One-pot synthesis of benzoxazoles via the metal-free ortho-C-H functionalization of phenols with nitroalkanes

One-pot synthesis of benzoxazoles via the metal-free ortho-C-H functionalization of phenols with nitroalkanes

PPA-activated nitroalkanes are employed in the design of a one-pot cascade transformation involving metal-free and oxidant-free direct ortho-C-H functionalization, followed by Beckman rearrangement and intramolecular cyclocondensation to produce benzoxazoles and benzobisoxazoles directly from easily...

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Главные авторы:	Aksenov, N. A., Аксенов, Н. А., Aksenov, A. V., Аксенов, А. В., Nadein, O. N., Надеин, О. Н., Aksenov, D. A., Аксенов, Д. А., Smirnov, A. N., Смирнов, А. Н., Rubin, M. A., Рубин, М. А.
Формат:	Статья
Язык:	English
Опубликовано:	Royal Society of Chemistry 2018
Темы:	Paraffins Benzoxazole C-H functionalization Cascade transformations Cyclocondensation Metal free Nitroalkanes One pot One-pot synthesis Phenols
Online-ссылка:	https://dspace.ncfu.ru/handle/20.500.12258/3700
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