N,N′-Diphenyldithiomalonamide as Methylene Active Thioamide: A First Synthesis of Stable Michael Adducts
N,N′-Diphenyldithiomalonamide reacts with the 4-nitrobenzylidene derivative of Meldrum’s acid (or with Meldrum’s acid and 4-nitrobenzaldehyde) in the presence of a base to form crystalline Michael adducts. Structure of triethylammonium 2,2-dimethyl-5-(1-(4-nitrophenyl)-3-(phenylamino)-2-(phenylcarba...
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ir-20.500.12258-222782023-01-27T12:31:19Z N,N′-Diphenyldithiomalonamide as Methylene Active Thioamide: A First Synthesis of Stable Michael Adducts Dotsenko, V. V. Доценко, В. В. Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В. Active methylene thioamides Stable Michael adducts Dithiomalondianilide Meldrum’s acid N,N′-Diphenyldithiomalonamide reacts with the 4-nitrobenzylidene derivative of Meldrum’s acid (or with Meldrum’s acid and 4-nitrobenzaldehyde) in the presence of a base to form crystalline Michael adducts. Structure of triethylammonium 2,2-dimethyl-5-(1-(4-nitrophenyl)-3-(phenylamino)-2-(phenylcarbamothioyl)-3- thioxopropyl)-4-oxo-4H-1,3-dioxin-6-olate was studied by single crystal X-ray diffraction analysis. 2023-01-27T12:22:06Z 2023-01-27T12:22:06Z 2022 Статья Dotsenko, V.V., Sinotsko, A.E., Varzieva, E.A., Chigorina, E.A., Aksenov, N.A., Aksenova, I.V. N,N′-Diphenyldithiomalonamide as Methylene Active Thioamide: A First Synthesis of Stable Michael Adducts // Russian Journal of General Chemistry. - 2022. - 92 (11), pp. 2530-2535. - DOI: 10.1134/S107036322211041X http://hdl.handle.net/20.500.12258/22278 en Russian Journal of General Chemistry application/pdf application/pdf |
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English |
topic |
Active methylene thioamides Stable Michael adducts Dithiomalondianilide Meldrum’s acid |
spellingShingle |
Active methylene thioamides Stable Michael adducts Dithiomalondianilide Meldrum’s acid Dotsenko, V. V. Доценко, В. В. Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В. N,N′-Diphenyldithiomalonamide as Methylene Active Thioamide: A First Synthesis of Stable Michael Adducts |
description |
N,N′-Diphenyldithiomalonamide reacts with the 4-nitrobenzylidene derivative of Meldrum’s acid (or with Meldrum’s acid and 4-nitrobenzaldehyde) in the presence of a base to form crystalline Michael adducts. Structure of triethylammonium 2,2-dimethyl-5-(1-(4-nitrophenyl)-3-(phenylamino)-2-(phenylcarbamothioyl)-3-
thioxopropyl)-4-oxo-4H-1,3-dioxin-6-olate was studied by single crystal X-ray diffraction analysis. |
format |
Статья |
author |
Dotsenko, V. V. Доценко, В. В. Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В. |
author_facet |
Dotsenko, V. V. Доценко, В. В. Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В. |
author_sort |
Dotsenko, V. V. |
title |
N,N′-Diphenyldithiomalonamide as Methylene Active Thioamide: A First Synthesis of Stable Michael Adducts |
title_short |
N,N′-Diphenyldithiomalonamide as Methylene Active Thioamide: A First Synthesis of Stable Michael Adducts |
title_full |
N,N′-Diphenyldithiomalonamide as Methylene Active Thioamide: A First Synthesis of Stable Michael Adducts |
title_fullStr |
N,N′-Diphenyldithiomalonamide as Methylene Active Thioamide: A First Synthesis of Stable Michael Adducts |
title_full_unstemmed |
N,N′-Diphenyldithiomalonamide as Methylene Active Thioamide: A First Synthesis of Stable Michael Adducts |
title_sort |
n,n′-diphenyldithiomalonamide as methylene active thioamide: a first synthesis of stable michael adducts |
publishDate |
2023 |
url |
https://dspace.ncfu.ru/handle/20.500.12258/22278 |
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