Synthesis, structure, and biological activity of 2,6-diazido-4-methylnicotinonitrile derivatives

A number of 2,6-diazido-4-methylnicotinonitrile derivatives has been synthesized as prospective novel plant growth regulators. The 2-[(triphenylphosphoranylidene)amino]tetrazolo[1,5-a]pyridine derivative is selectively formed from 2,6-diazido-4-methylnicotinonitrile under the conditions of the Staud...

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Главные авторы:	Aksenov, N. A., Аксенов, Н. А., Dotsenko, V. V., Доценко, В. В.
Формат:	Статья
Язык:	English
Опубликовано:	Springer New York LLC 2018
Темы:	1,2,3-triazoles Azidopyridines Dimroth reaction Growth regulating activity Iminophosphoranes Nicotinonitriles Staudinger reaction
Online-ссылка:	https://dspace.ncfu.ru/handle/20.500.12258/3537
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spelling	ir-20.500.12258-35372025-02-12T13:04:57Z Synthesis, structure, and biological activity of 2,6-diazido-4-methylnicotinonitrile derivatives Aksenov, N. A. Аксенов, Н. А. Dotsenko, V. V. Доценко, В. В. 1,2,3-triazoles Azidopyridines Dimroth reaction Growth regulating activity Iminophosphoranes Nicotinonitriles Staudinger reaction A number of 2,6-diazido-4-methylnicotinonitrile derivatives has been synthesized as prospective novel plant growth regulators. The 2-[(triphenylphosphoranylidene)amino]tetrazolo[1,5-a]pyridine derivative is selectively formed from 2,6-diazido-4-methylnicotinonitrile under the conditions of the Staudinger reaction, from which N-(6-azido-5-cyano-4-methylpyridin-2-yl)acylamides can be obtained by sequential reduction and acylation. The obtained azidopyridines are converted into the corresponding 1,2,3-triazoles when treated with 1,3-dicarbonyl compounds in the presence of Et3N. Field studies showed that some of the synthesized compounds were effective growth regulators of wheat 2018-12-03T14:10:01Z 2018-12-03T14:10:01Z 2018 Статья Dyadyuchenko, L.V., Dmitrieva, I.G., Aksenov, N.A., Dotsenko, V.V. Synthesis, structure, and biological activity of 2,6-diazido-4-methylnicotinonitrile derivatives // Chemistry of Heterocyclic Compounds. - 2018. - Volume 54. - Issue 10. - Pages 964–970 http://hdl.handle.net/20.500.12258/3537 en Chemistry of Heterocyclic Compounds application/pdf application/pdf Springer New York LLC
institution	СКФУ
collection	Репозиторий
language	English
topic	1,2,3-triazoles Azidopyridines Dimroth reaction Growth regulating activity Iminophosphoranes Nicotinonitriles Staudinger reaction
spellingShingle	1,2,3-triazoles Azidopyridines Dimroth reaction Growth regulating activity Iminophosphoranes Nicotinonitriles Staudinger reaction Aksenov, N. A. Аксенов, Н. А. Dotsenko, V. V. Доценко, В. В. Synthesis, structure, and biological activity of 2,6-diazido-4-methylnicotinonitrile derivatives
description	A number of 2,6-diazido-4-methylnicotinonitrile derivatives has been synthesized as prospective novel plant growth regulators. The 2-[(triphenylphosphoranylidene)amino]tetrazolo[1,5-a]pyridine derivative is selectively formed from 2,6-diazido-4-methylnicotinonitrile under the conditions of the Staudinger reaction, from which N-(6-azido-5-cyano-4-methylpyridin-2-yl)acylamides can be obtained by sequential reduction and acylation. The obtained azidopyridines are converted into the corresponding 1,2,3-triazoles when treated with 1,3-dicarbonyl compounds in the presence of Et3N. Field studies showed that some of the synthesized compounds were effective growth regulators of wheat
format	Статья
author	Aksenov, N. A. Аксенов, Н. А. Dotsenko, V. V. Доценко, В. В.
author_facet	Aksenov, N. A. Аксенов, Н. А. Dotsenko, V. V. Доценко, В. В.
author_sort	Aksenov, N. A.
title	Synthesis, structure, and biological activity of 2,6-diazido-4-methylnicotinonitrile derivatives
title_short	Synthesis, structure, and biological activity of 2,6-diazido-4-methylnicotinonitrile derivatives
title_full	Synthesis, structure, and biological activity of 2,6-diazido-4-methylnicotinonitrile derivatives
title_fullStr	Synthesis, structure, and biological activity of 2,6-diazido-4-methylnicotinonitrile derivatives
title_full_unstemmed	Synthesis, structure, and biological activity of 2,6-diazido-4-methylnicotinonitrile derivatives
title_sort	synthesis, structure, and biological activity of 2,6-diazido-4-methylnicotinonitrile derivatives
publisher	Springer New York LLC
publishDate	2018
url	https://dspace.ncfu.ru/handle/20.500.12258/3537
work_keys_str_mv	AT aksenovna synthesisstructureandbiologicalactivityof26diazido4methylnicotinonitrilederivatives AT aksenovna synthesisstructureandbiologicalactivityof26diazido4methylnicotinonitrilederivatives AT dotsenkovv synthesisstructureandbiologicalactivityof26diazido4methylnicotinonitrilederivatives AT docenkovv synthesisstructureandbiologicalactivityof26diazido4methylnicotinonitrilederivatives
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Synthesis, structure, and biological activity of 2,6-diazido-4-methylnicotinonitrile derivatives

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