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SNH Amidation of 5-Nitroisoquinoline: Access to Nitro- and Nitroso Derivatives of Amides and Ureas on the Basis of Isoquinoline

SNH Amidation of 5-Nitroisoquinoline: Access to Nitro- and Nitroso Derivatives of Amides and Ureas on the Basis of Isoquinoline

For the first time, amides and ureas based on both 5-nitroisoquinoline and 5-nitrosoisoquinoline were obtained by direct nucleophilic substitution of hydrogen in the 5-nitroisoquinoline molecule. In the case of urea and monosubstituted ureas, only 5-nitrosoisoquinoline-6-amine is formed under anhy...

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Hlavní autoři: Avakyan, E. K., Авакян, Е. К., Borovleva, A. A., Боровлева, А. А., Pobedinskaya, D. Y., Побединская, Д. Ю., Demidov, O. P., Демидов, О. П., Ermolenko, A. P., Ермоленко, А. П., Larin, A. N., Ларин, А. Н., Borovlev, I. V., Боровлев, И. В.
Médium: Статья
Jazyk:English
Vydáno: 2023
Témata:
Heterocycles
SNH methodology
Metal-free C–N bond formation
5-nitroisoquinoline
Redox process
Oxidative SNH amidation
SNH dialkylcarbamoylamination
Regioselectivity
On-line přístup:https://dspace.ncfu.ru/handle/20.500.12258/22264
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https://dspace.ncfu.ru/handle/20.500.12258/22264

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