Synthesis of heterofunctional 1,3,7-triazapyrene derivatives by SNH and SNAr reactions

1,3,7-Triazapyrene reacts with amino alcohols in aqueous medium in the presence of K3Fe(CN)6 or in the system DMSO-KOH-O2 via oxidative nucleophilic substitution of hydrogen to give the corresponding 6-hydroxyalkylamino derivatives. The reaction of 1,3,7-triazapyrene with sodium amide in DMSO at roo...

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Auteurs principaux:	Borovlev, I. V., Боровлев, И. В., Demidov, O. P., Демидов, О. П., Kurnosova, N. A., Курносова, Н. А., Avakyan, E. K., Авакян, Е. К., Amangasieva, G. A., Амангазиева, Г. А.
Format:	Статья
Langue:	English
Publié:	Maik Nauka Publishing / Springer SBM 2018
Sujets:	1,3,7-triazapyrene Derivatives by SNH and SNAr reactions
Accès en ligne:	https://www.scopus.com/record/display.uri?eid=2-s2.0-84947425049&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=dc7f8c6f40c1112203ece798567bdeb2&sot=afnl&sdt=cl&cluster=scopubyr%2c%222015%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&relpos=10&citeCnt=0&searchTerm= https://dspace.ncfu.ru/handle/20.500.12258/3691
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spelling	ir-20.500.12258-36912020-09-15T07:57:39Z Synthesis of heterofunctional 1,3,7-triazapyrene derivatives by SNH and SNAr reactions Borovlev, I. V. Боровлев, И. В. Demidov, O. P. Демидов, О. П. Kurnosova, N. A. Курносова, Н. А. Avakyan, E. K. Авакян, Е. К. Amangasieva, G. A. Амангазиева, Г. А. 1,3,7-triazapyrene Derivatives by SNH and SNAr reactions 1,3,7-Triazapyrene reacts with amino alcohols in aqueous medium in the presence of K3Fe(CN)6 or in the system DMSO-KOH-O2 via oxidative nucleophilic substitution of hydrogen to give the corresponding 6-hydroxyalkylamino derivatives. The reaction of 1,3,7-triazapyrene with sodium amide in DMSO at room temperature yields 1,3,7-triazapyren-6-amine. N-Alkyl-8-methoxy-1,3,7-triazapyren-6-amines or N,N'-dialkyl- 1,3,7-triazapyrene-6,8-diamines are formed in reactions of 6,8-dimethoxy-1,3,7-triazapyrene with alkylamines or amino alcohols in DMSO, depending on the conditions 2018-12-17T10:12:21Z 2018-12-17T10:12:21Z 2015 Статья Borovlev, I.V., Demidov, O.P., Kurnosova, N.A., Avakyan, E.K., Amangazieva, G.A. Synthesis of heterofunctional 1,3,7-triazapyrene derivatives by SNH and SNAr reactions // Russian Journal of Organic Chemistry. - 2015. - Volume 51. - Issue 10. - Pages 1438-1443 https://www.scopus.com/record/display.uri?eid=2-s2.0-84947425049&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=dc7f8c6f40c1112203ece798567bdeb2&sot=afnl&sdt=cl&cluster=scopubyr%2c%222015%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&relpos=10&citeCnt=0&searchTerm= http://hdl.handle.net/20.500.12258/3691 en Russian Journal of Organic Chemistry application/pdf application/pdf Maik Nauka Publishing / Springer SBM
institution	СКФУ
collection	Репозиторий
language	English
topic	1,3,7-triazapyrene Derivatives by SNH and SNAr reactions
spellingShingle	1,3,7-triazapyrene Derivatives by SNH and SNAr reactions Borovlev, I. V. Боровлев, И. В. Demidov, O. P. Демидов, О. П. Kurnosova, N. A. Курносова, Н. А. Avakyan, E. K. Авакян, Е. К. Amangasieva, G. A. Амангазиева, Г. А. Synthesis of heterofunctional 1,3,7-triazapyrene derivatives by SNH and SNAr reactions
description	1,3,7-Triazapyrene reacts with amino alcohols in aqueous medium in the presence of K3Fe(CN)6 or in the system DMSO-KOH-O2 via oxidative nucleophilic substitution of hydrogen to give the corresponding 6-hydroxyalkylamino derivatives. The reaction of 1,3,7-triazapyrene with sodium amide in DMSO at room temperature yields 1,3,7-triazapyren-6-amine. N-Alkyl-8-methoxy-1,3,7-triazapyren-6-amines or N,N'-dialkyl- 1,3,7-triazapyrene-6,8-diamines are formed in reactions of 6,8-dimethoxy-1,3,7-triazapyrene with alkylamines or amino alcohols in DMSO, depending on the conditions
format	Статья
author	Borovlev, I. V. Боровлев, И. В. Demidov, O. P. Демидов, О. П. Kurnosova, N. A. Курносова, Н. А. Avakyan, E. K. Авакян, Е. К. Amangasieva, G. A. Амангазиева, Г. А.
author_facet	Borovlev, I. V. Боровлев, И. В. Demidov, O. P. Демидов, О. П. Kurnosova, N. A. Курносова, Н. А. Avakyan, E. K. Авакян, Е. К. Amangasieva, G. A. Амангазиева, Г. А.
author_sort	Borovlev, I. V.
title	Synthesis of heterofunctional 1,3,7-triazapyrene derivatives by SNH and SNAr reactions
title_short	Synthesis of heterofunctional 1,3,7-triazapyrene derivatives by SNH and SNAr reactions
title_full	Synthesis of heterofunctional 1,3,7-triazapyrene derivatives by SNH and SNAr reactions
title_fullStr	Synthesis of heterofunctional 1,3,7-triazapyrene derivatives by SNH and SNAr reactions
title_full_unstemmed	Synthesis of heterofunctional 1,3,7-triazapyrene derivatives by SNH and SNAr reactions
title_sort	synthesis of heterofunctional 1,3,7-triazapyrene derivatives by snh and snar reactions
publisher	Maik Nauka Publishing / Springer SBM
publishDate	2018
url	https://www.scopus.com/record/display.uri?eid=2-s2.0-84947425049&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=dc7f8c6f40c1112203ece798567bdeb2&sot=afnl&sdt=cl&cluster=scopubyr%2c%222015%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&relpos=10&citeCnt=0&searchTerm= https://dspace.ncfu.ru/handle/20.500.12258/3691
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Synthesis of heterofunctional 1,3,7-triazapyrene derivatives by SNH and SNAr reactions

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