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Nitrostyrenes as 1,4-CCNO-dipoles: diastereoselective formal [4+1] cycloaddition of indoles

Nitrostyrenes as 1,4-CCNO-dipoles: diastereoselective formal [4+1] cycloaddition of indoles

An unusual reactivity of nitrostyrenes in phosphorous acid was discovered, which permits the employment of these readily available synthons as 1,4-CCNO-dipole surrogates in a highly diastereoselective (4+1)-cycloaddition of indoles to afford 4'H-spiro[indole-3,5'-isoxazoles] in a diastereo...

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Главные авторы: Aksenov, A. V., Аксенов, А. В., Aksenov, N. A., Аксенов, Н. А., Aksenov, D. A., Аксенов, Д. А., Khamraev, V. F., Хамраев, В. Ф., Rubin, M. A., Рубин, М. А.
Формат: Статья
Язык:English
Опубликовано: NLM (Medline) 2018
Темы:
Indole
Cycloaddition of indoles
Online-ссылка:https://dspace.ncfu.ru/handle/20.500.12258/3532
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Краткое описание:An unusual reactivity of nitrostyrenes in phosphorous acid was discovered, which permits the employment of these readily available synthons as 1,4-CCNO-dipole surrogates in a highly diastereoselective (4+1)-cycloaddition of indoles to afford 4'H-spiro[indole-3,5'-isoxazoles] in a diastereomerically pure form

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