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N,N′-Diphenyldithiomalonamide as Methylene Active Thioamide: A First Synthesis of Stable Michael Adducts

N,N′-Diphenyldithiomalonamide reacts with the 4-nitrobenzylidene derivative of Meldrum’s acid (or with Meldrum’s acid and 4-nitrobenzaldehyde) in the presence of a base to form crystalline Michael adducts. Structure of triethylammonium 2,2-dimethyl-5-(1-(4-nitrophenyl)-3-(phenylamino)-2-(phenylcarba...

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Hoofdauteurs: Dotsenko, V. V., Доценко, В. В., Aksenov, N. A., Аксенов, Н. А., Aksenova, I. V., Аксенова, И. В.
Formaat: Статья
Taal:English
Gepubliceerd in: 2023
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Online toegang:https://dspace.ncfu.ru/handle/20.500.12258/22278
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spelling ir-20.500.12258-222782023-01-27T12:31:19Z N,N′-Diphenyldithiomalonamide as Methylene Active Thioamide: A First Synthesis of Stable Michael Adducts Dotsenko, V. V. Доценко, В. В. Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В. Active methylene thioamides Stable Michael adducts Dithiomalondianilide Meldrum’s acid N,N′-Diphenyldithiomalonamide reacts with the 4-nitrobenzylidene derivative of Meldrum’s acid (or with Meldrum’s acid and 4-nitrobenzaldehyde) in the presence of a base to form crystalline Michael adducts. Structure of triethylammonium 2,2-dimethyl-5-(1-(4-nitrophenyl)-3-(phenylamino)-2-(phenylcarbamothioyl)-3- thioxopropyl)-4-oxo-4H-1,3-dioxin-6-olate was studied by single crystal X-ray diffraction analysis. 2023-01-27T12:22:06Z 2023-01-27T12:22:06Z 2022 Статья Dotsenko, V.V., Sinotsko, A.E., Varzieva, E.A., Chigorina, E.A., Aksenov, N.A., Aksenova, I.V. N,N′-Diphenyldithiomalonamide as Methylene Active Thioamide: A First Synthesis of Stable Michael Adducts // Russian Journal of General Chemistry. - 2022. - 92 (11), pp. 2530-2535. - DOI: 10.1134/S107036322211041X http://hdl.handle.net/20.500.12258/22278 en Russian Journal of General Chemistry application/pdf application/pdf
institution СКФУ
collection Репозиторий
language English
topic Active methylene thioamides
Stable Michael adducts
Dithiomalondianilide
Meldrum’s acid
spellingShingle Active methylene thioamides
Stable Michael adducts
Dithiomalondianilide
Meldrum’s acid
Dotsenko, V. V.
Доценко, В. В.
Aksenov, N. A.
Аксенов, Н. А.
Aksenova, I. V.
Аксенова, И. В.
N,N′-Diphenyldithiomalonamide as Methylene Active Thioamide: A First Synthesis of Stable Michael Adducts
description N,N′-Diphenyldithiomalonamide reacts with the 4-nitrobenzylidene derivative of Meldrum’s acid (or with Meldrum’s acid and 4-nitrobenzaldehyde) in the presence of a base to form crystalline Michael adducts. Structure of triethylammonium 2,2-dimethyl-5-(1-(4-nitrophenyl)-3-(phenylamino)-2-(phenylcarbamothioyl)-3- thioxopropyl)-4-oxo-4H-1,3-dioxin-6-olate was studied by single crystal X-ray diffraction analysis.
format Статья
author Dotsenko, V. V.
Доценко, В. В.
Aksenov, N. A.
Аксенов, Н. А.
Aksenova, I. V.
Аксенова, И. В.
author_facet Dotsenko, V. V.
Доценко, В. В.
Aksenov, N. A.
Аксенов, Н. А.
Aksenova, I. V.
Аксенова, И. В.
author_sort Dotsenko, V. V.
title N,N′-Diphenyldithiomalonamide as Methylene Active Thioamide: A First Synthesis of Stable Michael Adducts
title_short N,N′-Diphenyldithiomalonamide as Methylene Active Thioamide: A First Synthesis of Stable Michael Adducts
title_full N,N′-Diphenyldithiomalonamide as Methylene Active Thioamide: A First Synthesis of Stable Michael Adducts
title_fullStr N,N′-Diphenyldithiomalonamide as Methylene Active Thioamide: A First Synthesis of Stable Michael Adducts
title_full_unstemmed N,N′-Diphenyldithiomalonamide as Methylene Active Thioamide: A First Synthesis of Stable Michael Adducts
title_sort n,n′-diphenyldithiomalonamide as methylene active thioamide: a first synthesis of stable michael adducts
publishDate 2023
url https://dspace.ncfu.ru/handle/20.500.12258/22278
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