Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones

The reaction of tetraalkynyltin with aldehydes was studied for the first time. The reaction was shown to proceed as a tandem process of nucleophilic addition of tin acetylide to aldehyde followed by Oppenauer-type oxidation of produced tin alcoholates, and may be used as a convenient one-pot approac...

ver descrição completa

Na minha lista:

Detalhes bibliográficos
Главные авторы:	Aksenov, N. A., Аксенов, Н. А., Aksenova, I. V., Аксенова, И. В.
Formato:	Статья
Idioma:	English
Publicado em:	Royal Society of Chemistry 2018
Assuntos:	Aldehyde derivative Ketone derivative Stannic chloride Oxidative coupling
Acesso em linha:	https://www.scopus.com/record/display.uri?eid=2-s2.0-85027030617&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=1af4e03e943ebe5b20c0bfa6c2ca02b9&sot=afnl&sdt=sisr&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Oxidative+coupling+of+tetraalkynyltin+with+aldehydes+leading+to+alkynyl+ketones%29&relpos=1&citeCnt=3&searchTerm= https://dspace.ncfu.ru/handle/20.500.12258/2974
Tags:	Adicionar Tag Sem tags, seja o primeiro a adicionar uma tag!

id	ir-20.500.12258-2974
record_format	dspace
spelling	ir-20.500.12258-29742020-07-07T10:13:00Z Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В. Aldehyde derivative Ketone derivative Stannic chloride Oxidative coupling The reaction of tetraalkynyltin with aldehydes was studied for the first time. The reaction was shown to proceed as a tandem process of nucleophilic addition of tin acetylide to aldehyde followed by Oppenauer-type oxidation of produced tin alcoholates, and may be used as a convenient one-pot approach to acetylenic ketones. The advantages and limitations of the proposed method are discussed 2018-09-14T08:43:35Z 2018-09-14T08:43:35Z 2017 Статья Levashov, A.S., Aksenov, N.A., Aksenova, I.V., Konshin, V.V. Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones // New Journal of Chemistry. - 2017. - Volume 41. - Issue 16. - Pages 8297-8304 https://www.scopus.com/record/display.uri?eid=2-s2.0-85027030617&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=1af4e03e943ebe5b20c0bfa6c2ca02b9&sot=afnl&sdt=sisr&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Oxidative+coupling+of+tetraalkynyltin+with+aldehydes+leading+to+alkynyl+ketones%29&relpos=1&citeCnt=3&searchTerm= http://hdl.handle.net/20.500.12258/2974 en New Journal of Chemistry application/pdf application/pdf Royal Society of Chemistry
institution	СКФУ
collection	Репозиторий
language	English
topic	Aldehyde derivative Ketone derivative Stannic chloride Oxidative coupling
spellingShingle	Aldehyde derivative Ketone derivative Stannic chloride Oxidative coupling Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В. Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones
description	The reaction of tetraalkynyltin with aldehydes was studied for the first time. The reaction was shown to proceed as a tandem process of nucleophilic addition of tin acetylide to aldehyde followed by Oppenauer-type oxidation of produced tin alcoholates, and may be used as a convenient one-pot approach to acetylenic ketones. The advantages and limitations of the proposed method are discussed
format	Статья
author	Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В.
author_facet	Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В.
author_sort	Aksenov, N. A.
title	Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones
title_short	Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones
title_full	Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones
title_fullStr	Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones
title_full_unstemmed	Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones
title_sort	oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones
publisher	Royal Society of Chemistry
publishDate	2018
url	https://www.scopus.com/record/display.uri?eid=2-s2.0-85027030617&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=1af4e03e943ebe5b20c0bfa6c2ca02b9&sot=afnl&sdt=sisr&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Oxidative+coupling+of+tetraalkynyltin+with+aldehydes+leading+to+alkynyl+ketones%29&relpos=1&citeCnt=3&searchTerm= https://dspace.ncfu.ru/handle/20.500.12258/2974
work_keys_str_mv	AT aksenovna oxidativecouplingoftetraalkynyltinwithaldehydesleadingtoalkynylketones AT aksenovna oxidativecouplingoftetraalkynyltinwithaldehydesleadingtoalkynylketones AT aksenovaiv oxidativecouplingoftetraalkynyltinwithaldehydesleadingtoalkynylketones AT aksenovaiv oxidativecouplingoftetraalkynyltinwithaldehydesleadingtoalkynylketones
_version_	1760599532068929536

Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones

Registos relacionados