Synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates
The sequential reaction of furfural with cyclic secondary amines and further with benzaldehyde and cyanoacetates affords new 2,4-dicyano-8-(R2N)-6-oxo-3-phenylbicyclo[3.2.1]-octane-2,4-dicarboxylates as rac-(1R,2R,3R,4S,5S,8R)-diastereomers. The structures of the reaction products were determined by...
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2020
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ir-20.500.12258-146362020-11-26T11:38:08Z Synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates Dotsenko, V. V. Доценко, В. В. Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В. Aza-Piancatelli rearrangement Bicyclo[3.2.1]octane Cyanoacetates Furfural Nazarov reaction Stenhouse salts X-ray analysis The sequential reaction of furfural with cyclic secondary amines and further with benzaldehyde and cyanoacetates affords new 2,4-dicyano-8-(R2N)-6-oxo-3-phenylbicyclo[3.2.1]-octane-2,4-dicarboxylates as rac-(1R,2R,3R,4S,5S,8R)-diastereomers. The structures of the reaction products were determined by X-ray diffraction 2020-11-25T09:05:10Z 2020-11-25T09:05:10Z 2020 Статья Ismiyev, A.I., Dotsenko, V.V., Aksenov, N.A., Aksenova, I.V., Magerramov, A.M. Synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates // Russian Chemical Bulletin. - 2020. - Volume 69. - Issue 10. - Pages 1938-1943 http://hdl.handle.net/20.500.12258/14636 en Russian Chemical Bulletin application/pdf application/pdf Springer |
institution |
СКФУ |
collection |
Репозиторий |
language |
English |
topic |
Aza-Piancatelli rearrangement Bicyclo[3.2.1]octane Cyanoacetates Furfural Nazarov reaction Stenhouse salts X-ray analysis |
spellingShingle |
Aza-Piancatelli rearrangement Bicyclo[3.2.1]octane Cyanoacetates Furfural Nazarov reaction Stenhouse salts X-ray analysis Dotsenko, V. V. Доценко, В. В. Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В. Synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates |
description |
The sequential reaction of furfural with cyclic secondary amines and further with benzaldehyde and cyanoacetates affords new 2,4-dicyano-8-(R2N)-6-oxo-3-phenylbicyclo[3.2.1]-octane-2,4-dicarboxylates as rac-(1R,2R,3R,4S,5S,8R)-diastereomers. The structures of the reaction products were determined by X-ray diffraction |
format |
Статья |
author |
Dotsenko, V. V. Доценко, В. В. Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В. |
author_facet |
Dotsenko, V. V. Доценко, В. В. Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В. |
author_sort |
Dotsenko, V. V. |
title |
Synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates |
title_short |
Synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates |
title_full |
Synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates |
title_fullStr |
Synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates |
title_full_unstemmed |
Synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates |
title_sort |
synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates |
publisher |
Springer |
publishDate |
2020 |
url |
https://dspace.ncfu.ru/handle/20.500.12258/14636 |
work_keys_str_mv |
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