Benzimidazoles and benzoxazoles via the nucleophilic addition of anilines to nitroalkanes

PPA-induced umpolung triggers efficient nucleophilic addition of unactivated anilines to nitroalkanes to produce N-hydroxyimidamides. The latter undergo sequential acid-promoted cyclocondensation with ortho-OH or ortho-NHR moieties to afford benzoxazoles and benzimidazoles, respectively

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Bibliografski detalji
Glavni autori:	Aksenov, A. V., Аксенов, А. В., Smirnov, A. N., Смирнов, А. Н., Aksenov, N. A., Аксенов, Н. А., Bijieva, A. S., Биджиева, А. С., Aksenova, I. V., Аксенова, И. В., Rubin, M. A., Рубин, М. А.
Format:	Статья
Jezik:	English
Izdano:	Royal Society of Chemistry 2018
Teme:	Addition reaction Aniline Benzimidazole Benzoxazoles Cyclocondensation Nitroalkanes Nucleophilic addition Umpolung
Online pristup:	https://www.scopus.com/record/display.uri?eid=2-s2.0-84925835134&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=fe656e0c7517dbc25228b3d577bd000c&sot=afnl&sdt=cl&cluster=scopubyr%2c%222015%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&relpos=35&citeCnt=19&searchTerm= https://dspace.ncfu.ru/handle/20.500.12258/3722
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spelling	ir-20.500.12258-37222020-09-14T14:12:31Z Benzimidazoles and benzoxazoles via the nucleophilic addition of anilines to nitroalkanes Aksenov, A. V. Аксенов, А. В. Smirnov, A. N. Смирнов, А. Н. Aksenov, N. A. Аксенов, Н. А. Bijieva, A. S. Биджиева, А. С. Aksenova, I. V. Аксенова, И. В. Rubin, M. A. Рубин, М. А. Addition reaction Aniline Benzimidazole Benzoxazoles Cyclocondensation Nitroalkanes Nucleophilic addition Umpolung PPA-induced umpolung triggers efficient nucleophilic addition of unactivated anilines to nitroalkanes to produce N-hydroxyimidamides. The latter undergo sequential acid-promoted cyclocondensation with ortho-OH or ortho-NHR moieties to afford benzoxazoles and benzimidazoles, respectively 2018-12-19T14:16:50Z 2018-12-19T14:16:50Z 2015 Статья Aksenov, A.V., Smirnov, A.N., Aksenov, N.A., Bijieva, A.S., Aksenova, I.V., Rubin, M. Benzimidazoles and benzoxazoles via the nucleophilic addition of anilines to nitroalkanes // Organic and Biomolecular Chemistry. - 2015. - Volume 13. - Issue 14. - Pages 4289-4295 https://www.scopus.com/record/display.uri?eid=2-s2.0-84925835134&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=fe656e0c7517dbc25228b3d577bd000c&sot=afnl&sdt=cl&cluster=scopubyr%2c%222015%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&relpos=35&citeCnt=19&searchTerm= http://hdl.handle.net/20.500.12258/3722 en Organic and Biomolecular Chemistry application/pdf application/pdf Royal Society of Chemistry
institution	СКФУ
collection	Репозиторий
language	English
topic	Addition reaction Aniline Benzimidazole Benzoxazoles Cyclocondensation Nitroalkanes Nucleophilic addition Umpolung
spellingShingle	Addition reaction Aniline Benzimidazole Benzoxazoles Cyclocondensation Nitroalkanes Nucleophilic addition Umpolung Aksenov, A. V. Аксенов, А. В. Smirnov, A. N. Смирнов, А. Н. Aksenov, N. A. Аксенов, Н. А. Bijieva, A. S. Биджиева, А. С. Aksenova, I. V. Аксенова, И. В. Rubin, M. A. Рубин, М. А. Benzimidazoles and benzoxazoles via the nucleophilic addition of anilines to nitroalkanes
description	PPA-induced umpolung triggers efficient nucleophilic addition of unactivated anilines to nitroalkanes to produce N-hydroxyimidamides. The latter undergo sequential acid-promoted cyclocondensation with ortho-OH or ortho-NHR moieties to afford benzoxazoles and benzimidazoles, respectively
format	Статья
author	Aksenov, A. V. Аксенов, А. В. Smirnov, A. N. Смирнов, А. Н. Aksenov, N. A. Аксенов, Н. А. Bijieva, A. S. Биджиева, А. С. Aksenova, I. V. Аксенова, И. В. Rubin, M. A. Рубин, М. А.
author_facet	Aksenov, A. V. Аксенов, А. В. Smirnov, A. N. Смирнов, А. Н. Aksenov, N. A. Аксенов, Н. А. Bijieva, A. S. Биджиева, А. С. Aksenova, I. V. Аксенова, И. В. Rubin, M. A. Рубин, М. А.
author_sort	Aksenov, A. V.
title	Benzimidazoles and benzoxazoles via the nucleophilic addition of anilines to nitroalkanes
title_short	Benzimidazoles and benzoxazoles via the nucleophilic addition of anilines to nitroalkanes
title_full	Benzimidazoles and benzoxazoles via the nucleophilic addition of anilines to nitroalkanes
title_fullStr	Benzimidazoles and benzoxazoles via the nucleophilic addition of anilines to nitroalkanes
title_full_unstemmed	Benzimidazoles and benzoxazoles via the nucleophilic addition of anilines to nitroalkanes
title_sort	benzimidazoles and benzoxazoles via the nucleophilic addition of anilines to nitroalkanes
publisher	Royal Society of Chemistry
publishDate	2018
url	https://www.scopus.com/record/display.uri?eid=2-s2.0-84925835134&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=fe656e0c7517dbc25228b3d577bd000c&sot=afnl&sdt=cl&cluster=scopubyr%2c%222015%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&relpos=35&citeCnt=19&searchTerm= https://dspace.ncfu.ru/handle/20.500.12258/3722
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Benzimidazoles and benzoxazoles via the nucleophilic addition of anilines to nitroalkanes

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