Ureas as new nucleophilic reagents for SN H amination and carbamoyl amination reactions in the 1,3,7-triazapyrene series

The ability of urea anions to react as nucleophiles with 1,3,7-triazapyrenes has been investigated. It was found that, against all expectations, the products of the substitution of hydrogen (SN H) by an amino group were isolated in good yields. The reactions proceed in anhydrous DMSO solution at roo...

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Prif Awduron:	Borovlev, I. V., Боровлев, И. В., Demidov, O. P., Демидов, О. П., Amangasieva, G. A., Амангазиева, Г. А., Avakyan, E. K., Авакян, Е. К., Kurnosova, N. A., Курносова, Н. А.
Fformat:	Статья
Iaith:	English
Cyhoeddwyd:	Arkat 2018
Pynciau:	1,3,7-triazapyren-6-amines Amination Carbamoyl amination Nucleophilic aromatic substitution of hydrogen
Mynediad Ar-lein:	https://www.scopus.com/record/display.uri?eid=2-s2.0-84960124757&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=b34ee1a283c2e8415711b601b248f06f&sot=afnl&sdt=cl&cluster=scopubyr%2c%222016%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&relpos=81&citeCnt=6&searchTerm= https://dspace.ncfu.ru/handle/20.500.12258/3298
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spelling	ir-20.500.12258-32982020-07-31T13:29:08Z Ureas as new nucleophilic reagents for SN H amination and carbamoyl amination reactions in the 1,3,7-triazapyrene series Borovlev, I. V. Боровлев, И. В. Demidov, O. P. Демидов, О. П. Amangasieva, G. A. Амангазиева, Г. А. Avakyan, E. K. Авакян, Е. К. Kurnosova, N. A. Курносова, Н. А. 1,3,7-triazapyren-6-amines Amination Carbamoyl amination Nucleophilic aromatic substitution of hydrogen The ability of urea anions to react as nucleophiles with 1,3,7-triazapyrenes has been investigated. It was found that, against all expectations, the products of the substitution of hydrogen (SN H) by an amino group were isolated in good yields. The reactions proceed in anhydrous DMSO solution at room temperature. However, when anions of mono substituted ureas containing bulky substituents were used, the products of previously unknown SN H reactions of alkyl carbamoyl amination were obtained 2018-10-19T13:02:25Z 2018-10-19T13:02:25Z 2016 Статья Borovlev, I.V., Demidov, O.P., Amangasieva, G.A., Avakyan, E.K., Kurnosova, N.A. Ureas as new nucleophilic reagents for SN H amination and carbamoyl amination reactions in the 1,3,7-triazapyrene series // Arkivoc. - 2016. - Volume 2016. - Issue 3. - Pages 58-70 https://www.scopus.com/record/display.uri?eid=2-s2.0-84960124757&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=b34ee1a283c2e8415711b601b248f06f&sot=afnl&sdt=cl&cluster=scopubyr%2c%222016%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&relpos=81&citeCnt=6&searchTerm= http://hdl.handle.net/20.500.12258/3298 en Arkivoc application/pdf application/pdf Arkat
institution	СКФУ
collection	Репозиторий
language	English
topic	1,3,7-triazapyren-6-amines Amination Carbamoyl amination Nucleophilic aromatic substitution of hydrogen
spellingShingle	1,3,7-triazapyren-6-amines Amination Carbamoyl amination Nucleophilic aromatic substitution of hydrogen Borovlev, I. V. Боровлев, И. В. Demidov, O. P. Демидов, О. П. Amangasieva, G. A. Амангазиева, Г. А. Avakyan, E. K. Авакян, Е. К. Kurnosova, N. A. Курносова, Н. А. Ureas as new nucleophilic reagents for SN H amination and carbamoyl amination reactions in the 1,3,7-triazapyrene series
description	The ability of urea anions to react as nucleophiles with 1,3,7-triazapyrenes has been investigated. It was found that, against all expectations, the products of the substitution of hydrogen (SN H) by an amino group were isolated in good yields. The reactions proceed in anhydrous DMSO solution at room temperature. However, when anions of mono substituted ureas containing bulky substituents were used, the products of previously unknown SN H reactions of alkyl carbamoyl amination were obtained
format	Статья
author	Borovlev, I. V. Боровлев, И. В. Demidov, O. P. Демидов, О. П. Amangasieva, G. A. Амангазиева, Г. А. Avakyan, E. K. Авакян, Е. К. Kurnosova, N. A. Курносова, Н. А.
author_facet	Borovlev, I. V. Боровлев, И. В. Demidov, O. P. Демидов, О. П. Amangasieva, G. A. Амангазиева, Г. А. Avakyan, E. K. Авакян, Е. К. Kurnosova, N. A. Курносова, Н. А.
author_sort	Borovlev, I. V.
title	Ureas as new nucleophilic reagents for SN H amination and carbamoyl amination reactions in the 1,3,7-triazapyrene series
title_short	Ureas as new nucleophilic reagents for SN H amination and carbamoyl amination reactions in the 1,3,7-triazapyrene series
title_full	Ureas as new nucleophilic reagents for SN H amination and carbamoyl amination reactions in the 1,3,7-triazapyrene series
title_fullStr	Ureas as new nucleophilic reagents for SN H amination and carbamoyl amination reactions in the 1,3,7-triazapyrene series
title_full_unstemmed	Ureas as new nucleophilic reagents for SN H amination and carbamoyl amination reactions in the 1,3,7-triazapyrene series
title_sort	ureas as new nucleophilic reagents for sn h amination and carbamoyl amination reactions in the 1,3,7-triazapyrene series
publisher	Arkat
publishDate	2018
url	https://www.scopus.com/record/display.uri?eid=2-s2.0-84960124757&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=b34ee1a283c2e8415711b601b248f06f&sot=afnl&sdt=cl&cluster=scopubyr%2c%222016%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&relpos=81&citeCnt=6&searchTerm= https://dspace.ncfu.ru/handle/20.500.12258/3298
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Ureas as new nucleophilic reagents for SN H amination and carbamoyl amination reactions in the 1,3,7-triazapyrene series

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