Reactions of beta-carbonyl-substituted 4H-chromenes and 1H-benzo[f]chromenes with 5-aminopyrazoles
A method for the preparation of pyrazolo[1,5-a]pyrimidines containing a 2-hydroxybenzyl or (2-hydroxynaphthalen-1-yl)methyl group in position 6 based on the reaction of beta-carbonyl-substituted 4H-chromenes and their benzo analogs with 5-aminopyrazoles is proposed. A new type of ring-chain tautomer...
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2021
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ir-20.500.12258-184592025-02-05T07:42:24Z Reactions of beta-carbonyl-substituted 4H-chromenes and 1H-benzo[f]chromenes with 5-aminopyrazoles Demidov, O. P. Демидов, О. П. 5-amino-1H-pyrazoles 1H-benzo[f]chromene beta-carbonyl-substituted chromene 4H-chromene Pyrazolo[1,5-a]pyrimidines Aza-Michael reaction (3+3) cyclocondensation Tautomerism A method for the preparation of pyrazolo[1,5-a]pyrimidines containing a 2-hydroxybenzyl or (2-hydroxynaphthalen-1-yl)methyl group in position 6 based on the reaction of beta-carbonyl-substituted 4H-chromenes and their benzo analogs with 5-aminopyrazoles is proposed. A new type of ring-chain tautomerism with the participation of 7-(trifluoromethyl)pyrazolo[1,5-a]pyrimidines was discovered. 2021-11-30T11:24:24Z 2021-11-30T11:24:24Z 2021 Статья Osyanin, V. A., Osipov, D. V., Korzhenko, K. S., Demidov, O. P., Klimochkin, Y. N. Reactions of beta-carbonyl-substituted 4H-chromenes and 1H-benzo[f]chromenes with 5-aminopyrazoles // Chemistry of Heterocyclic Compounds. - 2021. - Том 57. - Выпуск 3. - Стр.: 305-313. - DOI10.1007/s10593-021-02908-4 http://hdl.handle.net/20.500.12258/18459 Chemistry of Heterocyclic Compounds application/pdf Springer |
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Репозиторий |
| topic |
5-amino-1H-pyrazoles 1H-benzo[f]chromene beta-carbonyl-substituted chromene 4H-chromene Pyrazolo[1,5-a]pyrimidines Aza-Michael reaction (3+3) cyclocondensation Tautomerism |
| spellingShingle |
5-amino-1H-pyrazoles 1H-benzo[f]chromene beta-carbonyl-substituted chromene 4H-chromene Pyrazolo[1,5-a]pyrimidines Aza-Michael reaction (3+3) cyclocondensation Tautomerism Demidov, O. P. Демидов, О. П. Reactions of beta-carbonyl-substituted 4H-chromenes and 1H-benzo[f]chromenes with 5-aminopyrazoles |
| description |
A method for the preparation of pyrazolo[1,5-a]pyrimidines containing a 2-hydroxybenzyl or (2-hydroxynaphthalen-1-yl)methyl group in position 6 based on the reaction of beta-carbonyl-substituted 4H-chromenes and their benzo analogs with 5-aminopyrazoles is proposed. A new type of ring-chain tautomerism with the participation of 7-(trifluoromethyl)pyrazolo[1,5-a]pyrimidines was discovered. |
| format |
Статья |
| author |
Demidov, O. P. Демидов, О. П. |
| author_facet |
Demidov, O. P. Демидов, О. П. |
| author_sort |
Demidov, O. P. |
| title |
Reactions of beta-carbonyl-substituted 4H-chromenes and 1H-benzo[f]chromenes with 5-aminopyrazoles |
| title_short |
Reactions of beta-carbonyl-substituted 4H-chromenes and 1H-benzo[f]chromenes with 5-aminopyrazoles |
| title_full |
Reactions of beta-carbonyl-substituted 4H-chromenes and 1H-benzo[f]chromenes with 5-aminopyrazoles |
| title_fullStr |
Reactions of beta-carbonyl-substituted 4H-chromenes and 1H-benzo[f]chromenes with 5-aminopyrazoles |
| title_full_unstemmed |
Reactions of beta-carbonyl-substituted 4H-chromenes and 1H-benzo[f]chromenes with 5-aminopyrazoles |
| title_sort |
reactions of beta-carbonyl-substituted 4h-chromenes and 1h-benzo[f]chromenes with 5-aminopyrazoles |
| publisher |
Springer |
| publishDate |
2021 |
| url |
https://dspace.ncfu.ru/handle/20.500.12258/18459 |
| work_keys_str_mv |
AT demidovop reactionsofbetacarbonylsubstituted4hchromenesand1hbenzofchromeneswith5aminopyrazoles AT demidovop reactionsofbetacarbonylsubstituted4hchromenesand1hbenzofchromeneswith5aminopyrazoles |
| _version_ |
1842245434702036992 |