Nitrostyrenes as 1,4-CCNO-dipoles: diastereoselective formal [4+1] cycloaddition of indoles

An unusual reactivity of nitrostyrenes in phosphorous acid was discovered, which permits the employment of these readily available synthons as 1,4-CCNO-dipole surrogates in a highly diastereoselective (4+1)-cycloaddition of indoles to afford 4'H-spiro[indole-3,5'-isoxazoles] in a diastereo...

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Главные авторы:	Aksenov, A. V., Аксенов, А. В., Aksenov, N. A., Аксенов, Н. А., Aksenov, D. A., Аксенов, Д. А., Khamraev, V. F., Хамраев, В. Ф., Rubin, M. A., Рубин, М. А.
Формат:	Статья
Язык:	English
Опубликовано:	NLM (Medline) 2018
Темы:	Indole Cycloaddition of indoles
Online-ссылка:	https://dspace.ncfu.ru/handle/20.500.12258/3532
Метки:	Добавить метку Нет меток, Требуется 1-ая метка записи!

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spelling	ir-20.500.12258-35322025-02-13T12:35:21Z Nitrostyrenes as 1,4-CCNO-dipoles: diastereoselective formal [4+1] cycloaddition of indoles Aksenov, A. V. Аксенов, А. В. Aksenov, N. A. Аксенов, Н. А. Aksenov, D. A. Аксенов, Д. А. Khamraev, V. F. Хамраев, В. Ф. Rubin, M. A. Рубин, М. А. Indole Cycloaddition of indoles An unusual reactivity of nitrostyrenes in phosphorous acid was discovered, which permits the employment of these readily available synthons as 1,4-CCNO-dipole surrogates in a highly diastereoselective (4+1)-cycloaddition of indoles to afford 4'H-spiro[indole-3,5'-isoxazoles] in a diastereomerically pure form 2018-12-03T13:10:54Z 2018-12-03T13:10:54Z 2018 Статья Aksenov, A.V., Aksenov, N.A., Aksenov, D.A., Khamraev, V.F., Rubin, M. Nitrostyrenes as 1,4-CCNO-dipoles: diastereoselective formal [4+1] cycloaddition of indoles // Chemical communications (Cambridge, England). - 2018. - Volume 54. - Issue 94. - Pages 13260-13263 http://hdl.handle.net/20.500.12258/3532 en Chemical communications application/pdf application/pdf NLM (Medline)
institution	СКФУ
collection	Репозиторий
language	English
topic	Indole Cycloaddition of indoles
spellingShingle	Indole Cycloaddition of indoles Aksenov, A. V. Аксенов, А. В. Aksenov, N. A. Аксенов, Н. А. Aksenov, D. A. Аксенов, Д. А. Khamraev, V. F. Хамраев, В. Ф. Rubin, M. A. Рубин, М. А. Nitrostyrenes as 1,4-CCNO-dipoles: diastereoselective formal [4+1] cycloaddition of indoles
description	An unusual reactivity of nitrostyrenes in phosphorous acid was discovered, which permits the employment of these readily available synthons as 1,4-CCNO-dipole surrogates in a highly diastereoselective (4+1)-cycloaddition of indoles to afford 4'H-spiro[indole-3,5'-isoxazoles] in a diastereomerically pure form
format	Статья
author	Aksenov, A. V. Аксенов, А. В. Aksenov, N. A. Аксенов, Н. А. Aksenov, D. A. Аксенов, Д. А. Khamraev, V. F. Хамраев, В. Ф. Rubin, M. A. Рубин, М. А.
author_facet	Aksenov, A. V. Аксенов, А. В. Aksenov, N. A. Аксенов, Н. А. Aksenov, D. A. Аксенов, Д. А. Khamraev, V. F. Хамраев, В. Ф. Rubin, M. A. Рубин, М. А.
author_sort	Aksenov, A. V.
title	Nitrostyrenes as 1,4-CCNO-dipoles: diastereoselective formal [4+1] cycloaddition of indoles
title_short	Nitrostyrenes as 1,4-CCNO-dipoles: diastereoselective formal [4+1] cycloaddition of indoles
title_full	Nitrostyrenes as 1,4-CCNO-dipoles: diastereoselective formal [4+1] cycloaddition of indoles
title_fullStr	Nitrostyrenes as 1,4-CCNO-dipoles: diastereoselective formal [4+1] cycloaddition of indoles
title_full_unstemmed	Nitrostyrenes as 1,4-CCNO-dipoles: diastereoselective formal [4+1] cycloaddition of indoles
title_sort	nitrostyrenes as 1,4-ccno-dipoles: diastereoselective formal [4+1] cycloaddition of indoles
publisher	NLM (Medline)
publishDate	2018
url	https://dspace.ncfu.ru/handle/20.500.12258/3532
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Nitrostyrenes as 1,4-CCNO-dipoles: diastereoselective formal [4+1] cycloaddition of indoles

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