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Synthesis of 1,5-dioxocanes via the two-fold C-O bond forming nucleophilic 4 + 4-cyclodimerization of cycloprop-2-en-1-ylmethanols

Synthesis of 1,5-dioxocanes via the two-fold C-O bond forming nucleophilic 4 + 4-cyclodimerization of cycloprop-2-en-1-ylmethanols

An efficient [4 + 4] cyclodimerization of cyclopropenemethanols operating via a two-fold strain release-driven addition of alkoxides across the double bond of cyclopropenes was investigated. This chemo- and diastereoselective transformation provided previously unknown 2,7-dioxatricyclo[7.1.0.04,6]de...

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Главные авторы: Rubin, M. A., Рубин, М. А.
格式: Статья
语言:English
出版: Royal Society of Chemistry 2018
主题:
Alkoxides
Bond forming
Cyclodimerization
Cyclopropenes
Diastereoselective
Double bonds
Strain release
Scaffolds
在线阅读:https://www.scopus.com/record/display.uri?eid=2-s2.0-84940491140&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=dc7f8c6f40c1112203ece798567bdeb2&sot=afnl&sdt=cl&cluster=scopubyr%2c%222015%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&relpos=18&citeCnt=8&searchTerm=
https://dspace.ncfu.ru/handle/20.500.12258/3699
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https://www.scopus.com/record/display.uri?eid=2-s2.0-84940491140&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=dc7f8c6f40c1112203ece798567bdeb2&sot=afnl&sdt=cl&cluster=scopubyr%2c%222015%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&relpos=18&citeCnt=8&searchTerm=
https://dspace.ncfu.ru/handle/20.500.12258/3699

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