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Nitrostyrenes as 1,4-CCNO-dipoles: diastereoselective formal [4+1] cycloaddition of indoles

Nitrostyrenes as 1,4-CCNO-dipoles: diastereoselective formal [4+1] cycloaddition of indoles

An unusual reactivity of nitrostyrenes in phosphorous acid was discovered, which permits the employment of these readily available synthons as 1,4-CCNO-dipole surrogates in a highly diastereoselective (4+1)-cycloaddition of indoles to afford 4'H-spiro[indole-3,5'-isoxazoles] in a diastereo...

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Главные авторы: Aksenov, A. V., Аксенов, А. В., Aksenov, N. A., Аксенов, Н. А., Aksenov, D. A., Аксенов, Д. А., Khamraev, V. F., Хамраев, В. Ф., Rubin, M. A., Рубин, М. А.
格式: Статья
语言:English
出版: NLM (Medline) 2018
主题:
Indole
Cycloaddition of indoles
在线阅读:https://www.scopus.com/record/display.uri?eid=2-s2.0-85056941680&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=daa86f0573a9fe8189fcdb08cc741e58&sot=afnl&sdt=sisr&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Nitrostyrenes+as+1%2c4-CCNO-dipoles%3a+diastereoselective+formal+%5b4%2b1%5d+cycloaddition+of+indoles%29&relpos=0&citeCnt=0&searchTerm=
https://dspace.ncfu.ru/handle/20.500.12258/3532
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https://www.scopus.com/record/display.uri?eid=2-s2.0-85056941680&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=daa86f0573a9fe8189fcdb08cc741e58&sot=afnl&sdt=sisr&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Nitrostyrenes+as+1%2c4-CCNO-dipoles%3a+diastereoselective+formal+%5b4%2b1%5d+cycloaddition+of+indoles%29&relpos=0&citeCnt=0&searchTerm=
https://dspace.ncfu.ru/handle/20.500.12258/3532

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