One-Pot Synthesis of (E)-2-(3-Oxoindolin-2-Ylidene)-2-Arylacetonitriles
A highly efficient and expeditious one-pot approach towards 2-(3-oxoindolin-2-yl)acetonitriles was designed, which involves a base-assisted aldol reaction of ortho-nitroacetophenones, followed by hydrocyanation, triggering an unusual reductive cyclization reaction.
Сохранить в:
| Главные авторы: | , , , , , , , , , , , , , , , |
|---|---|
| Формат: | Статья |
| Язык: | English |
| Опубликовано: |
MDPI
2022
|
| Темы: | |
| Online-ссылка: | https://dspace.ncfu.ru/handle/20.500.12258/19606 |
| Метки: |
Добавить метку
Нет меток, Требуется 1-ая метка записи!
|
| id |
ir-20.500.12258-19606 |
|---|---|
| record_format |
dspace |
| spelling |
ir-20.500.12258-196062025-03-06T12:33:31Z One-Pot Synthesis of (E)-2-(3-Oxoindolin-2-Ylidene)-2-Arylacetonitriles Aksenov, N. A. Аксенов, Н. А. Aksenov, A. V. Аксенов, А. В. Kurenkov, I. A. Куренков, И. А. Kirilov, N. K. Кирилов, Н. К. Aksenov, D. A. Аксенов, Д. А. Arutiunov, N. A. Арутюнов, Н. А. Aksenova, D. S. Аксенова, Д. С. Rubin, M. A. Рубин, М. А. Brønsted acid catalysis Cascade transformations Indoles Nitroalkanes Rearrangements A highly efficient and expeditious one-pot approach towards 2-(3-oxoindolin-2-yl)acetonitriles was designed, which involves a base-assisted aldol reaction of ortho-nitroacetophenones, followed by hydrocyanation, triggering an unusual reductive cyclization reaction. 2022-05-25T07:08:58Z 2022-05-25T07:08:58Z 2022 Статья Aksenov, N. A., Aksenov, A. V., Kurenkov, I. A., Kirillov, N. K., Aksenov, D. A., Arutiunov, N. A., Aksenova, D. S., Rubin, M. One-Pot Synthesis of (E)-2-(3-Oxoindolin-2-Ylidene)-2-Arylacetonitriles // Molecules. - 2022. - Том 27. - Выпуск 9. - Номер статьи 2808. - DOI10.3390/molecules27092808 http://hdl.handle.net/20.500.12258/19606 en Molecules application/pdf application/pdf MDPI |
| institution |
СКФУ |
| collection |
Репозиторий |
| language |
English |
| topic |
Brønsted acid catalysis Cascade transformations Indoles Nitroalkanes Rearrangements |
| spellingShingle |
Brønsted acid catalysis Cascade transformations Indoles Nitroalkanes Rearrangements Aksenov, N. A. Аксенов, Н. А. Aksenov, A. V. Аксенов, А. В. Kurenkov, I. A. Куренков, И. А. Kirilov, N. K. Кирилов, Н. К. Aksenov, D. A. Аксенов, Д. А. Arutiunov, N. A. Арутюнов, Н. А. Aksenova, D. S. Аксенова, Д. С. Rubin, M. A. Рубин, М. А. One-Pot Synthesis of (E)-2-(3-Oxoindolin-2-Ylidene)-2-Arylacetonitriles |
| description |
A highly efficient and expeditious one-pot approach towards 2-(3-oxoindolin-2-yl)acetonitriles was designed, which involves a base-assisted aldol reaction of ortho-nitroacetophenones, followed by hydrocyanation, triggering an unusual reductive cyclization reaction. |
| format |
Статья |
| author |
Aksenov, N. A. Аксенов, Н. А. Aksenov, A. V. Аксенов, А. В. Kurenkov, I. A. Куренков, И. А. Kirilov, N. K. Кирилов, Н. К. Aksenov, D. A. Аксенов, Д. А. Arutiunov, N. A. Арутюнов, Н. А. Aksenova, D. S. Аксенова, Д. С. Rubin, M. A. Рубин, М. А. |
| author_facet |
Aksenov, N. A. Аксенов, Н. А. Aksenov, A. V. Аксенов, А. В. Kurenkov, I. A. Куренков, И. А. Kirilov, N. K. Кирилов, Н. К. Aksenov, D. A. Аксенов, Д. А. Arutiunov, N. A. Арутюнов, Н. А. Aksenova, D. S. Аксенова, Д. С. Rubin, M. A. Рубин, М. А. |
| author_sort |
Aksenov, N. A. |
| title |
One-Pot Synthesis of (E)-2-(3-Oxoindolin-2-Ylidene)-2-Arylacetonitriles |
| title_short |
One-Pot Synthesis of (E)-2-(3-Oxoindolin-2-Ylidene)-2-Arylacetonitriles |
| title_full |
One-Pot Synthesis of (E)-2-(3-Oxoindolin-2-Ylidene)-2-Arylacetonitriles |
| title_fullStr |
One-Pot Synthesis of (E)-2-(3-Oxoindolin-2-Ylidene)-2-Arylacetonitriles |
| title_full_unstemmed |
One-Pot Synthesis of (E)-2-(3-Oxoindolin-2-Ylidene)-2-Arylacetonitriles |
| title_sort |
one-pot synthesis of (e)-2-(3-oxoindolin-2-ylidene)-2-arylacetonitriles |
| publisher |
MDPI |
| publishDate |
2022 |
| url |
https://dspace.ncfu.ru/handle/20.500.12258/19606 |
| work_keys_str_mv |
AT aksenovna onepotsynthesisofe23oxoindolin2ylidene2arylacetonitriles AT aksenovna onepotsynthesisofe23oxoindolin2ylidene2arylacetonitriles AT aksenovav onepotsynthesisofe23oxoindolin2ylidene2arylacetonitriles AT aksenovav onepotsynthesisofe23oxoindolin2ylidene2arylacetonitriles AT kurenkovia onepotsynthesisofe23oxoindolin2ylidene2arylacetonitriles AT kurenkovia onepotsynthesisofe23oxoindolin2ylidene2arylacetonitriles AT kirilovnk onepotsynthesisofe23oxoindolin2ylidene2arylacetonitriles AT kirilovnk onepotsynthesisofe23oxoindolin2ylidene2arylacetonitriles AT aksenovda onepotsynthesisofe23oxoindolin2ylidene2arylacetonitriles AT aksenovda onepotsynthesisofe23oxoindolin2ylidene2arylacetonitriles AT arutiunovna onepotsynthesisofe23oxoindolin2ylidene2arylacetonitriles AT arutûnovna onepotsynthesisofe23oxoindolin2ylidene2arylacetonitriles AT aksenovads onepotsynthesisofe23oxoindolin2ylidene2arylacetonitriles AT aksenovads onepotsynthesisofe23oxoindolin2ylidene2arylacetonitriles AT rubinma onepotsynthesisofe23oxoindolin2ylidene2arylacetonitriles AT rubinma onepotsynthesisofe23oxoindolin2ylidene2arylacetonitriles |
| _version_ |
1842245755771813888 |