SNH Amidation of 5-Nitroisoquinoline: Access to Nitro- and Nitroso Derivatives of Amides and Ureas on the Basis of Isoquinoline

For the first time, amides and ureas based on both 5-nitroisoquinoline and 5-nitrosoisoquinoline were obtained by direct nucleophilic substitution of hydrogen in the 5-nitroisoquinoline molecule. In the case of urea and monosubstituted ureas, only 5-nitrosoisoquinoline-6-amine is formed under anhy...

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Autores principales:	Avakyan, E. K., Авакян, Е. К., Borovleva, A. A., Боровлева, А. А., Pobedinskaya, D. Y., Побединская, Д. Ю., Demidov, O. P., Демидов, О. П., Ermolenko, A. P., Ермоленко, А. П., Larin, A. N., Ларин, А. Н., Borovlev, I. V., Боровлев, И. В.
Formato:	Статья
Lenguaje:	English
Publicado:	2023
Materias:	Heterocycles SNH methodology Metal-free C–N bond formation 5-nitroisoquinoline Redox process Oxidative SNH amidation SNH dialkylcarbamoylamination Regioselectivity
Acceso en línea:	https://dspace.ncfu.ru/handle/20.500.12258/22264
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spelling	ir-20.500.12258-222642023-01-26T14:53:35Z SNH Amidation of 5-Nitroisoquinoline: Access to Nitro- and Nitroso Derivatives of Amides and Ureas on the Basis of Isoquinoline Avakyan, E. K. Авакян, Е. К. Borovleva, A. A. Боровлева, А. А. Pobedinskaya, D. Y. Побединская, Д. Ю. Demidov, O. P. Демидов, О. П. Ermolenko, A. P. Ермоленко, А. П. Larin, A. N. Ларин, А. Н. Borovlev, I. V. Боровлев, И. В. Heterocycles SNH methodology Metal-free C–N bond formation 5-nitroisoquinoline Redox process Oxidative SNH amidation SNH dialkylcarbamoylamination Regioselectivity For the first time, amides and ureas based on both 5-nitroisoquinoline and 5-nitrosoisoquinoline were obtained by direct nucleophilic substitution of hydrogen in the 5-nitroisoquinoline molecule. In the case of urea and monosubstituted ureas, only 5-nitrosoisoquinoline-6-amine is formed under anhy- drous conditions. 2023-01-26T14:52:14Z 2023-01-26T14:52:14Z 2022 Статья Avakyan, E.K., Borovleva, A.A., Pobedinskaya, D.Y., Demidov, O.P., Ermolenko, A.P., Larin, A.N., Borovlev, I.V. SNH Amidation of 5-Nitroisoquinoline: Access to Nitro- and Nitroso Derivatives of Amides and Ureas on the Basis of Isoquinoline // Molecules. - 2022. - 27 (22), статья № 7862. - DOI: 10.3390/molecules27227862 http://hdl.handle.net/20.500.12258/22264 en Molecules application/pdf application/pdf
institution	СКФУ
collection	Репозиторий
language	English
topic	Heterocycles SNH methodology Metal-free C–N bond formation 5-nitroisoquinoline Redox process Oxidative SNH amidation SNH dialkylcarbamoylamination Regioselectivity
spellingShingle	Heterocycles SNH methodology Metal-free C–N bond formation 5-nitroisoquinoline Redox process Oxidative SNH amidation SNH dialkylcarbamoylamination Regioselectivity Avakyan, E. K. Авакян, Е. К. Borovleva, A. A. Боровлева, А. А. Pobedinskaya, D. Y. Побединская, Д. Ю. Demidov, O. P. Демидов, О. П. Ermolenko, A. P. Ермоленко, А. П. Larin, A. N. Ларин, А. Н. Borovlev, I. V. Боровлев, И. В. SNH Amidation of 5-Nitroisoquinoline: Access to Nitro- and Nitroso Derivatives of Amides and Ureas on the Basis of Isoquinoline
description	For the first time, amides and ureas based on both 5-nitroisoquinoline and 5-nitrosoisoquinoline were obtained by direct nucleophilic substitution of hydrogen in the 5-nitroisoquinoline molecule. In the case of urea and monosubstituted ureas, only 5-nitrosoisoquinoline-6-amine is formed under anhy- drous conditions.
format	Статья
author	Avakyan, E. K. Авакян, Е. К. Borovleva, A. A. Боровлева, А. А. Pobedinskaya, D. Y. Побединская, Д. Ю. Demidov, O. P. Демидов, О. П. Ermolenko, A. P. Ермоленко, А. П. Larin, A. N. Ларин, А. Н. Borovlev, I. V. Боровлев, И. В.
author_facet	Avakyan, E. K. Авакян, Е. К. Borovleva, A. A. Боровлева, А. А. Pobedinskaya, D. Y. Побединская, Д. Ю. Demidov, O. P. Демидов, О. П. Ermolenko, A. P. Ермоленко, А. П. Larin, A. N. Ларин, А. Н. Borovlev, I. V. Боровлев, И. В.
author_sort	Avakyan, E. K.
title	SNH Amidation of 5-Nitroisoquinoline: Access to Nitro- and Nitroso Derivatives of Amides and Ureas on the Basis of Isoquinoline
title_short	SNH Amidation of 5-Nitroisoquinoline: Access to Nitro- and Nitroso Derivatives of Amides and Ureas on the Basis of Isoquinoline
title_full	SNH Amidation of 5-Nitroisoquinoline: Access to Nitro- and Nitroso Derivatives of Amides and Ureas on the Basis of Isoquinoline
title_fullStr	SNH Amidation of 5-Nitroisoquinoline: Access to Nitro- and Nitroso Derivatives of Amides and Ureas on the Basis of Isoquinoline
title_full_unstemmed	SNH Amidation of 5-Nitroisoquinoline: Access to Nitro- and Nitroso Derivatives of Amides and Ureas on the Basis of Isoquinoline
title_sort	snh amidation of 5-nitroisoquinoline: access to nitro- and nitroso derivatives of amides and ureas on the basis of isoquinoline
publishDate	2023
url	https://dspace.ncfu.ru/handle/20.500.12258/22264
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SNH Amidation of 5-Nitroisoquinoline: Access to Nitro- and Nitroso Derivatives of Amides and Ureas on the Basis of Isoquinoline

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