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Templated assembly of chiral medium-sized cyclic ethers via 8-endo-trig nucleophilic cyclization of cyclopropenes

Templated assembly of chiral medium-sized cyclic ethers via 8-endo-trig nucleophilic cyclization of cyclopropenes

An efficient approach toward enantioenriched eight-membered heterocycles via the intramolecular formal substitution of bromocyclopropanes with oxygen-based nucleophiles has been developed. The reaction proceeds via a reactive cyclopropene intermediate, which undergoes a rapid 8-endo-trig cyclization...

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Hlavní autoři: Rubin, M. A., Рубин, М. А.
Médium: Статья
Jazyk:English
Vydáno: American Chemical Society 2018
Témata:
Cyclopropane derivative
Cyclopropenes
Ether derivative
Chemical structure
Cyclization
Molecular structure
Particle size
On-line přístup:https://www.scopus.com/record/display.uri?eid=2-s2.0-85006341889&origin=resultslist&sort=plf-f&src=s&nlo=&nlr=&nls=&sid=2d4e826478140d99650a215e37019390&sot=aff&sdt=cl&cluster=scopubyr%2c%222016%22%2ct&sl=174&s=AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29+OR+AF-ID%28%22Stavropol+State+University%22+60070961%29+OR+AF-ID%28%22stavropolskij+Gosudarstvennyj+Tehniceskij+Universitet%22+60026323%29&relpos=2&citeCnt=3&searchTerm=
https://dspace.ncfu.ru/handle/20.500.12258/3164
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https://www.scopus.com/record/display.uri?eid=2-s2.0-85006341889&origin=resultslist&sort=plf-f&src=s&nlo=&nlr=&nls=&sid=2d4e826478140d99650a215e37019390&sot=aff&sdt=cl&cluster=scopubyr%2c%222016%22%2ct&sl=174&s=AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29+OR+AF-ID%28%22Stavropol+State+University%22+60070961%29+OR+AF-ID%28%22stavropolskij+Gosudarstvennyj+Tehniceskij+Universitet%22+60026323%29&relpos=2&citeCnt=3&searchTerm=
https://dspace.ncfu.ru/handle/20.500.12258/3164

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