Synthesis and Structure of (2E)-3-Aryl(hetaryl)-2-[5-bromo-4-aryl(hetaryl)-1,3-thiazol-2-yl]acrylonitriles

Bromination of (2E)-3-aryl(hetaryl)-2-[4-aryl(hetaryl)-1,3-thiazol-2-yl]acrylonitriles proceeds regioselectively at the C5 atom of the thiazole ring with the formation of new (2E)-3-aryl(hetaryl)-2-[5-bromo-4-aryl(hetaryl)-1,3-thiazol-2-yl]acrylonitriles. The latter were alternatively obtained by th...

Полное описание

Сохранить в:

Библиографические подробности
Главные авторы:	Dotsenko, V. V., Доценко, В. В., Aksenov, N. A., Аксенов, Н. А., Aksenova, I. V., Аксенова, И. В.
Формат:	Статья
Язык:	English
Опубликовано:	Pleiades journals 2021
Темы:	Bromination Cyanothioacetamide 1,3-thiazoles 2-cyanothioacrylamides 5-bromo-1,3-thiazoles
Online-ссылка:	https://dspace.ncfu.ru/handle/20.500.12258/15867
Метки:	Добавить метку Нет меток, Требуется 1-ая метка записи!

id	ir-20.500.12258-15867
record_format	dspace
spelling	ir-20.500.12258-158672025-02-13T11:27:18Z Synthesis and Structure of (2E)-3-Aryl(hetaryl)-2-[5-bromo-4-aryl(hetaryl)-1,3-thiazol-2-yl]acrylonitriles Dotsenko, V. V. Доценко, В. В. Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В. Bromination Cyanothioacetamide 1,3-thiazoles 2-cyanothioacrylamides 5-bromo-1,3-thiazoles Bromination of (2E)-3-aryl(hetaryl)-2-[4-aryl(hetaryl)-1,3-thiazol-2-yl]acrylonitriles proceeds regioselectively at the C5 atom of the thiazole ring with the formation of new (2E)-3-aryl(hetaryl)-2-[5-bromo-4-aryl(hetaryl)-1,3-thiazol-2-yl]acrylonitriles. The latter were alternatively obtained by the reaction of aldehydes, cyanothioacetamide, α-bromoketones and bromine in the presence of triethylamine in DMF. Structure of the key compounds was confirmed using 2D NMR spectroscopy and single crystal X-ray diffraction analysis 2021-05-13T12:28:55Z 2021-05-13T12:28:55Z 2021 Статья Pakholka N.A., Abramenko V.L., Dotsenko V.V., Aksenov N.A., Aksenova I.V., Krivokolysko S.G. Synthesis and Structure of (2E)-3-Aryl(hetaryl)-2-[5-bromo-4-aryl(hetaryl)-1,3-thiazol-2-yl]acrylonitriles // Russian Journal of General Chemistry. - 2021. - Том 91. - Выпуск 3. - Pages 357 - 368 http://hdl.handle.net/20.500.12258/15867 en Russian Journal of General Chemistry application/pdf application/pdf Pleiades journals
institution	СКФУ
collection	Репозиторий
language	English
topic	Bromination Cyanothioacetamide 1,3-thiazoles 2-cyanothioacrylamides 5-bromo-1,3-thiazoles
spellingShingle	Bromination Cyanothioacetamide 1,3-thiazoles 2-cyanothioacrylamides 5-bromo-1,3-thiazoles Dotsenko, V. V. Доценко, В. В. Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В. Synthesis and Structure of (2E)-3-Aryl(hetaryl)-2-[5-bromo-4-aryl(hetaryl)-1,3-thiazol-2-yl]acrylonitriles
description	Bromination of (2E)-3-aryl(hetaryl)-2-[4-aryl(hetaryl)-1,3-thiazol-2-yl]acrylonitriles proceeds regioselectively at the C5 atom of the thiazole ring with the formation of new (2E)-3-aryl(hetaryl)-2-[5-bromo-4-aryl(hetaryl)-1,3-thiazol-2-yl]acrylonitriles. The latter were alternatively obtained by the reaction of aldehydes, cyanothioacetamide, α-bromoketones and bromine in the presence of triethylamine in DMF. Structure of the key compounds was confirmed using 2D NMR spectroscopy and single crystal X-ray diffraction analysis
format	Статья
author	Dotsenko, V. V. Доценко, В. В. Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В.
author_facet	Dotsenko, V. V. Доценко, В. В. Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В.
author_sort	Dotsenko, V. V.
title	Synthesis and Structure of (2E)-3-Aryl(hetaryl)-2-[5-bromo-4-aryl(hetaryl)-1,3-thiazol-2-yl]acrylonitriles
title_short	Synthesis and Structure of (2E)-3-Aryl(hetaryl)-2-[5-bromo-4-aryl(hetaryl)-1,3-thiazol-2-yl]acrylonitriles
title_full	Synthesis and Structure of (2E)-3-Aryl(hetaryl)-2-[5-bromo-4-aryl(hetaryl)-1,3-thiazol-2-yl]acrylonitriles
title_fullStr	Synthesis and Structure of (2E)-3-Aryl(hetaryl)-2-[5-bromo-4-aryl(hetaryl)-1,3-thiazol-2-yl]acrylonitriles
title_full_unstemmed	Synthesis and Structure of (2E)-3-Aryl(hetaryl)-2-[5-bromo-4-aryl(hetaryl)-1,3-thiazol-2-yl]acrylonitriles
title_sort	synthesis and structure of (2e)-3-aryl(hetaryl)-2-[5-bromo-4-aryl(hetaryl)-1,3-thiazol-2-yl]acrylonitriles
publisher	Pleiades journals
publishDate	2021
url	https://dspace.ncfu.ru/handle/20.500.12258/15867
work_keys_str_mv	AT dotsenkovv synthesisandstructureof2e3arylhetaryl25bromo4arylhetaryl13thiazol2ylacrylonitriles AT docenkovv synthesisandstructureof2e3arylhetaryl25bromo4arylhetaryl13thiazol2ylacrylonitriles AT aksenovna synthesisandstructureof2e3arylhetaryl25bromo4arylhetaryl13thiazol2ylacrylonitriles AT aksenovna synthesisandstructureof2e3arylhetaryl25bromo4arylhetaryl13thiazol2ylacrylonitriles AT aksenovaiv synthesisandstructureof2e3arylhetaryl25bromo4arylhetaryl13thiazol2ylacrylonitriles AT aksenovaiv synthesisandstructureof2e3arylhetaryl25bromo4arylhetaryl13thiazol2ylacrylonitriles
_version_	1842245705621569536

Synthesis and Structure of (2E)-3-Aryl(hetaryl)-2-[5-bromo-4-aryl(hetaryl)-1,3-thiazol-2-yl]acrylonitriles

Схожие документы