New methods of synthesis, structure and aminomethylation of 4-imino-2-(dicyanomethylene)-3-azaspiro[5.5]undecane-1,5-dicarbonitrile
Sequential reaction of cyclohexanone with malononitrile and2-aminopropene-1,1,3-tricarbonitrile in the presence of potassium hydroxide orsodium ethylate in ethanol gave4-imino-2-(dicyanomethylene)-3-azaspiro[5.5]undecane-1,5-dicarbonitrile. Thelatter reacted with primary amines and an excess of form...
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| Главные авторы: | , , , , , , , , , |
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| פורמט: | Статья |
| שפה: | English |
| יצא לאור: |
Pleiades journals
2021
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| נושאים: | |
| גישה מקוונת: | https://dspace.ncfu.ru/handle/20.500.12258/18061 |
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| סיכום: | Sequential reaction of cyclohexanone with malononitrile and2-aminopropene-1,1,3-tricarbonitrile in the presence of potassium hydroxide orsodium ethylate in ethanol gave4-imino-2-(dicyanomethylene)-3-azaspiro[5.5]undecane-1,5-dicarbonitrile. Thelatter reacted with primary amines and an excess of formaldehyde to form new2-(dicyanomethylene)-3,7-diazaspiro[bicyclo[3.3.1]non-3-ene-9,1′-cyclohexane]-1.5-dicarbonitrilederivatives. Contrary to the literature data, the reaction of cyclohexanone with2-aminopropene-1,1,3-tricarbonitrile in benzene in the presence of piperidineand glacial acetic acid led to the formation of2,4-diamino-5,6,7,8-tetrahydronaphthalene-1,3-dicarbonitrile |
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