One-pot synthesis of benzoxazoles via the metal-free ortho-C-H functionalization of phenols with nitroalkanes
PPA-activated nitroalkanes are employed in the design of a one-pot cascade transformation involving metal-free and oxidant-free direct ortho-C-H functionalization, followed by Beckman rearrangement and intramolecular cyclocondensation to produce benzoxazoles and benzobisoxazoles directly from easily...
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Royal Society of Chemistry
2018
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ir-20.500.12258-37002025-02-13T08:51:34Z One-pot synthesis of benzoxazoles via the metal-free ortho-C-H functionalization of phenols with nitroalkanes Aksenov, N. A. Аксенов, Н. А. Aksenov, A. V. Аксенов, А. В. Nadein, O. N. Надеин, О. Н. Aksenov, D. A. Аксенов, Д. А. Smirnov, A. N. Смирнов, А. Н. Rubin, M. A. Рубин, М. А. Paraffins Benzoxazole C-H functionalization Cascade transformations Cyclocondensation Metal free Nitroalkanes One pot One-pot synthesis Phenols PPA-activated nitroalkanes are employed in the design of a one-pot cascade transformation involving metal-free and oxidant-free direct ortho-C-H functionalization, followed by Beckman rearrangement and intramolecular cyclocondensation to produce benzoxazoles and benzobisoxazoles directly from easily available phenols 2018-12-17T14:49:41Z 2018-12-17T14:49:41Z 2015 Статья Aksenov, N.A., Aksenov, A.V., Nadein, O.N., Aksenov, D.A., Smirnov, A.N., Rubin, M. One-pot synthesis of benzoxazoles via the metal-free ortho-C-H functionalization of phenols with nitroalkanes // RSC Advances. - 2015. - Volume 5. - Issue 88. - Pages 71620-71626 http://hdl.handle.net/20.500.12258/3700 en RSC Advances application/pdf application/pdf Royal Society of Chemistry |
| institution |
СКФУ |
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Репозиторий |
| language |
English |
| topic |
Paraffins Benzoxazole C-H functionalization Cascade transformations Cyclocondensation Metal free Nitroalkanes One pot One-pot synthesis Phenols |
| spellingShingle |
Paraffins Benzoxazole C-H functionalization Cascade transformations Cyclocondensation Metal free Nitroalkanes One pot One-pot synthesis Phenols Aksenov, N. A. Аксенов, Н. А. Aksenov, A. V. Аксенов, А. В. Nadein, O. N. Надеин, О. Н. Aksenov, D. A. Аксенов, Д. А. Smirnov, A. N. Смирнов, А. Н. Rubin, M. A. Рубин, М. А. One-pot synthesis of benzoxazoles via the metal-free ortho-C-H functionalization of phenols with nitroalkanes |
| description |
PPA-activated nitroalkanes are employed in the design of a one-pot cascade transformation involving metal-free and oxidant-free direct ortho-C-H functionalization, followed by Beckman rearrangement and intramolecular cyclocondensation to produce benzoxazoles and benzobisoxazoles directly from easily available phenols |
| format |
Статья |
| author |
Aksenov, N. A. Аксенов, Н. А. Aksenov, A. V. Аксенов, А. В. Nadein, O. N. Надеин, О. Н. Aksenov, D. A. Аксенов, Д. А. Smirnov, A. N. Смирнов, А. Н. Rubin, M. A. Рубин, М. А. |
| author_facet |
Aksenov, N. A. Аксенов, Н. А. Aksenov, A. V. Аксенов, А. В. Nadein, O. N. Надеин, О. Н. Aksenov, D. A. Аксенов, Д. А. Smirnov, A. N. Смирнов, А. Н. Rubin, M. A. Рубин, М. А. |
| author_sort |
Aksenov, N. A. |
| title |
One-pot synthesis of benzoxazoles via the metal-free ortho-C-H functionalization of phenols with nitroalkanes |
| title_short |
One-pot synthesis of benzoxazoles via the metal-free ortho-C-H functionalization of phenols with nitroalkanes |
| title_full |
One-pot synthesis of benzoxazoles via the metal-free ortho-C-H functionalization of phenols with nitroalkanes |
| title_fullStr |
One-pot synthesis of benzoxazoles via the metal-free ortho-C-H functionalization of phenols with nitroalkanes |
| title_full_unstemmed |
One-pot synthesis of benzoxazoles via the metal-free ortho-C-H functionalization of phenols with nitroalkanes |
| title_sort |
one-pot synthesis of benzoxazoles via the metal-free ortho-c-h functionalization of phenols with nitroalkanes |
| publisher |
Royal Society of Chemistry |
| publishDate |
2018 |
| url |
https://dspace.ncfu.ru/handle/20.500.12258/3700 |
| work_keys_str_mv |
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