Synthesis, Structures, and Properties of the Zn(II), Cu(II), Co(II), and Ni(II) Bis(chelate) Complexes Based on 2,4,9,11-Tetra-tert-butylbenzo[5,6][1,4]oxazino[2,3-b]phenoxazin-1-ol

A series of zinc, copper, cobalt, and nickel bis(chelate) complexes (I–IV) with 2,4,9,11-tetra-tert-butylbenzo[5,6][1,4]oxazino[2,3-b]phenoxazin-1-ol (LН) of the general formula ML2 is synthesized. The spatial and electronic structures of the synthesized coordination compounds are studied by the den...

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Bibliografische gegevens
Hoofdauteurs:	Demidov, O. P., Демидов, О. П.
Formaat:	Статья
Taal:	English
Gepubliceerd in:	Pleiades journals 2022
Onderwerpen:	Chelate complexes Density functional theory Heteropentacenes Transition metals
Online toegang:	https://dspace.ncfu.ru/handle/20.500.12258/19757
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id	ir-20.500.12258-19757
record_format	dspace
spelling	ir-20.500.12258-197572022-06-22T08:24:35Z Synthesis, Structures, and Properties of the Zn(II), Cu(II), Co(II), and Ni(II) Bis(chelate) Complexes Based on 2,4,9,11-Tetra-tert-butylbenzo[5,6][1,4]oxazino[2,3-b]phenoxazin-1-ol Demidov, O. P. Демидов, О. П. Chelate complexes Density functional theory Heteropentacenes Transition metals A series of zinc, copper, cobalt, and nickel bis(chelate) complexes (I–IV) with 2,4,9,11-tetra-tert-butylbenzo[5,6][1,4]oxazino[2,3-b]phenoxazin-1-ol (LН) of the general formula ML2 is synthesized. The spatial and electronic structures of the synthesized coordination compounds are studied by the density functional theory (DFT B3LYP/6-311++g(d,p)). The molecular structure of the adduct of the copper complex with pyridine (II·Py) is determined by X-ray diffraction (CIF file CCDC no. 2113818). The spectral characteristics of the ligand and related complexes are studied. 2022-06-22T08:24:00Z 2022-06-22T08:24:00Z 2022 Статья Chegerev, M. G., Demidov, O. P., Knyazev, P. A., Makarova, N. I., Starikov, A. G., Ivakhnenko, E. P., Minkin, V. I. Synthesis, Structures, and Properties of the Zn(II), Cu(II), Co(II), and Ni(II) Bis(chelate) Complexes Based on 2,4,9,11-Tetra-tert-butylbenzo[5,6][1,4]oxazino[2,3-b]phenoxazin-1-ol // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. - 2022. - Том 48. - Выпуск 5. - Стр.: 261 - 269. - DOI10.1134/S1070328422050037 http://hdl.handle.net/20.500.12258/19757 en Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya application/pdf Pleiades journals
institution	СКФУ
collection	Репозиторий
language	English
topic	Chelate complexes Density functional theory Heteropentacenes Transition metals
spellingShingle	Chelate complexes Density functional theory Heteropentacenes Transition metals Demidov, O. P. Демидов, О. П. Synthesis, Structures, and Properties of the Zn(II), Cu(II), Co(II), and Ni(II) Bis(chelate) Complexes Based on 2,4,9,11-Tetra-tert-butylbenzo[5,6][1,4]oxazino[2,3-b]phenoxazin-1-ol
description	A series of zinc, copper, cobalt, and nickel bis(chelate) complexes (I–IV) with 2,4,9,11-tetra-tert-butylbenzo[5,6][1,4]oxazino[2,3-b]phenoxazin-1-ol (LН) of the general formula ML2 is synthesized. The spatial and electronic structures of the synthesized coordination compounds are studied by the density functional theory (DFT B3LYP/6-311++g(d,p)). The molecular structure of the adduct of the copper complex with pyridine (II·Py) is determined by X-ray diffraction (CIF file CCDC no. 2113818). The spectral characteristics of the ligand and related complexes are studied.
format	Статья
author	Demidov, O. P. Демидов, О. П.
author_facet	Demidov, O. P. Демидов, О. П.
author_sort	Demidov, O. P.
title	Synthesis, Structures, and Properties of the Zn(II), Cu(II), Co(II), and Ni(II) Bis(chelate) Complexes Based on 2,4,9,11-Tetra-tert-butylbenzo[5,6][1,4]oxazino[2,3-b]phenoxazin-1-ol
title_short	Synthesis, Structures, and Properties of the Zn(II), Cu(II), Co(II), and Ni(II) Bis(chelate) Complexes Based on 2,4,9,11-Tetra-tert-butylbenzo[5,6][1,4]oxazino[2,3-b]phenoxazin-1-ol
title_full	Synthesis, Structures, and Properties of the Zn(II), Cu(II), Co(II), and Ni(II) Bis(chelate) Complexes Based on 2,4,9,11-Tetra-tert-butylbenzo[5,6][1,4]oxazino[2,3-b]phenoxazin-1-ol
title_fullStr	Synthesis, Structures, and Properties of the Zn(II), Cu(II), Co(II), and Ni(II) Bis(chelate) Complexes Based on 2,4,9,11-Tetra-tert-butylbenzo[5,6][1,4]oxazino[2,3-b]phenoxazin-1-ol
title_full_unstemmed	Synthesis, Structures, and Properties of the Zn(II), Cu(II), Co(II), and Ni(II) Bis(chelate) Complexes Based on 2,4,9,11-Tetra-tert-butylbenzo[5,6][1,4]oxazino[2,3-b]phenoxazin-1-ol
title_sort	synthesis, structures, and properties of the zn(ii), cu(ii), co(ii), and ni(ii) bis(chelate) complexes based on 2,4,9,11-tetra-tert-butylbenzo[5,6][1,4]oxazino[2,3-b]phenoxazin-1-ol
publisher	Pleiades journals
publishDate	2022
url	https://dspace.ncfu.ru/handle/20.500.12258/19757
work_keys_str_mv	AT demidovop synthesisstructuresandpropertiesofthezniicuiicoiiandniiibischelatecomplexesbasedon24911tetratertbutylbenzo5614oxazino23bphenoxazin1ol AT demidovop synthesisstructuresandpropertiesofthezniicuiicoiiandniiibischelatecomplexesbasedon24911tetratertbutylbenzo5614oxazino23bphenoxazin1ol
_version_	1760600026666500096

Synthesis, Structures, and Properties of the Zn(II), Cu(II), Co(II), and Ni(II) Bis(chelate) Complexes Based on 2,4,9,11-Tetra-tert-butylbenzo[5,6][1,4]oxazino[2,3-b]phenoxazin-1-ol

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