Formal [3+3] cycloaddition reaction of 4-hydroxythiocoumarin to 4Н-chromene-3-carbaldehydes: synthesis of thiochromeno[3',4':5,6]pyrano[2,3-b]chromen-6-ones
A cascade reaction of 4-hydroxythiocoumarin and 4Н-chromene-3-carbaldehydes was developed, consisting of Knoevenagel condensation and oxa-6π electrocyclization in the presence of ammonium acetate as catalyst. A series of polycyclic acetals containing a fused thiocoumarin moiety were obtained
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| Main Authors: | , |
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| Format: | Статья |
| Language: | English |
| Published: |
Springer
2020
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| Subjects: | |
| Online Access: | https://dspace.ncfu.ru/handle/20.500.12258/14619 |
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| Summary: | A cascade reaction of 4-hydroxythiocoumarin and 4Н-chromene-3-carbaldehydes was developed, consisting of Knoevenagel condensation and oxa-6π electrocyclization in the presence of ammonium acetate as catalyst. A series of polycyclic acetals containing a fused thiocoumarin moiety were obtained |
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