Structure and properties of europium (III) triaquatriglycinate chloride

Coordination compound of Eu(III) with glycine (Gly) with the composition EuCl3·3Gly·3H2O is synthesized. The obtained XRD data testify that the coordination compound is characterized by a bidentate coordination of glycine via the carboxyl group without the participation of the amino group. The struc...

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Главные авторы:	Aksenov, N. A., Аксенов, Н. А.
Формат:	Статья
Язык:	English
Опубликовано:	Pleiades journals 2020
Темы:	Europium(III) Glycine IR spectroscopy Luminescence spectroscopy Thermogravimetry XRD
Online-ссылка:	https://dspace.ncfu.ru/handle/20.500.12258/14295
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spelling	ir-20.500.12258-142952025-02-13T10:58:37Z Structure and properties of europium (III) triaquatriglycinate chloride Aksenov, N. A. Аксенов, Н. А. Europium(III) Glycine IR spectroscopy Luminescence spectroscopy Thermogravimetry XRD Coordination compound of Eu(III) with glycine (Gly) with the composition EuCl3·3Gly·3H2O is synthesized. The obtained XRD data testify that the coordination compound is characterized by a bidentate coordination of glycine via the carboxyl group without the participation of the amino group. The structure is composed of polymer chains where two of three coordinating carboxyl groups are bridging groups connecting neighboring europium(III) atoms. The polymer chains are arranged in the form of parallel layers containing outer-sphere chlorine atoms between them. The structural formula [Eu(Gly)3(H2O)3]Cl3 of the complex is determined from XRD data which agree with IR spectroscopy, elemental and thermal analysis, and luminescence spectroscopy data 2020-10-06T14:26:57Z 2020-10-06T14:26:57Z 2020 Статья Panyushkin, V.T., Khasaeva, S.S., Bukov, N.N., Volynkin, V.A., Aksenov, N.A. STRUCTURE AND PROPERTIES OF EUROPIUM(III) TRIAQUATRIGLYCINATE CHLORIDE // Journal of Structural Chemistry. - 2020. - Volume 61. - Issue 8. - Pages 1203-1210 http://hdl.handle.net/20.500.12258/14295 en Journal of Structural Chemistry application/pdf application/pdf Pleiades journals
institution	СКФУ
collection	Репозиторий
language	English
topic	Europium(III) Glycine IR spectroscopy Luminescence spectroscopy Thermogravimetry XRD
spellingShingle	Europium(III) Glycine IR spectroscopy Luminescence spectroscopy Thermogravimetry XRD Aksenov, N. A. Аксенов, Н. А. Structure and properties of europium (III) triaquatriglycinate chloride
description	Coordination compound of Eu(III) with glycine (Gly) with the composition EuCl3·3Gly·3H2O is synthesized. The obtained XRD data testify that the coordination compound is characterized by a bidentate coordination of glycine via the carboxyl group without the participation of the amino group. The structure is composed of polymer chains where two of three coordinating carboxyl groups are bridging groups connecting neighboring europium(III) atoms. The polymer chains are arranged in the form of parallel layers containing outer-sphere chlorine atoms between them. The structural formula [Eu(Gly)3(H2O)3]Cl3 of the complex is determined from XRD data which agree with IR spectroscopy, elemental and thermal analysis, and luminescence spectroscopy data
format	Статья
author	Aksenov, N. A. Аксенов, Н. А.
author_facet	Aksenov, N. A. Аксенов, Н. А.
author_sort	Aksenov, N. A.
title	Structure and properties of europium (III) triaquatriglycinate chloride
title_short	Structure and properties of europium (III) triaquatriglycinate chloride
title_full	Structure and properties of europium (III) triaquatriglycinate chloride
title_fullStr	Structure and properties of europium (III) triaquatriglycinate chloride
title_full_unstemmed	Structure and properties of europium (III) triaquatriglycinate chloride
title_sort	structure and properties of europium (iii) triaquatriglycinate chloride
publisher	Pleiades journals
publishDate	2020
url	https://dspace.ncfu.ru/handle/20.500.12258/14295
work_keys_str_mv	AT aksenovna structureandpropertiesofeuropiumiiitriaquatriglycinatechloride AT aksenovna structureandpropertiesofeuropiumiiitriaquatriglycinatechloride
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Structure and properties of europium (III) triaquatriglycinate chloride

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