500.12258-101382025-02-13T09:34:21Z Electrophilically activated nitroalkanes in reaction with aliphatic diamines en route to imidazolines Aksenov, A. V. Аксенов, А. В. Aksenov, N. A. Аксенов, Н. А. Arutiunov, N. A. Арутюнов, Н. А. Malyuga, V. V. Малюга, В. В. Ovcharov, S. N. Овчаров, С. Н. Rubin, M. A. Рубин, М. А. Amines Aliphatic diamines Aromatic amines Benzimidazoles En-route Imidazolines Nitroalkanes Phosphorous acid Synthetic methodology Paraffins A novel synthetic methodology for the assembly of imidazolines via an unusual reaction between nitroalkanes and aliphatic 1,2-diamines in the presence of phosphorous acid is described. In contrast to the related highly efficient preparation of benzimidazoles from aromatic amines, this process represents a major synthetic challenge and for a long time was elusive. Analysis of the method limitations is provided 2019-12-24T08:36:18Z 2019-12-24T08:36:18Z 2019 Статья Aksenov, A.V., Aksenov, N.A., Arutiunov, N.A., Malyuga, V.V., Ovcharov, S.N., Rubin, M. Electrophilically activated nitroalkanes in reaction with aliphatic diamines en route to imidazolines // RSC Advances. - 2019. - Volume 9. - Issue 67. - Pages 39458-39465 http://hdl.handle.net/20.500.12258/10138 en RSC Advances application/pdf application/pdf Royal Society of Chemistry
institution	СКФУ
collection	Репозиторий
language	English
topic	Amines Aliphatic diamines Aromatic amines Benzimidazoles En-route Imidazolines Nitroalkanes Phosphorous acid Synthetic methodology Paraffins
spellingShingle	Amines Aliphatic diamines Aromatic amines Benzimidazoles En-route Imidazolines Nitroalkanes Phosphorous acid Synthetic methodology Paraffins Aksenov, A. V. Аксенов, А. В. Aksenov, N. A. Аксенов, Н. А. Arutiunov, N. A. Арутюнов, Н. А. Malyuga, V. V. Малюга, В. В. Ovcharov, S. N. Овчаров, С. Н. Rubin, M. A. Рубин, М. А. Electrophilically activated nitroalkanes in reaction with aliphatic diamines en route to imidazolines
description	A novel synthetic methodology for the assembly of imidazolines via an unusual reaction between nitroalkanes and aliphatic 1,2-diamines in the presence of phosphorous acid is described. In contrast to the related highly efficient preparation of benzimidazoles from aromatic amines, this process represents a major synthetic challenge and for a long time was elusive. Analysis of the method limitations is provided
format	Статья
author	Aksenov, A. V. Аксенов, А. В. Aksenov, N. A. Аксенов, Н. А. Arutiunov, N. A. Арутюнов, Н. А. Malyuga, V. V. Малюга, В. В. Ovcharov, S. N. Овчаров, С. Н. Rubin, M. A. Рубин, М. А.
author_facet	Aksenov, A. V. Аксенов, А. В. Aksenov, N. A. Аксенов, Н. А. Arutiunov, N. A. Арутюнов, Н. А. Malyuga, V. V. Малюга, В. В. Ovcharov, S. N. Овчаров, С. Н. Rubin, M. A. Рубин, М. А.
author_sort	Aksenov, A. V.
title	Electrophilically activated nitroalkanes in reaction with aliphatic diamines en route to imidazolines
title_short	Electrophilically activated nitroalkanes in reaction with aliphatic diamines en route to imidazolines
title_full	Electrophilically activated nitroalkanes in reaction with aliphatic diamines en route to imidazolines
title_fullStr	Electrophilically activated nitroalkanes in reaction with aliphatic diamines en route to imidazolines
title_full_unstemmed	Electrophilically activated nitroalkanes in reaction with aliphatic diamines en route to imidazolines
title_sort	electrophilically activated nitroalkanes in reaction with aliphatic diamines en route to imidazolines
publisher	Royal Society of Chemistry
publishDate	2019
url	https://dspace.ncfu.ru/handle/20.500.12258/10138
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Electrophilically activated nitroalkanes in reaction with aliphatic diamines en route to imidazolines

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