Пропуск в контексте
Synthesis of heterofunctional 1,3,7-triazapyrene derivatives by SNH and SNAr reactions

Synthesis of heterofunctional 1,3,7-triazapyrene derivatives by SNH and SNAr reactions

1,3,7-Triazapyrene reacts with amino alcohols in aqueous medium in the presence of K3Fe(CN)6 or in the system DMSO-KOH-O2 via oxidative nucleophilic substitution of hydrogen to give the corresponding 6-hydroxyalkylamino derivatives. The reaction of 1,3,7-triazapyrene with sodium amide in DMSO at roo...

全面介绍

Сохранить в:
书目详细资料
Главные авторы: Borovlev, I. V., Боровлев, И. В., Demidov, O. P., Демидов, О. П., Kurnosova, N. A., Курносова, Н. А., Avakyan, E. K., Авакян, Е. К., Amangasieva, G. A., Амангазиева, Г. А.
格式: Статья
语言:English
出版: Maik Nauka Publishing / Springer SBM 2018
主题:
1,3,7-triazapyrene
Derivatives by SNH and SNAr reactions
在线阅读:https://www.scopus.com/record/display.uri?eid=2-s2.0-84947425049&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=dc7f8c6f40c1112203ece798567bdeb2&sot=afnl&sdt=cl&cluster=scopubyr%2c%222015%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&relpos=10&citeCnt=0&searchTerm=
https://dspace.ncfu.ru/handle/20.500.12258/3691
标签: 添加标签
没有标签, 成为第一个标记此记录!
实物特征
总结:1,3,7-Triazapyrene reacts with amino alcohols in aqueous medium in the presence of K3Fe(CN)6 or in the system DMSO-KOH-O2 via oxidative nucleophilic substitution of hydrogen to give the corresponding 6-hydroxyalkylamino derivatives. The reaction of 1,3,7-triazapyrene with sodium amide in DMSO at room temperature yields 1,3,7-triazapyren-6-amine. N-Alkyl-8-methoxy-1,3,7-triazapyren-6-amines or N,N'-dialkyl- 1,3,7-triazapyrene-6,8-diamines are formed in reactions of 6,8-dimethoxy-1,3,7-triazapyrene with alkylamines or amino alcohols in DMSO, depending on the conditions

相似书籍