Unusual regioselective reaction of 2,6-dichloro-4-methylnicotinonitrile with malononitrile dimer

The reaction of 2,6-dichloro-4-methylnicotinonitrile with malononitrile dimer in the presence of triethylamine leads to regioselective nucleophilic substitution of the chlorine atom at position 6 with the formation of triethylammonium 2-amino-3-(6-chloro-5-cyano-4-methyl-pyridin-2-yl)-1,1,3-tricyano...

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Hauptverfasser:	Dotsenko, V. V., Доценко, В. В., Aksenov, N. A., Аксенов, Н. А., Aksenova, I. V., Аксенова, И. В.
Format:	Статья
Sprache:	English
Veröffentlicht:	Springer 2021
Schlagworte:	Nucleophilic substitution X-ray diffraction analysis Chloronicotinonitriles Malononitrile dimer
Online Zugang:	https://dspace.ncfu.ru/handle/20.500.12258/18059
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record_format	dspace
spelling	ir-20.500.12258-180592021-09-22T13:51:17Z Unusual regioselective reaction of 2,6-dichloro-4-methylnicotinonitrile with malononitrile dimer Dotsenko, V. V. Доценко, В. В. Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В. Nucleophilic substitution X-ray diffraction analysis Chloronicotinonitriles Malononitrile dimer The reaction of 2,6-dichloro-4-methylnicotinonitrile with malononitrile dimer in the presence of triethylamine leads to regioselective nucleophilic substitution of the chlorine atom at position 6 with the formation of triethylammonium 2-amino-3-(6-chloro-5-cyano-4-methyl-pyridin-2-yl)-1,1,3-tricyanoprop-2-en-1-ide. The structure of the product was confirmed by spectral methods and X-ray diffraction analysis 2021-09-01T12:44:14Z 2021-09-01T12:44:14Z 2021 Статья Dyadyuchenko, L.V.; Dotsenko, V. V.; Muraviev, V. S.; Dmitrieva, I. G.; Aksenov, N. A.; Aksenova, I. V. Unusual regioselective reaction of 2,6-dichloro-4-methylnicotinonitrile with malononitrile dimer // Russian Chemical Bulletin. - 2021. - Том 70. - Выпуск 7. - Стр.: 1363 - 1367 http://hdl.handle.net/20.500.12258/18059 en Russian Chemical Bulletin application/pdf application/pdf Springer
institution	СКФУ
collection	Репозиторий
language	English
topic	Nucleophilic substitution X-ray diffraction analysis Chloronicotinonitriles Malononitrile dimer
spellingShingle	Nucleophilic substitution X-ray diffraction analysis Chloronicotinonitriles Malononitrile dimer Dotsenko, V. V. Доценко, В. В. Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В. Unusual regioselective reaction of 2,6-dichloro-4-methylnicotinonitrile with malononitrile dimer
description	The reaction of 2,6-dichloro-4-methylnicotinonitrile with malononitrile dimer in the presence of triethylamine leads to regioselective nucleophilic substitution of the chlorine atom at position 6 with the formation of triethylammonium 2-amino-3-(6-chloro-5-cyano-4-methyl-pyridin-2-yl)-1,1,3-tricyanoprop-2-en-1-ide. The structure of the product was confirmed by spectral methods and X-ray diffraction analysis
format	Статья
author	Dotsenko, V. V. Доценко, В. В. Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В.
author_facet	Dotsenko, V. V. Доценко, В. В. Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В.
author_sort	Dotsenko, V. V.
title	Unusual regioselective reaction of 2,6-dichloro-4-methylnicotinonitrile with malononitrile dimer
title_short	Unusual regioselective reaction of 2,6-dichloro-4-methylnicotinonitrile with malononitrile dimer
title_full	Unusual regioselective reaction of 2,6-dichloro-4-methylnicotinonitrile with malononitrile dimer
title_fullStr	Unusual regioselective reaction of 2,6-dichloro-4-methylnicotinonitrile with malononitrile dimer
title_full_unstemmed	Unusual regioselective reaction of 2,6-dichloro-4-methylnicotinonitrile with malononitrile dimer
title_sort	unusual regioselective reaction of 2,6-dichloro-4-methylnicotinonitrile with malononitrile dimer
publisher	Springer
publishDate	2021
url	https://dspace.ncfu.ru/handle/20.500.12258/18059
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Unusual regioselective reaction of 2,6-dichloro-4-methylnicotinonitrile with malononitrile dimer

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