Intramolecular nucleophilic addition of carbanions generated from: N -benzylamides to cyclopropenes

An unusual reaction is described, involving a formal intramolecular nucleophilic substitution of bromocyclopropanes with nitrogen ylides generated in situ from N-benzyl carboxamides. It is shown that this reaction involves cyclopropene intermediates and allows for the facile and expeditious preparat...

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Κύριοι συγγραφείς:	Aksenov, N. A., Аксенов, Н. А., Rubin, M. A., Рубин, М. А.
Μορφή:	Статья
Γλώσσα:	English
Έκδοση:	Royal Society of Chemistry 2018
Θέματα:	Addition reaction Scaffolds Carboxamides Cyclopropene Nucleophilic addition Nucleophilic substitutions Reaction intermediate
Διαθέσιμο Online:	https://dspace.ncfu.ru:443/handle/20.500.12258/395
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id	ir-20.500.12258-395
record_format	dspace
spelling	ir-20.500.12258-3952025-02-13T09:31:43Z Intramolecular nucleophilic addition of carbanions generated from: N -benzylamides to cyclopropenes Aksenov, N. A. Аксенов, Н. А. Rubin, M. A. Рубин, М. А. Addition reaction Scaffolds Carboxamides Cyclopropene Nucleophilic addition Nucleophilic substitutions Reaction intermediate An unusual reaction is described, involving a formal intramolecular nucleophilic substitution of bromocyclopropanes with nitrogen ylides generated in situ from N-benzyl carboxamides. It is shown that this reaction involves cyclopropene intermediates and allows for the facile and expeditious preparation of 3-azabicyclo[3.1.0]hexan-2-one scaffolds 2018-05-31T14:52:57Z 2018-05-31T14:52:57Z 2018 Статья Maslivetc, V., Barrett, C., Aksenov, N.A., Rubina, M., Rubin, M. Intramolecular nucleophilic addition of carbanions generated from: N -benzylamides to cyclopropenes // Organic and Biomolecular Chemistry. - 2018. - Volume 16. - Issue 2. - pp. 285-294. https://dspace.ncfu.ru:443/handle/20.500.12258/395 en Organic and Biomolecular Chemistry application/pdf application/pdf Royal Society of Chemistry
institution	СКФУ
collection	Репозиторий
language	English
topic	Addition reaction Scaffolds Carboxamides Cyclopropene Nucleophilic addition Nucleophilic substitutions Reaction intermediate
spellingShingle	Addition reaction Scaffolds Carboxamides Cyclopropene Nucleophilic addition Nucleophilic substitutions Reaction intermediate Aksenov, N. A. Аксенов, Н. А. Rubin, M. A. Рубин, М. А. Intramolecular nucleophilic addition of carbanions generated from: N -benzylamides to cyclopropenes
description	An unusual reaction is described, involving a formal intramolecular nucleophilic substitution of bromocyclopropanes with nitrogen ylides generated in situ from N-benzyl carboxamides. It is shown that this reaction involves cyclopropene intermediates and allows for the facile and expeditious preparation of 3-azabicyclo[3.1.0]hexan-2-one scaffolds
format	Статья
author	Aksenov, N. A. Аксенов, Н. А. Rubin, M. A. Рубин, М. А.
author_facet	Aksenov, N. A. Аксенов, Н. А. Rubin, M. A. Рубин, М. А.
author_sort	Aksenov, N. A.
title	Intramolecular nucleophilic addition of carbanions generated from: N -benzylamides to cyclopropenes
title_short	Intramolecular nucleophilic addition of carbanions generated from: N -benzylamides to cyclopropenes
title_full	Intramolecular nucleophilic addition of carbanions generated from: N -benzylamides to cyclopropenes
title_fullStr	Intramolecular nucleophilic addition of carbanions generated from: N -benzylamides to cyclopropenes
title_full_unstemmed	Intramolecular nucleophilic addition of carbanions generated from: N -benzylamides to cyclopropenes
title_sort	intramolecular nucleophilic addition of carbanions generated from: n -benzylamides to cyclopropenes
publisher	Royal Society of Chemistry
publishDate	2018
url	https://dspace.ncfu.ru:443/handle/20.500.12258/395
work_keys_str_mv	AT aksenovna intramolecularnucleophilicadditionofcarbanionsgeneratedfromnbenzylamidestocyclopropenes AT aksenovna intramolecularnucleophilicadditionofcarbanionsgeneratedfromnbenzylamidestocyclopropenes AT rubinma intramolecularnucleophilicadditionofcarbanionsgeneratedfromnbenzylamidestocyclopropenes AT rubinma intramolecularnucleophilicadditionofcarbanionsgeneratedfromnbenzylamidestocyclopropenes
_version_	1842245947833188352

Intramolecular nucleophilic addition of carbanions generated from: N -benzylamides to cyclopropenes

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