α-Amino acid-assisted autoxidation of naphthalene proton sponge affording 1,4-naphthoquinone nitrogen derivatives
1,8-Bis(dimethylamino)naphthalene (naphthalene proton sponge) equipped at position 4 with N-terminal α-amino acid residues undergoes unprecedented easy autoxidation in basic medium forming 5-dimethylamino-1,4-naphthoquinone along with minor amounts of its derivatives. The new reaction is of interest...
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2023
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ir-20.500.12258-237932025-02-12T07:47:43Z α-Amino acid-assisted autoxidation of naphthalene proton sponge affording 1,4-naphthoquinone nitrogen derivatives Demidov, O. P. Демидов, О. П. 1,8-Bis(dimethylamino)naphthalene 5-dimethylamino-1,4-naphthoquinone 1,4-naphthoquinones Autoxidation 1,8-Bis(dimethylamino)naphthalene (naphthalene proton sponge) equipped at position 4 with N-terminal α-amino acid residues undergoes unprecedented easy autoxidation in basic medium forming 5-dimethylamino-1,4-naphthoquinone along with minor amounts of its derivatives. The new reaction is of interest against the background of wide distribution of 1,4-naphthoquinones in nature, their high biological significance and extremely limited information on nitrogen compounds of this series. 2023-06-29T12:07:44Z 2023-06-29T12:07:44Z 2023 Статья Vlasenko, M.P., Pozharskii, A.F., Demidov, O.P., Ozeryanskii, V.A., Borodkin, G.S. α-Amino acid-assisted autoxidation of naphthalene proton sponge affording 1,4-naphthoquinone nitrogen derivatives // Mendeleev Communications. - 2023. - 33(2), pp. 197-200. - DOI: 10.1016/j.mencom.2023.02.015 http://hdl.handle.net/20.500.12258/23793 en Mendeleev Communications application/pdf application/pdf |
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СКФУ |
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Репозиторий |
| language |
English |
| topic |
1,8-Bis(dimethylamino)naphthalene 5-dimethylamino-1,4-naphthoquinone 1,4-naphthoquinones Autoxidation |
| spellingShingle |
1,8-Bis(dimethylamino)naphthalene 5-dimethylamino-1,4-naphthoquinone 1,4-naphthoquinones Autoxidation Demidov, O. P. Демидов, О. П. α-Amino acid-assisted autoxidation of naphthalene proton sponge affording 1,4-naphthoquinone nitrogen derivatives |
| description |
1,8-Bis(dimethylamino)naphthalene (naphthalene proton sponge) equipped at position 4 with N-terminal α-amino acid residues undergoes unprecedented easy autoxidation in basic medium forming 5-dimethylamino-1,4-naphthoquinone along with minor amounts of its derivatives. The new reaction is of interest against the background of wide distribution of 1,4-naphthoquinones in nature, their high biological significance and extremely limited information on nitrogen compounds of this series. |
| format |
Статья |
| author |
Demidov, O. P. Демидов, О. П. |
| author_facet |
Demidov, O. P. Демидов, О. П. |
| author_sort |
Demidov, O. P. |
| title |
α-Amino acid-assisted autoxidation of naphthalene proton sponge affording 1,4-naphthoquinone nitrogen derivatives |
| title_short |
α-Amino acid-assisted autoxidation of naphthalene proton sponge affording 1,4-naphthoquinone nitrogen derivatives |
| title_full |
α-Amino acid-assisted autoxidation of naphthalene proton sponge affording 1,4-naphthoquinone nitrogen derivatives |
| title_fullStr |
α-Amino acid-assisted autoxidation of naphthalene proton sponge affording 1,4-naphthoquinone nitrogen derivatives |
| title_full_unstemmed |
α-Amino acid-assisted autoxidation of naphthalene proton sponge affording 1,4-naphthoquinone nitrogen derivatives |
| title_sort |
α-amino acid-assisted autoxidation of naphthalene proton sponge affording 1,4-naphthoquinone nitrogen derivatives |
| publishDate |
2023 |
| url |
https://dspace.ncfu.ru/handle/20.500.12258/23793 |
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