1,3,7-triazapyrene-based ortho-carborane fluorophores: convenient synthesis, theoretical studies, and aggregation-induced emission properties
A convenient transition-metal-free approach, based on nucleophilic substitution of hydrogen (SNH), for consecutive regioselective C-H functionalization of 1,3,7-triazapyrene scaffolds with carboranyllithium and phenyllithium is reported. The theoretical calculations disclosed highlight key features...
Shranjeno v:
| Главные авторы: | , , , |
|---|---|
| Format: | Статья |
| Jezik: | English |
| Izdano: |
American Chemical Society
2021
|
| Teme: | |
| Online dostop: | https://dspace.ncfu.ru/handle/20.500.12258/18091 |
| Oznake: |
Označite
Brez oznak, prvi označite!
|
| Izvleček: | A convenient transition-metal-free approach, based on nucleophilic substitution of hydrogen (SNH), for consecutive regioselective C-H functionalization of 1,3,7-triazapyrene scaffolds with carboranyllithium and phenyllithium is reported. The theoretical calculations disclosed highlight key features in the regioselectivity and mechanism of the investigated SNH transformations. The novel 1,3,7-triazapyrene-based ortho-carboranes obtained have large potential in the field of molecular electronics as organic luminophores, which are characterized by the aggregation-induced emission and dual-emission effects |
|---|