Unusual oxidative dimerization in the 3-aminothieno[2,3- b]pyridine-2-carboxamide series
Noncatalyzed, regio- and stereoselective hypochlorite oxidation of 3-aminothieno[2,3-b]pyridine-2-carboxamides is presented. Unexpectedly, the oxidation proceeded by different mechanistic pathways, and different products were formed, depending on the nature of solvents used. A possible mechanism, th...
Сохранить в:
| Главные авторы: | , , , |
|---|---|
| Формат: | Статья |
| Язык: | English |
| Опубликовано: |
American Chemical Society
2021
|
| Online-ссылка: | https://dspace.ncfu.ru/handle/20.500.12258/16563 |
| Метки: |
Добавить метку
Нет меток, Требуется 1-ая метка записи!
|
| Краткое описание: | Noncatalyzed, regio- and stereoselective hypochlorite oxidation of 3-aminothieno[2,3-b]pyridine-2-carboxamides is presented. Unexpectedly, the oxidation proceeded by different mechanistic pathways, and different products were formed, depending on the nature of solvents used. A possible mechanism, the structure of products, kinetics and dynamics of intramolecular processes, and biological activity of products are discussed |
|---|