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One-pot synthesis of benzoxazoles via the metal-free ortho-C-H functionalization of phenols with nitroalkanes

PPA-activated nitroalkanes are employed in the design of a one-pot cascade transformation involving metal-free and oxidant-free direct ortho-C-H functionalization, followed by Beckman rearrangement and intramolecular cyclocondensation to produce benzoxazoles and benzobisoxazoles directly from easily...

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Главные авторы: Aksenov, N. A., Аксенов, Н. А., Aksenov, A. V., Аксенов, А. В., Nadein, O. N., Надеин, О. Н., Aksenov, D. A., Аксенов, Д. А., Smirnov, A. N., Смирнов, А. Н., Rubin, M. A., Рубин, М. А.
Формат: Статья
Язык:English
Опубликовано: Royal Society of Chemistry 2018
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Online-ссылка:https://dspace.ncfu.ru/handle/20.500.12258/3700
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spelling ir-20.500.12258-37002025-02-13T08:51:34Z One-pot synthesis of benzoxazoles via the metal-free ortho-C-H functionalization of phenols with nitroalkanes Aksenov, N. A. Аксенов, Н. А. Aksenov, A. V. Аксенов, А. В. Nadein, O. N. Надеин, О. Н. Aksenov, D. A. Аксенов, Д. А. Smirnov, A. N. Смирнов, А. Н. Rubin, M. A. Рубин, М. А. Paraffins Benzoxazole C-H functionalization Cascade transformations Cyclocondensation Metal free Nitroalkanes One pot One-pot synthesis Phenols PPA-activated nitroalkanes are employed in the design of a one-pot cascade transformation involving metal-free and oxidant-free direct ortho-C-H functionalization, followed by Beckman rearrangement and intramolecular cyclocondensation to produce benzoxazoles and benzobisoxazoles directly from easily available phenols 2018-12-17T14:49:41Z 2018-12-17T14:49:41Z 2015 Статья Aksenov, N.A., Aksenov, A.V., Nadein, O.N., Aksenov, D.A., Smirnov, A.N., Rubin, M. One-pot synthesis of benzoxazoles via the metal-free ortho-C-H functionalization of phenols with nitroalkanes // RSC Advances. - 2015. - Volume 5. - Issue 88. - Pages 71620-71626 http://hdl.handle.net/20.500.12258/3700 en RSC Advances application/pdf application/pdf Royal Society of Chemistry
institution СКФУ
collection Репозиторий
language English
topic Paraffins
Benzoxazole
C-H functionalization
Cascade transformations
Cyclocondensation
Metal free
Nitroalkanes
One pot
One-pot synthesis
Phenols
spellingShingle Paraffins
Benzoxazole
C-H functionalization
Cascade transformations
Cyclocondensation
Metal free
Nitroalkanes
One pot
One-pot synthesis
Phenols
Aksenov, N. A.
Аксенов, Н. А.
Aksenov, A. V.
Аксенов, А. В.
Nadein, O. N.
Надеин, О. Н.
Aksenov, D. A.
Аксенов, Д. А.
Smirnov, A. N.
Смирнов, А. Н.
Rubin, M. A.
Рубин, М. А.
One-pot synthesis of benzoxazoles via the metal-free ortho-C-H functionalization of phenols with nitroalkanes
description PPA-activated nitroalkanes are employed in the design of a one-pot cascade transformation involving metal-free and oxidant-free direct ortho-C-H functionalization, followed by Beckman rearrangement and intramolecular cyclocondensation to produce benzoxazoles and benzobisoxazoles directly from easily available phenols
format Статья
author Aksenov, N. A.
Аксенов, Н. А.
Aksenov, A. V.
Аксенов, А. В.
Nadein, O. N.
Надеин, О. Н.
Aksenov, D. A.
Аксенов, Д. А.
Smirnov, A. N.
Смирнов, А. Н.
Rubin, M. A.
Рубин, М. А.
author_facet Aksenov, N. A.
Аксенов, Н. А.
Aksenov, A. V.
Аксенов, А. В.
Nadein, O. N.
Надеин, О. Н.
Aksenov, D. A.
Аксенов, Д. А.
Smirnov, A. N.
Смирнов, А. Н.
Rubin, M. A.
Рубин, М. А.
author_sort Aksenov, N. A.
title One-pot synthesis of benzoxazoles via the metal-free ortho-C-H functionalization of phenols with nitroalkanes
title_short One-pot synthesis of benzoxazoles via the metal-free ortho-C-H functionalization of phenols with nitroalkanes
title_full One-pot synthesis of benzoxazoles via the metal-free ortho-C-H functionalization of phenols with nitroalkanes
title_fullStr One-pot synthesis of benzoxazoles via the metal-free ortho-C-H functionalization of phenols with nitroalkanes
title_full_unstemmed One-pot synthesis of benzoxazoles via the metal-free ortho-C-H functionalization of phenols with nitroalkanes
title_sort one-pot synthesis of benzoxazoles via the metal-free ortho-c-h functionalization of phenols with nitroalkanes
publisher Royal Society of Chemistry
publishDate 2018
url https://dspace.ncfu.ru/handle/20.500.12258/3700
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