Templated assembly of medium cyclic ethers: Via exo-trig nucleophilic cyclization of cyclopropenes
A novel method for the assembly of medium heterocycles via an intramolecular nucleophilic addition to cyclopropenes generated in situ from the corresponding bromocyclopropanes is described. The exo-trig nucleophilic cyclizations were shown to proceed very efficiently and in a highly diastereoselecti...
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ir-20.500.12258-34192020-07-31T11:33:15Z Templated assembly of medium cyclic ethers: Via exo-trig nucleophilic cyclization of cyclopropenes Rubin, M. A. Рубин, М. А. Addition reaction Cyclization Diastereoisomer A novel method for the assembly of medium heterocycles via an intramolecular nucleophilic addition to cyclopropenes generated in situ from the corresponding bromocyclopropanes is described. The exo-trig nucleophilic cyclizations were shown to proceed very efficiently and in a highly diastereoselective fashion affording cis-fused bicyclic products possessing 7 to 10-membered medium rings; starting from a diastereomeric mixtures of bromocyclopropanes 2018-11-15T09:16:08Z 2018-11-15T09:16:08Z 2016 Статья Alnasleh, B.K., Rubina, M., Rubin, M. Templated assembly of medium cyclic ethers: Via exo-trig nucleophilic cyclization of cyclopropenes // Chemical Communications. - 2016. - Volume 52. - Issue 47. - Pages 7494-7496 https://www.scopus.com/record/display.uri?eid=2-s2.0-84973355637&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=0c7868cbb3df866f3fd416a84ccbeea5&sot=afnl&sdt=sisr&cluster=scopubyr%2c%222016%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Templated+assembly+of+medium+cyclic+ethers%3a+Via+exo-trig+nucleophilic+cyclization+of+cyclopropenes%29&relpos=1&citeCnt=5&searchTerm= http://hdl.handle.net/20.500.12258/3419 en Chemical communications application/pdf application/pdf Royal Society of Chemistry |
| institution |
СКФУ |
| collection |
Репозиторий |
| language |
English |
| topic |
Addition reaction Cyclization Diastereoisomer |
| spellingShingle |
Addition reaction Cyclization Diastereoisomer Rubin, M. A. Рубин, М. А. Templated assembly of medium cyclic ethers: Via exo-trig nucleophilic cyclization of cyclopropenes |
| description |
A novel method for the assembly of medium heterocycles via an intramolecular nucleophilic addition to cyclopropenes generated in situ from the corresponding bromocyclopropanes is described. The exo-trig nucleophilic cyclizations were shown to proceed very efficiently and in a highly diastereoselective fashion affording cis-fused bicyclic products possessing 7 to 10-membered medium rings; starting from a diastereomeric mixtures of bromocyclopropanes |
| format |
Статья |
| author |
Rubin, M. A. Рубин, М. А. |
| author_facet |
Rubin, M. A. Рубин, М. А. |
| author_sort |
Rubin, M. A. |
| title |
Templated assembly of medium cyclic ethers: Via exo-trig nucleophilic cyclization of cyclopropenes |
| title_short |
Templated assembly of medium cyclic ethers: Via exo-trig nucleophilic cyclization of cyclopropenes |
| title_full |
Templated assembly of medium cyclic ethers: Via exo-trig nucleophilic cyclization of cyclopropenes |
| title_fullStr |
Templated assembly of medium cyclic ethers: Via exo-trig nucleophilic cyclization of cyclopropenes |
| title_full_unstemmed |
Templated assembly of medium cyclic ethers: Via exo-trig nucleophilic cyclization of cyclopropenes |
| title_sort |
templated assembly of medium cyclic ethers: via exo-trig nucleophilic cyclization of cyclopropenes |
| publisher |
Royal Society of Chemistry |
| publishDate |
2018 |
| url |
https://www.scopus.com/record/display.uri?eid=2-s2.0-84973355637&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=0c7868cbb3df866f3fd416a84ccbeea5&sot=afnl&sdt=sisr&cluster=scopubyr%2c%222016%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Templated+assembly+of+medium+cyclic+ethers%3a+Via+exo-trig+nucleophilic+cyclization+of+cyclopropenes%29&relpos=1&citeCnt=5&searchTerm= https://dspace.ncfu.ru/handle/20.500.12258/3419 |
| work_keys_str_mv |
AT rubinma templatedassemblyofmediumcyclicethersviaexotrignucleophiliccyclizationofcyclopropenes AT rubinma templatedassemblyofmediumcyclicethersviaexotrignucleophiliccyclizationofcyclopropenes |
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1760599659087134720 |