Electrochemical dehydrogenative C(sp2)−H amination

A transition-metal-free direct electrolytic C−H amination involving an electrochemically generated nitrenium ion intermediate has been developed. The electrosynthesis takes place in the absence of any organoiodine catalysts and is enabled by an in situ generated electrolyte. A novel, efficient intra...

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Autores principales:	Khamraev, V. F., Хамраев, В. Ф.
Formato:	Статья
Lenguaje:	English
Publicado:	John Wiley and Sons Inc 2021
Materias:	Amination Heterocycles Electrochemistry Carbazole Nitrenium ion
Acceso en línea:	https://dspace.ncfu.ru/handle/20.500.12258/15944
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id	ir-20.500.12258-15944
record_format	dspace
spelling	ir-20.500.12258-159442021-06-07T12:26:34Z Electrochemical dehydrogenative C(sp2)−H amination Khamraev, V. F. Хамраев, В. Ф. Amination Heterocycles Electrochemistry Carbazole Nitrenium ion A transition-metal-free direct electrolytic C−H amination involving an electrochemically generated nitrenium ion intermediate has been developed. The electrosynthesis takes place in the absence of any organoiodine catalysts and is enabled by an in situ generated electrolyte. A novel, efficient intramolecular and intermolecular C−H amination has been demonstrated using a simple reaction setup 2021-05-31T12:46:25Z 2021-05-31T12:46:25Z 2021 Статья Puthanveedu M., Khamraev V., Brieger L., Strohmann C., Antonchick A.P. Electrochemical dehydrogenative C(sp2)−H amination // Chemistry - A European Journal. - 2021 http://hdl.handle.net/20.500.12258/15944 en Chemistry - A European Journal application/pdf application/pdf John Wiley and Sons Inc
institution	СКФУ
collection	Репозиторий
language	English
topic	Amination Heterocycles Electrochemistry Carbazole Nitrenium ion
spellingShingle	Amination Heterocycles Electrochemistry Carbazole Nitrenium ion Khamraev, V. F. Хамраев, В. Ф. Electrochemical dehydrogenative C(sp2)−H amination
description	A transition-metal-free direct electrolytic C−H amination involving an electrochemically generated nitrenium ion intermediate has been developed. The electrosynthesis takes place in the absence of any organoiodine catalysts and is enabled by an in situ generated electrolyte. A novel, efficient intramolecular and intermolecular C−H amination has been demonstrated using a simple reaction setup
format	Статья
author	Khamraev, V. F. Хамраев, В. Ф.
author_facet	Khamraev, V. F. Хамраев, В. Ф.
author_sort	Khamraev, V. F.
title	Electrochemical dehydrogenative C(sp2)−H amination
title_short	Electrochemical dehydrogenative C(sp2)−H amination
title_full	Electrochemical dehydrogenative C(sp2)−H amination
title_fullStr	Electrochemical dehydrogenative C(sp2)−H amination
title_full_unstemmed	Electrochemical dehydrogenative C(sp2)−H amination
title_sort	electrochemical dehydrogenative c(sp2)−h amination
publisher	John Wiley and Sons Inc
publishDate	2021
url	https://dspace.ncfu.ru/handle/20.500.12258/15944
work_keys_str_mv	AT khamraevvf electrochemicaldehydrogenativecsp2hamination AT hamraevvf electrochemicaldehydrogenativecsp2hamination
_version_	1760601844721123328

Electrochemical dehydrogenative C(sp2)−H amination

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