Unexpected cyclization ortho-nitrochalcones into 2-alkylideneindolin-3-ones

An original, facile, and highly efficient method for the preparation of 2-(3-oxoindolin-2-ylidene)acetonitriles fromortho-nitrochalcones is described. The featured transformation is a triggered Michael addition of the cyanide anion to the chalcone followed by a cascade cyclization mechanistically re...

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Հիմնական հեղինակներ:	Aksenov, N. A., Аксенов, Н. А., Aksenov, D. A., Аксенов, Д. А., Arutiunov, N. A., Арутюнов, Н. А., Aksenova, D. S., Аксенова, Д. С., Aksenov, A. V., Аксенов, А. В., Rubin, M. A., Рубин, М. А.
Ձևաչափ:	Статья
Լեզու:	English
Հրապարակվել է:	Royal Society of Chemistry 2020
Խորագրեր:	Addition reaction Cascade cyclization Chalcones Cyanide anions Michael additions Cyclization
Առցանց հասանելիություն:	https://dspace.ncfu.ru/handle/20.500.12258/12154
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id	ir-20.500.12258-12154
record_format	dspace
spelling	ir-20.500.12258-121542025-02-12T13:08:26Z Unexpected cyclization ortho-nitrochalcones into 2-alkylideneindolin-3-ones Aksenov, N. A. Аксенов, Н. А. Aksenov, D. A. Аксенов, Д. А. Arutiunov, N. A. Арутюнов, Н. А. Aksenova, D. S. Аксенова, Д. С. Aksenov, A. V. Аксенов, А. В. Rubin, M. A. Рубин, М. А. Addition reaction Cascade cyclization Chalcones Cyanide anions Michael additions Cyclization An original, facile, and highly efficient method for the preparation of 2-(3-oxoindolin-2-ylidene)acetonitriles fromortho-nitrochalcones is described. The featured transformation is a triggered Michael addition of the cyanide anion to the chalcone followed by a cascade cyclization mechanistically related to the Baeyer-Drewson reaction 2020-06-30T10:10:02Z 2020-06-30T10:10:02Z 2020 Статья Aksenov, N.A., Aksenov, D.A., Arutiunov, N.A., Aksenova, D.S., Aksenov, A.V., Rubin, M. Unexpected cyclization ortho-nitrochalcones into 2-alkylideneindolin-3-ones // RSC Advances. - 2020. - Volume 10. - Issue 31. -Pages 18440-18450 http://hdl.handle.net/20.500.12258/12154 en RSC Advances application/pdf application/pdf Royal Society of Chemistry
institution	СКФУ
collection	Репозиторий
language	English
topic	Addition reaction Cascade cyclization Chalcones Cyanide anions Michael additions Cyclization
spellingShingle	Addition reaction Cascade cyclization Chalcones Cyanide anions Michael additions Cyclization Aksenov, N. A. Аксенов, Н. А. Aksenov, D. A. Аксенов, Д. А. Arutiunov, N. A. Арутюнов, Н. А. Aksenova, D. S. Аксенова, Д. С. Aksenov, A. V. Аксенов, А. В. Rubin, M. A. Рубин, М. А. Unexpected cyclization ortho-nitrochalcones into 2-alkylideneindolin-3-ones
description	An original, facile, and highly efficient method for the preparation of 2-(3-oxoindolin-2-ylidene)acetonitriles fromortho-nitrochalcones is described. The featured transformation is a triggered Michael addition of the cyanide anion to the chalcone followed by a cascade cyclization mechanistically related to the Baeyer-Drewson reaction
format	Статья
author	Aksenov, N. A. Аксенов, Н. А. Aksenov, D. A. Аксенов, Д. А. Arutiunov, N. A. Арутюнов, Н. А. Aksenova, D. S. Аксенова, Д. С. Aksenov, A. V. Аксенов, А. В. Rubin, M. A. Рубин, М. А.
author_facet	Aksenov, N. A. Аксенов, Н. А. Aksenov, D. A. Аксенов, Д. А. Arutiunov, N. A. Арутюнов, Н. А. Aksenova, D. S. Аксенова, Д. С. Aksenov, A. V. Аксенов, А. В. Rubin, M. A. Рубин, М. А.
author_sort	Aksenov, N. A.
title	Unexpected cyclization ortho-nitrochalcones into 2-alkylideneindolin-3-ones
title_short	Unexpected cyclization ortho-nitrochalcones into 2-alkylideneindolin-3-ones
title_full	Unexpected cyclization ortho-nitrochalcones into 2-alkylideneindolin-3-ones
title_fullStr	Unexpected cyclization ortho-nitrochalcones into 2-alkylideneindolin-3-ones
title_full_unstemmed	Unexpected cyclization ortho-nitrochalcones into 2-alkylideneindolin-3-ones
title_sort	unexpected cyclization ortho-nitrochalcones into 2-alkylideneindolin-3-ones
publisher	Royal Society of Chemistry
publishDate	2020
url	https://dspace.ncfu.ru/handle/20.500.12258/12154
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Unexpected cyclization ortho-nitrochalcones into 2-alkylideneindolin-3-ones

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