Opening of the furan ring of 3-Nitrobenzofurans by the action of carbonyl-stabilized sulfonium ylides

Opening of the furan ring of 3-Nitrobenzofurans by the action of carbonyl-stabilized sulfonium ylides

Upon treatment of 3-nitrobenzofurans with dimethylphenacylsulfonium salts in the presence of a base, the opening of the furan ring to form (E)-1-aryl-2-(dimethylsulfonio)-4-nitro-1-oxobut-3-en-2-ides takes place. The mechanism of nucleophilic dearomatization of 3-nitrobenzofurans involves consecutiv...

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Wedi'i Gadw mewn:

Manylion Llyfryddiaeth
Prif Awduron:	Demidov, O. P., Демидов, О. П.
Fformat:	Статья
Iaith:	English
Cyhoeddwyd:	Springer 2022
Pynciau:	3-nitrobenzofurans Dimethylphenacylsulfonium salts Michael reaction Nucleophilic dearomatization Sulfur ylides
Mynediad Ar-lein:	https://dspace.ncfu.ru/handle/20.500.12258/19744
Tagiau:	Ychwanegu Tag Dim Tagiau, Byddwch y cyntaf i dagio'r cofnod hwn!

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