Electrochemical Oxidation of 3-Aryl-2-cyanothioacrylamides

Electrochemical oxidation of (Е)-3-aryl-2-cyanoprop-2-enethioamides in a undivided cell in the presence of KBr in an aqueous or aqueous-organic medium has led to the formation of (2Е,2′E)-2,2′-(1,2,4-thiadiazole-3,5-diyl)bis[3-arylacrylonitriles] in 37–76% yield. A plausible reaction mechanism has b...

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Главные авторы:	Dotsenko, V. V., Доценко, В. В., Strelkov, V. D., Стрелков, В. Д., Aksenov, N. A., Аксенов, Н. А., Aksenova, I. V., Аксенова, И. В.
Формат:	Статья
Язык:	Russian
Опубликовано:	2023
Темы:	Growth-regulating activity Antidote activity against 2,4-D Thioamides Oxidative dimerization Electrochemical synthesis 1,2,4-thiadiazoles
Online-ссылка:	https://dspace.ncfu.ru/handle/20.500.12258/22277
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id	ir-20.500.12258-22277
record_format	dspace
spelling	ir-20.500.12258-222772025-02-12T14:52:49Z Electrochemical Oxidation of 3-Aryl-2-cyanothioacrylamides Dotsenko, V. V. Доценко, В. В. Strelkov, V. D. Стрелков, В. Д. Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В. Growth-regulating activity Antidote activity against 2,4-D Thioamides Oxidative dimerization Electrochemical synthesis 1,2,4-thiadiazoles Electrochemical oxidation of (Е)-3-aryl-2-cyanoprop-2-enethioamides in a undivided cell in the presence of KBr in an aqueous or aqueous-organic medium has led to the formation of (2Е,2′E)-2,2′-(1,2,4-thiadiazole-3,5-diyl)bis[3-arylacrylonitriles] in 37–76% yield. A plausible reaction mechanism has been discussed. In laboratory experiments, (2E,2′E)-2,2′-(1,2,4-thiadiazol-3,5-diyl)bis[3-(4-methoxyphenyl)acrylonitrile] has revealed pronounced antidote effect against herbicide 2,4-D on sunflower seedlings and no pronounced growth-regulating properties. 2023-01-27T12:05:40Z 2023-01-27T12:05:40Z 2022 Статья Osminin, V.I., Mironenko, A.A., Dahno, P.G., Nazarenko, M.A., Oflidi, A.I., Dotsenko, V.V., Strelkov, V.D., Aksenov, N.A., Aksenova, I.V. Electrochemical Oxidation of 3-Aryl-2-cyanothioacrylamides // Russian Journal of General Chemistry. - 2022. - 92 (11), pp. 2235-2245. - DOI: 10.1134/S1070363222110068 http://hdl.handle.net/20.500.12258/22277 ru Russian Journal of General Chemistry application/pdf application/pdf
institution	СКФУ
collection	Репозиторий
language	Russian
topic	Growth-regulating activity Antidote activity against 2,4-D Thioamides Oxidative dimerization Electrochemical synthesis 1,2,4-thiadiazoles
spellingShingle	Growth-regulating activity Antidote activity against 2,4-D Thioamides Oxidative dimerization Electrochemical synthesis 1,2,4-thiadiazoles Dotsenko, V. V. Доценко, В. В. Strelkov, V. D. Стрелков, В. Д. Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В. Electrochemical Oxidation of 3-Aryl-2-cyanothioacrylamides
description	Electrochemical oxidation of (Е)-3-aryl-2-cyanoprop-2-enethioamides in a undivided cell in the presence of KBr in an aqueous or aqueous-organic medium has led to the formation of (2Е,2′E)-2,2′-(1,2,4-thiadiazole-3,5-diyl)bis[3-arylacrylonitriles] in 37–76% yield. A plausible reaction mechanism has been discussed. In laboratory experiments, (2E,2′E)-2,2′-(1,2,4-thiadiazol-3,5-diyl)bis[3-(4-methoxyphenyl)acrylonitrile] has revealed pronounced antidote effect against herbicide 2,4-D on sunflower seedlings and no pronounced growth-regulating properties.
format	Статья
author	Dotsenko, V. V. Доценко, В. В. Strelkov, V. D. Стрелков, В. Д. Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В.
author_facet	Dotsenko, V. V. Доценко, В. В. Strelkov, V. D. Стрелков, В. Д. Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В.
author_sort	Dotsenko, V. V.
title	Electrochemical Oxidation of 3-Aryl-2-cyanothioacrylamides
title_short	Electrochemical Oxidation of 3-Aryl-2-cyanothioacrylamides
title_full	Electrochemical Oxidation of 3-Aryl-2-cyanothioacrylamides
title_fullStr	Electrochemical Oxidation of 3-Aryl-2-cyanothioacrylamides
title_full_unstemmed	Electrochemical Oxidation of 3-Aryl-2-cyanothioacrylamides
title_sort	electrochemical oxidation of 3-aryl-2-cyanothioacrylamides
publishDate	2023
url	https://dspace.ncfu.ru/handle/20.500.12258/22277
work_keys_str_mv	AT dotsenkovv electrochemicaloxidationof3aryl2cyanothioacrylamides AT docenkovv electrochemicaloxidationof3aryl2cyanothioacrylamides AT strelkovvd electrochemicaloxidationof3aryl2cyanothioacrylamides AT strelkovvd electrochemicaloxidationof3aryl2cyanothioacrylamides AT aksenovna electrochemicaloxidationof3aryl2cyanothioacrylamides AT aksenovna electrochemicaloxidationof3aryl2cyanothioacrylamides AT aksenovaiv electrochemicaloxidationof3aryl2cyanothioacrylamides AT aksenovaiv electrochemicaloxidationof3aryl2cyanothioacrylamides
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Electrochemical Oxidation of 3-Aryl-2-cyanothioacrylamides

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