Temperature dependences of the magnetic susceptibility of water-based magnetic fluids
This paper presents the results of a study of the temperature dependences of the magnetic susceptibility of water-based magnetic fluids (magnetic colloids) with magnetite particles stabilized by their electrostatic interaction. The average size of dispersed particles was 8 nm, and the volume concent...
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2021
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ir-20.500.12258-148252021-01-25T12:26:15Z Temperature dependences of the magnetic susceptibility of water-based magnetic fluids Dikansky, Y. I. Диканский, Ю. И. Ispiryan, A. G. Испирян, А. Г. Kunikin, S. A. Куникин, С. А. Magnetic fluid Phase transition Magnetic susceptibility Superparamagnetism This paper presents the results of a study of the temperature dependences of the magnetic susceptibility of water-based magnetic fluids (magnetic colloids) with magnetite particles stabilized by their electrostatic interaction. The average size of dispersed particles was 8 nm, and the volume concentration of particles in the selected samples under study was 1.4% and 1.6%. The investigations were carried out over a wide temperature range. The temperature dependence of the susceptibility, for the first time, was obtained in the region of the colloidal phase transition under supercooling of the dispersion medium (water). Significant differences were found between the temperature dependences of the magnetic susceptibility of such magnetic fluids, where as similar dependences have been found for the susceptibility of magnetic hydrocarbon-based fluids. The observed behavior of such dependences near the water phase transition temperature is determined by the changes in the water phase state, heat release and structuring of the colloid as a result of water crystallization. Moreover, it is suggested that a certain impact on the dependence behavior in the region of the colloidal solidification temperature can also come from the process of blocking the Brownian degrees of freedom of a small fraction of large dispersed particles. It is concluded that the observed maxima in the investigated susceptibility temperature dependences in the lower temperature region are due to magnetic transformations in the colloidal zones formed at the solidification front of the disperse medium with a dense packing of single-domain colloidal particles 2021-01-25T12:24:58Z 2021-01-25T12:24:58Z 2020 Статья Dikansky, YI; Ispiryan, AG; Kunikin, SA; Zakharzhevskii, M; Drozdov, AS. Temperature dependences of the magnetic susceptibility of water-based magnetic fluids. - 2020. - JOURNAL OF NANOFLUIDS. - Том: 9. - Выпуск: 2. - Стр.: 90-97 http://hdl.handle.net/20.500.12258/14825 en JOURNAL OF NANOFLUIDS application/pdf AMER SCIENTIFIC PUBLISHERS |
institution |
СКФУ |
collection |
Репозиторий |
language |
English |
topic |
Magnetic fluid Phase transition Magnetic susceptibility Superparamagnetism |
spellingShingle |
Magnetic fluid Phase transition Magnetic susceptibility Superparamagnetism Dikansky, Y. I. Диканский, Ю. И. Ispiryan, A. G. Испирян, А. Г. Kunikin, S. A. Куникин, С. А. Temperature dependences of the magnetic susceptibility of water-based magnetic fluids |
description |
This paper presents the results of a study of the temperature dependences of the magnetic susceptibility of water-based magnetic fluids (magnetic colloids) with magnetite particles stabilized by their electrostatic interaction. The average size of dispersed particles was 8 nm, and the volume concentration of particles in the selected samples under study was 1.4% and 1.6%. The investigations were carried out over a wide temperature range. The temperature dependence of the susceptibility, for the first time, was obtained in the region of the colloidal phase transition under supercooling of the dispersion medium (water). Significant differences were found between the temperature dependences of the magnetic susceptibility of such magnetic fluids, where as similar dependences have been found for the susceptibility of magnetic hydrocarbon-based fluids. The observed behavior of such dependences near the water phase transition temperature is determined by the changes in the water phase state, heat release and structuring of the colloid as a result of water crystallization. Moreover, it is suggested that a certain impact on the dependence behavior in the region of the colloidal solidification temperature can also come from the process of blocking the Brownian degrees of freedom of a small fraction of large dispersed particles. It is concluded that the observed maxima in the investigated susceptibility temperature dependences in the lower temperature region are due to magnetic transformations in the colloidal zones formed at the solidification front of the disperse medium with a dense packing of single-domain colloidal particles |
format |
Статья |
author |
Dikansky, Y. I. Диканский, Ю. И. Ispiryan, A. G. Испирян, А. Г. Kunikin, S. A. Куникин, С. А. |
author_facet |
Dikansky, Y. I. Диканский, Ю. И. Ispiryan, A. G. Испирян, А. Г. Kunikin, S. A. Куникин, С. А. |
author_sort |
Dikansky, Y. I. |
title |
Temperature dependences of the magnetic susceptibility of water-based magnetic fluids |
title_short |
Temperature dependences of the magnetic susceptibility of water-based magnetic fluids |
title_full |
Temperature dependences of the magnetic susceptibility of water-based magnetic fluids |
title_fullStr |
Temperature dependences of the magnetic susceptibility of water-based magnetic fluids |
title_full_unstemmed |
Temperature dependences of the magnetic susceptibility of water-based magnetic fluids |
title_sort |
temperature dependences of the magnetic susceptibility of water-based magnetic fluids |
publisher |
AMER SCIENTIFIC PUBLISHERS |
publishDate |
2021 |
url |
https://dspace.ncfu.ru/handle/20.500.12258/14825 |
work_keys_str_mv |
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