Introduction of tetrazol-1-yl and 5-methyltetrazol-1-yl substituents in the phenyl ring of dibenzo-18-crown-6
Derivatives of the macrocyclic polyether dibenzo-18-crown-6 containing tetrazol-1-yl and 5-methyltetrazol-1-yl substituents in one of the phenyl rings have been synthesized for the first time: 1-(6,7,9,10,17,18,20,21-octahydrodibenzo[b,k][1,4,7,10,13,16]hexaoxacyclooctadecen- 2-yl)-1H-tetrazole and...
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ir-20.500.12258-31842020-07-31T08:59:24Z Introduction of tetrazol-1-yl and 5-methyltetrazol-1-yl substituents in the phenyl ring of dibenzo-18-crown-6 Aksenov, N. A. Аксенов, Н. А. Aksenov, A. V. Аксенов, А. В. Tetrazol-1-yl 5-methyltetrazol-1-yl Dibenzo-18-crown-6 Derivatives of the macrocyclic polyether dibenzo-18-crown-6 containing tetrazol-1-yl and 5-methyltetrazol-1-yl substituents in one of the phenyl rings have been synthesized for the first time: 1-(6,7,9,10,17,18,20,21-octahydrodibenzo[b,k][1,4,7,10,13,16]hexaoxacyclooctadecen- 2-yl)-1H-tetrazole and 5-methyl-1-(6,7,9,10,17,18,20,21-octahydrodibenzo[b,k][1,4,7,10,13,16]hexaoxacyclooctadecen- 2-yl)-1H-tetrazole, respectively. The first compound was obtained by a three-component domino reaction involving an arylamino derivative of dibenzo-18-crown-6, triethyl orthoformate, and sodium azide in glacial acetic acid. The second compound was prepared by treating the appropriate acetamide with tetrachlorosilane–sodium azide system in acetonitrile 2018-10-10T12:42:12Z 2018-10-10T12:42:12Z 2016 Статья Ostrovskii, V.A., Mazur, M.S., Mikhailenko, V.V., Aksenov, N.A., Aksenov, A.V. Introduction of tetrazol-1-yl and 5-methyltetrazol-1-yl substituents in the phenyl ring of dibenzo-18-crown-6 // Chemistry of Heterocyclic Compounds. - 2016. - Volume 52. - Issue 10. - Pages 849-851 https://www.scopus.com/record/display.uri?eid=2-s2.0-84997501224&origin=resultslist&sort=plf-f&src=s&nlo=&nlr=&nls=&sid=4571c9c342bce71328dbf4646312b3f0&sot=aff&sdt=cl&cluster=scopubyr%2c%222016%22%2ct&sl=174&s=AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29+OR+AF-ID%28%22Stavropol+State+University%22+60070961%29+OR+AF-ID%28%22stavropolskij+Gosudarstvennyj+Tehniceskij+Universitet%22+60026323%29&relpos=22&citeCnt=1&searchTerm= http://hdl.handle.net/20.500.12258/3184 en Chemistry of Heterocyclic Compounds application/pdf application/pdf Springer New York LLC |
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Tetrazol-1-yl 5-methyltetrazol-1-yl Dibenzo-18-crown-6 |
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Tetrazol-1-yl 5-methyltetrazol-1-yl Dibenzo-18-crown-6 Aksenov, N. A. Аксенов, Н. А. Aksenov, A. V. Аксенов, А. В. Introduction of tetrazol-1-yl and 5-methyltetrazol-1-yl substituents in the phenyl ring of dibenzo-18-crown-6 |
description |
Derivatives of the macrocyclic polyether dibenzo-18-crown-6 containing tetrazol-1-yl and 5-methyltetrazol-1-yl substituents in one of the phenyl rings have been synthesized for the first time: 1-(6,7,9,10,17,18,20,21-octahydrodibenzo[b,k][1,4,7,10,13,16]hexaoxacyclooctadecen- 2-yl)-1H-tetrazole and 5-methyl-1-(6,7,9,10,17,18,20,21-octahydrodibenzo[b,k][1,4,7,10,13,16]hexaoxacyclooctadecen- 2-yl)-1H-tetrazole, respectively. The first compound was obtained by a three-component domino reaction involving an arylamino derivative of dibenzo-18-crown-6, triethyl orthoformate, and sodium azide in glacial acetic acid. The second compound was prepared by treating the appropriate acetamide with tetrachlorosilane–sodium azide system in acetonitrile |
format |
Статья |
author |
Aksenov, N. A. Аксенов, Н. А. Aksenov, A. V. Аксенов, А. В. |
author_facet |
Aksenov, N. A. Аксенов, Н. А. Aksenov, A. V. Аксенов, А. В. |
author_sort |
Aksenov, N. A. |
title |
Introduction of tetrazol-1-yl and 5-methyltetrazol-1-yl substituents in the phenyl ring of dibenzo-18-crown-6 |
title_short |
Introduction of tetrazol-1-yl and 5-methyltetrazol-1-yl substituents in the phenyl ring of dibenzo-18-crown-6 |
title_full |
Introduction of tetrazol-1-yl and 5-methyltetrazol-1-yl substituents in the phenyl ring of dibenzo-18-crown-6 |
title_fullStr |
Introduction of tetrazol-1-yl and 5-methyltetrazol-1-yl substituents in the phenyl ring of dibenzo-18-crown-6 |
title_full_unstemmed |
Introduction of tetrazol-1-yl and 5-methyltetrazol-1-yl substituents in the phenyl ring of dibenzo-18-crown-6 |
title_sort |
introduction of tetrazol-1-yl and 5-methyltetrazol-1-yl substituents in the phenyl ring of dibenzo-18-crown-6 |
publisher |
Springer New York LLC |
publishDate |
2018 |
url |
https://www.scopus.com/record/display.uri?eid=2-s2.0-84997501224&origin=resultslist&sort=plf-f&src=s&nlo=&nlr=&nls=&sid=4571c9c342bce71328dbf4646312b3f0&sot=aff&sdt=cl&cluster=scopubyr%2c%222016%22%2ct&sl=174&s=AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29+OR+AF-ID%28%22Stavropol+State+University%22+60070961%29+OR+AF-ID%28%22stavropolskij+Gosudarstvennyj+Tehniceskij+Universitet%22+60026323%29&relpos=22&citeCnt=1&searchTerm= https://dspace.ncfu.ru/handle/20.500.12258/3184 |
work_keys_str_mv |
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