1,3,7-triazapyrene-based ortho-carborane fluorophores: convenient synthesis, theoretical studies, and aggregation-induced emission properties

A convenient transition-metal-free approach, based on nucleophilic substitution of hydrogen (SNH), for consecutive regioselective C-H functionalization of 1,3,7-triazapyrene scaffolds with carboranyllithium and phenyllithium is reported. The theoretical calculations disclosed highlight key features...

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প্রধান লেখক:	Demidov, O. P., Демидов, О. П., Borovlev, I. V., Боровлев, И. В.
বিন্যাস:	Статья
ভাষা:	English
প্রকাশিত:	American Chemical Society 2021
বিষয়গুলি:	1,3,7-Triazapyrene-based ortho-carborane fluorophores Molecular electronics Organic luminophores
অনলাইন ব্যবহার করুন:	https://dspace.ncfu.ru/handle/20.500.12258/18091
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id	ir-20.500.12258-18091
record_format	dspace
spelling	ir-20.500.12258-180912021-09-10T12:35:14Z 1,3,7-triazapyrene-based ortho-carborane fluorophores: convenient synthesis, theoretical studies, and aggregation-induced emission properties Demidov, O. P. Демидов, О. П. Borovlev, I. V. Боровлев, И. В. 1,3,7-Triazapyrene-based ortho-carborane fluorophores Molecular electronics Organic luminophores A convenient transition-metal-free approach, based on nucleophilic substitution of hydrogen (SNH), for consecutive regioselective C-H functionalization of 1,3,7-triazapyrene scaffolds with carboranyllithium and phenyllithium is reported. The theoretical calculations disclosed highlight key features in the regioselectivity and mechanism of the investigated SNH transformations. The novel 1,3,7-triazapyrene-based ortho-carboranes obtained have large potential in the field of molecular electronics as organic luminophores, which are characterized by the aggregation-induced emission and dual-emission effects 2021-09-06T12:29:27Z 2021-09-06T12:29:27Z 2021 Статья Smyshliaeva, L. A.; Varaksin, M. V.; Fomina, E. I.; Medvedeva M. V.; Svalova T. S.; Kozitsina A. N.; Demidov, O. P.; Borovlev, I V .; Mensch C.; Mampuys P.; Maes B. U. W.; Charushin, V. N.; Chupakhin, O. N. 1,3,7-triazapyrene-based ortho-carborane fluorophores: convenient synthesis, theoretical studies, and aggregation-induced emission properties // Organometallics. - 2021. - Volume 40. - Issue 16. - Page 2792-2807 http://hdl.handle.net/20.500.12258/18091 en Organometallics application/pdf application/pdf American Chemical Society
institution	СКФУ
collection	Репозиторий
language	English
topic	1,3,7-Triazapyrene-based ortho-carborane fluorophores Molecular electronics Organic luminophores
spellingShingle	1,3,7-Triazapyrene-based ortho-carborane fluorophores Molecular electronics Organic luminophores Demidov, O. P. Демидов, О. П. Borovlev, I. V. Боровлев, И. В. 1,3,7-triazapyrene-based ortho-carborane fluorophores: convenient synthesis, theoretical studies, and aggregation-induced emission properties
description	A convenient transition-metal-free approach, based on nucleophilic substitution of hydrogen (SNH), for consecutive regioselective C-H functionalization of 1,3,7-triazapyrene scaffolds with carboranyllithium and phenyllithium is reported. The theoretical calculations disclosed highlight key features in the regioselectivity and mechanism of the investigated SNH transformations. The novel 1,3,7-triazapyrene-based ortho-carboranes obtained have large potential in the field of molecular electronics as organic luminophores, which are characterized by the aggregation-induced emission and dual-emission effects
format	Статья
author	Demidov, O. P. Демидов, О. П. Borovlev, I. V. Боровлев, И. В.
author_facet	Demidov, O. P. Демидов, О. П. Borovlev, I. V. Боровлев, И. В.
author_sort	Demidov, O. P.
title	1,3,7-triazapyrene-based ortho-carborane fluorophores: convenient synthesis, theoretical studies, and aggregation-induced emission properties
title_short	1,3,7-triazapyrene-based ortho-carborane fluorophores: convenient synthesis, theoretical studies, and aggregation-induced emission properties
title_full	1,3,7-triazapyrene-based ortho-carborane fluorophores: convenient synthesis, theoretical studies, and aggregation-induced emission properties
title_fullStr	1,3,7-triazapyrene-based ortho-carborane fluorophores: convenient synthesis, theoretical studies, and aggregation-induced emission properties
title_full_unstemmed	1,3,7-triazapyrene-based ortho-carborane fluorophores: convenient synthesis, theoretical studies, and aggregation-induced emission properties
title_sort	1,3,7-triazapyrene-based ortho-carborane fluorophores: convenient synthesis, theoretical studies, and aggregation-induced emission properties
publisher	American Chemical Society
publishDate	2021
url	https://dspace.ncfu.ru/handle/20.500.12258/18091
work_keys_str_mv	AT demidovop 137triazapyrenebasedorthocarboranefluorophoresconvenientsynthesistheoreticalstudiesandaggregationinducedemissionproperties AT demidovop 137triazapyrenebasedorthocarboranefluorophoresconvenientsynthesistheoreticalstudiesandaggregationinducedemissionproperties AT borovleviv 137triazapyrenebasedorthocarboranefluorophoresconvenientsynthesistheoreticalstudiesandaggregationinducedemissionproperties AT borovleviv 137triazapyrenebasedorthocarboranefluorophoresconvenientsynthesistheoreticalstudiesandaggregationinducedemissionproperties
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1,3,7-triazapyrene-based ortho-carborane fluorophores: convenient synthesis, theoretical studies, and aggregation-induced emission properties

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