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Unexpected cyclization of 2-(2-aminophenyl)indoles with nitroalkenes to furnish indolo[3,2-: C] quinolines

Unexpected cyclization of 2-(2-aminophenyl)indoles with nitroalkenes to furnish indolo[3,2-: C] quinolines

The polyphosphoric acid-mediated reaction of 2-(2-aminophenyl)indenes with nitroalkenes was tested in the frame of synthetic studies towards CDK inhibitors with the paullone core. Unexpectedly, this reaction proceeded via a different mechanistic pathway affording derivatives of the natural alkaloid...

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Hlavní autoři: Aksenov, A. V., Аксенов, А. В., Aksenov, D. A., Аксенов, Д. А., Griaznov, G. D., Грязнов, Г. Д., Aksenov, N. A., Аксенов, Н. А., Rubin, M. A., Рубин, М. А.
Médium: Статья
Jazyk:English
Vydáno: Royal Society of Chemistry 2018
Témata:
Positive ions
CDK inhibitors
Mechanistic pathways
Mediated reactions
Nitroalkenes
Polyphosphoric acids
Synthetic study
Chemistry
On-line přístup:https://www.scopus.com/record/display.uri?eid=2-s2.0-85048659764&origin=resultslist&sort=plf-f&src=s&nlo=&nlr=&nls=&sid=91fa45a4f686626d1b5858a2082471eb&sot=aff&sdt=sisr&sl=145&s=AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29+OR+AF-ID%28%22%5bNo+Affiliation+ID+found%5d%22+60070961%29+OR+AF-ID%28%22%5bNo+Affiliation+ID+found%5d%22+60026323%29&ref=%28Unexpected+cyclization+of+2%29&relpos=2&citeCnt=0&searchTerm=
https://dspace.ncfu.ru:443/handle/20.500.12258/2446
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https://www.scopus.com/record/display.uri?eid=2-s2.0-85048659764&origin=resultslist&sort=plf-f&src=s&nlo=&nlr=&nls=&sid=91fa45a4f686626d1b5858a2082471eb&sot=aff&sdt=sisr&sl=145&s=AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29+OR+AF-ID%28%22%5bNo+Affiliation+ID+found%5d%22+60070961%29+OR+AF-ID%28%22%5bNo+Affiliation+ID+found%5d%22+60026323%29&ref=%28Unexpected+cyclization+of+2%29&relpos=2&citeCnt=0&searchTerm=
https://dspace.ncfu.ru:443/handle/20.500.12258/2446

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