Bifunctional Organic Molecules as an Effective Stabilizer for Selenium Nanoparticles

This paper presents the results of studying the process of stabilization of selenium nanoparticles using 20 basic amino acids. Selenious acid was used as a selenium-containing precursor, sodium borohydride was used as a reducing agent, and 20 basic amino acids acted as stabilizers. The synthesis was...

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Asıl Yazarlar:	Blinov, A. V., Блинов, А. В., Maglakelidze, D. G., Маглакелидзе, Д. Г., Blinova, A. A., Блинова, А. А.
Materyal Türü:	Статья
Dil:	English
Baskı/Yayın Bilgisi:	2024
Konular:	Computer quantum chemical simulation Selenium nanoparticles Amino acids Average hydrodynamic radius
Online Erişim:	https://dspace.ncfu.ru/handle/20.500.12258/26468
Etiketler:	Etiketle Etiket eklenmemiş, İlk siz ekleyin!

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record_format	dspace
spelling	ir-20.500.12258-264682024-02-15T10:10:14Z Bifunctional Organic Molecules as an Effective Stabilizer for Selenium Nanoparticles Blinov, A. V. Блинов, А. В. Maglakelidze, D. G. Маглакелидзе, Д. Г. Blinova, A. A. Блинова, А. А. Computer quantum chemical simulation Selenium nanoparticles Amino acids Average hydrodynamic radius This paper presents the results of studying the process of stabilization of selenium nanoparticles using 20 basic amino acids. Selenious acid was used as a selenium-containing precursor, sodium borohydride was used as a reducing agent, and 20 basic amino acids acted as stabilizers. The synthesis was carried out by the method of chemical reduction in an aqueous medium. The average hydrodynamic radius of the particles obtained samples was determined by photon correlation spectroscopy. As a result of the analysis of the obtained data, it was found that the optimal amino acids for stabilizing selenium nanoparticles are L-valine, L-aspargine, L-serine, L-lysine, L-methionine, L-threonine, L-proline, L-glutamine, L-cysteine, L-phenylalanine, L-leucine. We also studied the influence of the optimal stabilizer concentration on the average hydrodynamic radius of selenium nanoparticles. It has been established that samples of nanoselenium stabilized with the amino acid L-methionine have the smallest particle radius. We also studied the stabilization of selenium nanoparticles with amino acids using computer quantum chemical simulation. As a result of quantum chemical modeling, it was found that the energetically favorable interaction is the Se-L-methionine configuration through the thiol group of the amino acid, the energy value of which was -12789.474 kcal/mol. 2024-02-15T10:08:57Z 2024-02-15T10:08:57Z 2023 Статья Blinov, A., Maglakelidze, D., Blinova, A., Dodov, M., Magomedova, P. Bifunctional Organic Molecules as an Effective Stabilizer for Selenium Nanoparticles // AIP Conference Proceedings. - 2023. - 2931 (1). - статья № 060005. - DOI: 10.1063/5.0179713 http://hdl.handle.net/20.500.12258/26468 en AIP Conference Proceedings application/pdf
institution	СКФУ
collection	Репозиторий
language	English
topic	Computer quantum chemical simulation Selenium nanoparticles Amino acids Average hydrodynamic radius
spellingShingle	Computer quantum chemical simulation Selenium nanoparticles Amino acids Average hydrodynamic radius Blinov, A. V. Блинов, А. В. Maglakelidze, D. G. Маглакелидзе, Д. Г. Blinova, A. A. Блинова, А. А. Bifunctional Organic Molecules as an Effective Stabilizer for Selenium Nanoparticles
description	This paper presents the results of studying the process of stabilization of selenium nanoparticles using 20 basic amino acids. Selenious acid was used as a selenium-containing precursor, sodium borohydride was used as a reducing agent, and 20 basic amino acids acted as stabilizers. The synthesis was carried out by the method of chemical reduction in an aqueous medium. The average hydrodynamic radius of the particles obtained samples was determined by photon correlation spectroscopy. As a result of the analysis of the obtained data, it was found that the optimal amino acids for stabilizing selenium nanoparticles are L-valine, L-aspargine, L-serine, L-lysine, L-methionine, L-threonine, L-proline, L-glutamine, L-cysteine, L-phenylalanine, L-leucine. We also studied the influence of the optimal stabilizer concentration on the average hydrodynamic radius of selenium nanoparticles. It has been established that samples of nanoselenium stabilized with the amino acid L-methionine have the smallest particle radius. We also studied the stabilization of selenium nanoparticles with amino acids using computer quantum chemical simulation. As a result of quantum chemical modeling, it was found that the energetically favorable interaction is the Se-L-methionine configuration through the thiol group of the amino acid, the energy value of which was -12789.474 kcal/mol.
format	Статья
author	Blinov, A. V. Блинов, А. В. Maglakelidze, D. G. Маглакелидзе, Д. Г. Blinova, A. A. Блинова, А. А.
author_facet	Blinov, A. V. Блинов, А. В. Maglakelidze, D. G. Маглакелидзе, Д. Г. Blinova, A. A. Блинова, А. А.
author_sort	Blinov, A. V.
title	Bifunctional Organic Molecules as an Effective Stabilizer for Selenium Nanoparticles
title_short	Bifunctional Organic Molecules as an Effective Stabilizer for Selenium Nanoparticles
title_full	Bifunctional Organic Molecules as an Effective Stabilizer for Selenium Nanoparticles
title_fullStr	Bifunctional Organic Molecules as an Effective Stabilizer for Selenium Nanoparticles
title_full_unstemmed	Bifunctional Organic Molecules as an Effective Stabilizer for Selenium Nanoparticles
title_sort	bifunctional organic molecules as an effective stabilizer for selenium nanoparticles
publishDate	2024
url	https://dspace.ncfu.ru/handle/20.500.12258/26468
work_keys_str_mv	AT blinovav bifunctionalorganicmoleculesasaneffectivestabilizerforseleniumnanoparticles AT blinovav bifunctionalorganicmoleculesasaneffectivestabilizerforseleniumnanoparticles AT maglakelidzedg bifunctionalorganicmoleculesasaneffectivestabilizerforseleniumnanoparticles AT maglakelidzedg bifunctionalorganicmoleculesasaneffectivestabilizerforseleniumnanoparticles AT blinovaaa bifunctionalorganicmoleculesasaneffectivestabilizerforseleniumnanoparticles AT blinovaaa bifunctionalorganicmoleculesasaneffectivestabilizerforseleniumnanoparticles
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Bifunctional Organic Molecules as an Effective Stabilizer for Selenium Nanoparticles

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