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Reactions of beta-carbonyl-substituted 4H-chromenes and 1H-benzo[f]chromenes with 5-aminopyrazoles

A method for the preparation of pyrazolo[1,5-a]pyrimidines containing a 2-hydroxybenzyl or (2-hydroxynaphthalen-1-yl)methyl group in position 6 based on the reaction of beta-carbonyl-substituted 4H-chromenes and their benzo analogs with 5-aminopyrazoles is proposed. A new type of ring-chain tautomer...

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Главные авторы: Demidov, O. P., Демидов, О. П.
Формат: Статья
Опубликовано: Springer 2021
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Online-ссылка:https://dspace.ncfu.ru/handle/20.500.12258/18459
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spelling ir-20.500.12258-184592025-02-05T07:42:24Z Reactions of beta-carbonyl-substituted 4H-chromenes and 1H-benzo[f]chromenes with 5-aminopyrazoles Demidov, O. P. Демидов, О. П. 5-amino-1H-pyrazoles 1H-benzo[f]chromene beta-carbonyl-substituted chromene 4H-chromene Pyrazolo[1,5-a]pyrimidines Aza-Michael reaction (3+3) cyclocondensation Tautomerism A method for the preparation of pyrazolo[1,5-a]pyrimidines containing a 2-hydroxybenzyl or (2-hydroxynaphthalen-1-yl)methyl group in position 6 based on the reaction of beta-carbonyl-substituted 4H-chromenes and their benzo analogs with 5-aminopyrazoles is proposed. A new type of ring-chain tautomerism with the participation of 7-(trifluoromethyl)pyrazolo[1,5-a]pyrimidines was discovered. 2021-11-30T11:24:24Z 2021-11-30T11:24:24Z 2021 Статья Osyanin, V. A., Osipov, D. V., Korzhenko, K. S., Demidov, O. P., Klimochkin, Y. N. Reactions of beta-carbonyl-substituted 4H-chromenes and 1H-benzo[f]chromenes with 5-aminopyrazoles // Chemistry of Heterocyclic Compounds. - 2021. - Том 57. - Выпуск 3. - Стр.: 305-313. - DOI10.1007/s10593-021-02908-4 http://hdl.handle.net/20.500.12258/18459 Chemistry of Heterocyclic Compounds application/pdf Springer
institution СКФУ
collection Репозиторий
topic 5-amino-1H-pyrazoles
1H-benzo[f]chromene
beta-carbonyl-substituted chromene
4H-chromene
Pyrazolo[1,5-a]pyrimidines
Aza-Michael reaction
(3+3) cyclocondensation
Tautomerism
spellingShingle 5-amino-1H-pyrazoles
1H-benzo[f]chromene
beta-carbonyl-substituted chromene
4H-chromene
Pyrazolo[1,5-a]pyrimidines
Aza-Michael reaction
(3+3) cyclocondensation
Tautomerism
Demidov, O. P.
Демидов, О. П.
Reactions of beta-carbonyl-substituted 4H-chromenes and 1H-benzo[f]chromenes with 5-aminopyrazoles
description A method for the preparation of pyrazolo[1,5-a]pyrimidines containing a 2-hydroxybenzyl or (2-hydroxynaphthalen-1-yl)methyl group in position 6 based on the reaction of beta-carbonyl-substituted 4H-chromenes and their benzo analogs with 5-aminopyrazoles is proposed. A new type of ring-chain tautomerism with the participation of 7-(trifluoromethyl)pyrazolo[1,5-a]pyrimidines was discovered.
format Статья
author Demidov, O. P.
Демидов, О. П.
author_facet Demidov, O. P.
Демидов, О. П.
author_sort Demidov, O. P.
title Reactions of beta-carbonyl-substituted 4H-chromenes and 1H-benzo[f]chromenes with 5-aminopyrazoles
title_short Reactions of beta-carbonyl-substituted 4H-chromenes and 1H-benzo[f]chromenes with 5-aminopyrazoles
title_full Reactions of beta-carbonyl-substituted 4H-chromenes and 1H-benzo[f]chromenes with 5-aminopyrazoles
title_fullStr Reactions of beta-carbonyl-substituted 4H-chromenes and 1H-benzo[f]chromenes with 5-aminopyrazoles
title_full_unstemmed Reactions of beta-carbonyl-substituted 4H-chromenes and 1H-benzo[f]chromenes with 5-aminopyrazoles
title_sort reactions of beta-carbonyl-substituted 4h-chromenes and 1h-benzo[f]chromenes with 5-aminopyrazoles
publisher Springer
publishDate 2021
url https://dspace.ncfu.ru/handle/20.500.12258/18459
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