Does electrophilic activation of nitroalkanes in polyphosphoric acid involve formation of nitrile oxides?

Does electrophilic activation of nitroalkanes in polyphosphoric acid involve formation of nitrile oxides?

The mechanistic rationale involving activation of nitroalkanes towards interaction with nucleophilic reagents in the presence of polyphosphoric acid (PPA) was re-evaluated. Could nitrile oxide moieties be formed during this process? This experiment demonstrates that at least in some cases this could...

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Главные авторы:	Aksenov, A. V., Аксенов, А. В., Aksenov, N. A., Аксенов, Н. А., Kirilov, N. K., Кирилов, Н. К., Skomorokhov, A. A., Скоморохов, А. А., Aksenov, D. A., Аксенов, Д. А., Kurenkov, I. A., Куренков, И. А., Rubin, M. A., Рубин, М. А.
Формат:	Статья
Язык:	English
Опубликовано:	ROYAL SOC CHEMISTRY 2021
Темы:	Nucleophilic-addition Michael addition Benzoxazoles Reactivity Catalyst
Online-ссылка:	https://dspace.ncfu.ru/handle/20.500.12258/18317
Метки:	Добавить метку Нет меток, Требуется 1-ая метка записи!

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