A general method for the synthesis of heterocyclic dithiocarboxylate betaines: potential precursors of NHC based on a novel type of functionalization of the methyl group

A more general, non-carbene route to heterocyclic dithiocarboxylate betaines was developed based on a novel type of functionalization of the C-methyl group of heterocyclic quaternary salts under the action of sulfur. These types of betaines are of interest as possible precursors for N-heterocyclic c...

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Главные авторы:	Demidov, O. P., Демидов, О. П.
פורמט:	Статья
שפה:	English
יצא לאור:	Elsevier Ltd 2020
נושאים:	Carbene precursors Dithiocarboxylate betaines Methylene bases Nitrogen heterocycles Thiolation
גישה מקוונת:	https://dspace.ncfu.ru/handle/20.500.12258/13670
תגים:	הוספת תג אין תגיות, היה/י הראשונ/ה לתייג את הרשומה!

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spelling	ir-20.500.12258-136702020-09-02T08:53:19Z A general method for the synthesis of heterocyclic dithiocarboxylate betaines: potential precursors of NHC based on a novel type of functionalization of the methyl group Demidov, O. P. Демидов, О. П. Carbene precursors Dithiocarboxylate betaines Methylene bases Nitrogen heterocycles Thiolation A more general, non-carbene route to heterocyclic dithiocarboxylate betaines was developed based on a novel type of functionalization of the C-methyl group of heterocyclic quaternary salts under the action of sulfur. These types of betaines are of interest as possible precursors for N-heterocyclic carbenes and metal complex catalysts 2020-08-31T11:34:55Z 2020-08-31T11:34:55Z 2020 Статья Morkovnik, A., Zubenko, A., Divaeva, L., Demidov, O., Gribanova, T., Sochnev, V., Klimenko, A., Dobaeva, N., Borodkin, G., Drobin, Y.,Fetisov, L., Kononenko, K. A general method for the synthesis of heterocyclic dithiocarboxylate betaines: Potential precursors of NHC based on a novel type of functionalization of the methyl group // Tetrahedron Letters. - 2020. - Volume 61. - Issue 35. - Номер статьи 152228 http://hdl.handle.net/20.500.12258/13670 en Tetrahedron Letters application/pdf application/pdf Elsevier Ltd
institution	СКФУ
collection	Репозиторий
language	English
topic	Carbene precursors Dithiocarboxylate betaines Methylene bases Nitrogen heterocycles Thiolation
spellingShingle	Carbene precursors Dithiocarboxylate betaines Methylene bases Nitrogen heterocycles Thiolation Demidov, O. P. Демидов, О. П. A general method for the synthesis of heterocyclic dithiocarboxylate betaines: potential precursors of NHC based on a novel type of functionalization of the methyl group
description	A more general, non-carbene route to heterocyclic dithiocarboxylate betaines was developed based on a novel type of functionalization of the C-methyl group of heterocyclic quaternary salts under the action of sulfur. These types of betaines are of interest as possible precursors for N-heterocyclic carbenes and metal complex catalysts
format	Статья
author	Demidov, O. P. Демидов, О. П.
author_facet	Demidov, O. P. Демидов, О. П.
author_sort	Demidov, O. P.
title	A general method for the synthesis of heterocyclic dithiocarboxylate betaines: potential precursors of NHC based on a novel type of functionalization of the methyl group
title_short	A general method for the synthesis of heterocyclic dithiocarboxylate betaines: potential precursors of NHC based on a novel type of functionalization of the methyl group
title_full	A general method for the synthesis of heterocyclic dithiocarboxylate betaines: potential precursors of NHC based on a novel type of functionalization of the methyl group
title_fullStr	A general method for the synthesis of heterocyclic dithiocarboxylate betaines: potential precursors of NHC based on a novel type of functionalization of the methyl group
title_full_unstemmed	A general method for the synthesis of heterocyclic dithiocarboxylate betaines: potential precursors of NHC based on a novel type of functionalization of the methyl group
title_sort	general method for the synthesis of heterocyclic dithiocarboxylate betaines: potential precursors of nhc based on a novel type of functionalization of the methyl group
publisher	Elsevier Ltd
publishDate	2020
url	https://dspace.ncfu.ru/handle/20.500.12258/13670
work_keys_str_mv	AT demidovop ageneralmethodforthesynthesisofheterocyclicdithiocarboxylatebetainespotentialprecursorsofnhcbasedonanoveltypeoffunctionalizationofthemethylgroup AT demidovop ageneralmethodforthesynthesisofheterocyclicdithiocarboxylatebetainespotentialprecursorsofnhcbasedonanoveltypeoffunctionalizationofthemethylgroup AT demidovop generalmethodforthesynthesisofheterocyclicdithiocarboxylatebetainespotentialprecursorsofnhcbasedonanoveltypeoffunctionalizationofthemethylgroup AT demidovop generalmethodforthesynthesisofheterocyclicdithiocarboxylatebetainespotentialprecursorsofnhcbasedonanoveltypeoffunctionalizationofthemethylgroup
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A general method for the synthesis of heterocyclic dithiocarboxylate betaines: potential precursors of NHC based on a novel type of functionalization of the methyl group

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