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Formal [3+3] cycloaddition reaction of 4-hydroxythiocoumarin to 4Н-chromene-3-carbaldehydes: synthesis of thiochromeno[3',4':5,6]pyrano[2,3-b]chromen-6-ones

A cascade reaction of 4-hydroxythiocoumarin and 4Н-chromene-3-carbaldehydes was developed, consisting of Knoevenagel condensation and oxa-6π electrocyclization in the presence of ammonium acetate as catalyst. A series of polycyclic acetals containing a fused thiocoumarin moiety were obtained

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Príomhchruthaitheoirí: Demidov, O. P., Демидов, О. П.
Formáid: Статья
Teanga:English
Foilsithe / Cruthaithe: Springer 2020
Ábhair:
Rochtain ar líne:https://dspace.ncfu.ru/handle/20.500.12258/14619
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Achoimre:A cascade reaction of 4-hydroxythiocoumarin and 4Н-chromene-3-carbaldehydes was developed, consisting of Knoevenagel condensation and oxa-6π electrocyclization in the presence of ammonium acetate as catalyst. A series of polycyclic acetals containing a fused thiocoumarin moiety were obtained