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Synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates

The sequential reaction of furfural with cyclic secondary amines and further with benzaldehyde and cyanoacetates affords new 2,4-dicyano-8-(R2N)-6-oxo-3-phenylbicyclo[3.2.1]-octane-2,4-dicarboxylates as rac-(1R,2R,3R,4S,5S,8R)-diastereomers. The structures of the reaction products were determined by...

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Главные авторы: Dotsenko, V. V., Доценко, В. В., Aksenov, N. A., Аксенов, Н. А., Aksenova, I. V., Аксенова, И. В.
格式: Статья
語言:English
出版: Springer 2020
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在線閱讀:https://dspace.ncfu.ru/handle/20.500.12258/14636
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spelling ir-20.500.12258-146362020-11-26T11:38:08Z Synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates Dotsenko, V. V. Доценко, В. В. Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В. Aza-Piancatelli rearrangement Bicyclo[3.2.1]octane Cyanoacetates Furfural Nazarov reaction Stenhouse salts X-ray analysis The sequential reaction of furfural with cyclic secondary amines and further with benzaldehyde and cyanoacetates affords new 2,4-dicyano-8-(R2N)-6-oxo-3-phenylbicyclo[3.2.1]-octane-2,4-dicarboxylates as rac-(1R,2R,3R,4S,5S,8R)-diastereomers. The structures of the reaction products were determined by X-ray diffraction 2020-11-25T09:05:10Z 2020-11-25T09:05:10Z 2020 Статья Ismiyev, A.I., Dotsenko, V.V., Aksenov, N.A., Aksenova, I.V., Magerramov, A.M. Synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates // Russian Chemical Bulletin. - 2020. - Volume 69. - Issue 10. - Pages 1938-1943 http://hdl.handle.net/20.500.12258/14636 en Russian Chemical Bulletin application/pdf application/pdf Springer
institution СКФУ
collection Репозиторий
language English
topic Aza-Piancatelli rearrangement
Bicyclo[3.2.1]octane
Cyanoacetates
Furfural
Nazarov reaction
Stenhouse salts
X-ray analysis
spellingShingle Aza-Piancatelli rearrangement
Bicyclo[3.2.1]octane
Cyanoacetates
Furfural
Nazarov reaction
Stenhouse salts
X-ray analysis
Dotsenko, V. V.
Доценко, В. В.
Aksenov, N. A.
Аксенов, Н. А.
Aksenova, I. V.
Аксенова, И. В.
Synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates
description The sequential reaction of furfural with cyclic secondary amines and further with benzaldehyde and cyanoacetates affords new 2,4-dicyano-8-(R2N)-6-oxo-3-phenylbicyclo[3.2.1]-octane-2,4-dicarboxylates as rac-(1R,2R,3R,4S,5S,8R)-diastereomers. The structures of the reaction products were determined by X-ray diffraction
format Статья
author Dotsenko, V. V.
Доценко, В. В.
Aksenov, N. A.
Аксенов, Н. А.
Aksenova, I. V.
Аксенова, И. В.
author_facet Dotsenko, V. V.
Доценко, В. В.
Aksenov, N. A.
Аксенов, Н. А.
Aksenova, I. V.
Аксенова, И. В.
author_sort Dotsenko, V. V.
title Synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates
title_short Synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates
title_full Synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates
title_fullStr Synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates
title_full_unstemmed Synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates
title_sort synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates
publisher Springer
publishDate 2020
url https://dspace.ncfu.ru/handle/20.500.12258/14636
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